The 2015 Antarctic Ozone Hole Summary: Report #5, Monday 14 September 2015 Paul Krummel and Paul Fraser CSIRO Oceans and Atmosphere Aspendale, Victoria Summary For the 2015 ozone hole we will again be reporting images and metrics calculated from both the OMI and OMPS data products (see the instrumentation section for a description of these). Please note that due to operational reasons, the OMPS Level 3 global gridded daily total ozone column products provided by NASA run 4-5 days behind the current day. By mid-August, the onset of the 2015 ozone hole was yet to start. This is the latest onset of the ozone hole that has been seen since the mid-to-late 1980s. The mid-to-lower Antarctic stratospheric temperatures have been colder than usual in late July/early August, with a less-than-normal stratospheric heat flux towards the pole from mid-July onwards. On 18 August the 2015 ozone hole had begun and by 21 August the ozone hole area had risen to 2.9 million km2 and the ozone minima had dropped to 191 DU. The low-tomid Antarctic stratospheric temperatures remained colder than usual during the third week of August. The fourth week of August saw moderate growth in the ozone hole area, reaching 6.3 million km 2 on 26 August, while the ozone minima showed quite a bit of variability fluctuating between 164 and 202 DU. The low-tomid Antarctic stratospheric temperatures remained colder than usual during the fourth week of August. The last few days of August, beginning of September saw the ozone hole area increase rapidly to be approximately 15 million km2 by 4 September, but large variability remained in the ozone hole minima, dropping to 161 DU on 1 September before rising again to 184 DU on 4 September. The low-to-mid Antarctic stratospheric temperatures remained colder than usual during this period. The period of 5-11 September saw the ozone hole area continue to grow, reaching 21.5 million km2 by 11 September, but the ozone hole is yet to fully close for 2015. The variability on the ozone minima has reduced considerably, with the minima dropping to a low of 156 DU during this period. The colder than usual low-to-mid Antarctic stratospheric temperatures continued during this period. The 2015 ozone hole Ozone hole area By mid-August, the 2015 ozone hole had essentially yet to appear, with the OMI data indicating no area where the total column ozone was less than 220 DU. The OMPS data indicate some small excursions below 220 DU in early August, but nothing since. This is the latest onset of the ozone hole since the mid-to-late 1980s.The 2015 ozone hole finally started to form on 18 August, and by 21 August the ozone hole area had grown to 2.9 million km2. The ozone hole area continued to grow during the fourth week of August reaching 6.3 million km2 on 26 August before dropping back to just under 5 million km2 on 27 August. The development of this years’ hole based on this metric is similar to the 2010 ozone hole, which was also a late developing hole but was a persistent hole as well. The last few days of August, beginning of September saw the ozone hole area increase rapidly to be approximately 15 million km2 by 4 September, which is close to the long-term 1979-2014 average for this time of year, and similar to the 2012 & 2014 ozone holes. The ozone hole continued to grow during the second week of September, reaching 20.9 million km2 on 7 September before dropping back to 18.7 million km2 on 9 September and increasing again to 21.5 million km2 on 11 September. This variability is due to the ozone hole not yet being completely closed. The ozone hole area is currently (11 Sep) very close to the 2013 ozone hole on the same date. Ozone deficit The bottom panel of Figure 1 shows that by mid-August there was no estimated daily ozone deficit to date. By the end of the third week of August the estimated daily ozone deficit had reached 1 million tonnes. The fourth week of August saw the daily ozone deficit remain quite low below 2 million tonnes. The beginning of September saw the daily ozone hole deficit reach 5 million tonnes before dropping back to about 4 million tonnes by 4 September. This is well below the long-term 1979-2014 average for this time of year and is similar to the 2010 ozone hole. During the second week of September the ozone deficit continued to grow reaching 11.7 million tonnes by 11 September, which is still below the long-term 19792014 average for this time of year. Ozone hole minima By mid-August the OMI ozone minima had not yet dropped below the 220 DU threshold, but it is expected to do so in the next week (current minima is approximately 225 DU). The OMPS minima did fall below 220 DU on 3, 5 & 6 August due to a few ‘pixels’ right at the polar vortex edge reaching just below this threshold. On 18 August the ozone minima dropped sharply below 220 DU indicating the beginning of the 2015 ozone hole, and by 21 August the minima had dropped to 191 DU, close to the long-term 1979-2014 average. The OMPS minima appears to have dropped below, and remained below 220 DU, 2-3 days earlier than the OMI data show, but the timing of the onset can be uncertain due to the large variability in this metric during the first few weeks of August. The daily ozone minima continued to be quite variable during the fourth week of August dropping to 164 DU on 24 August before increasing to 202 DU on 27 August. The variability in this metric will reduce in the next one to two weeks as the polar night reduces. The variability in the ozone hole minima continued during the last days of August through early September, dropping to 161 DU on 1 September before rising again to 184 DU on 4 September. By 8 September the ozone minima had reached 156 DU, before rising slightly to 159 DU by 11 September, which is very close to the long-term 1979-2014 average. The large variability in the ozone minima has now reduced considerably. Average ozone in the hole The average ozone amount in the hole (averaged column ozone amount in the hole weighted by area; Figure 2 bottom panel) shows that the ozone hole for 2015 is yet to commence by mid-August. During the third week of August the average amount of ozone in the hole dropped rapidly to be at 203 DU on 21 August. Similar to the ozone minima, this metric is showing quite a bit of variability, dropping to 195 DU on 24 August before rising again to 213 DU on 27 August. The average ozone amount in the hole also continued to show quite a bit of variability, dropping to 194 DU on 1 September before rising again to 207 DU on 4 September. The large variability in this metric has also reduce now, with the average ozone amount in the hole falling to 194 DU on 11 September. Total column ozone images Total column ozone data over Australia and Antarctica for 20 August – 4 September 2015 from OMI are shown in Figure 3 and for 14 - 29 August 2015 from OMPS are shown in Figure 4. By the end of the second week of August the Antarctic polar night region still covered most of Antarctica, with essentially no sign yet of any areas below the 220 DU threshold that defines the Antarctic ozone hole. What is quite evident, compared to recent years, is the lack of the strong ridge of high ozone in the band immediately south of Australia between about 40-60°S. The areas of higher ozone that are present in this latitude band appear to be patchy, possibly indicating some wave activity. The third week of August saw the 2015 ozone hole begin to form, which can be seen as small areas indicated by the red 220 DU contour predominantly in the region of 150°W to 60°W at around 70°S during 18-21 August. During the fourth week of August the ozone hole continued to form in the region of 0°W to 90°W before propagating to the region between 0°E to 120°E. On 28 August, the Australian Antarctic stations of Mawson and Casey were within the 220 DU contour. The formation of the 2015 ozone hole can be clearly seen in the images from 30 August through to 4 September, as the red 220 DU contour progressively grew during this period. It is expected that the 2015 ozone hole will fully form during the next week, which will see the areas below 220 DU completely join up and the 220 DU contour will close to encircle the Antarctic continent. The Australian Antarctic stations of Mawson, Davis and Casey were within or on the edge of the 220 DU contour on 30-31 August, and again on 4 September. The lack of the strong ridge of high ozone in the band immediately south of Australia between about 40-60°S is still evident and quite unusual compared to most previous years. The period of 5-11 September saw the ozone hole almost completely close, except for a small wedge of higher total column ozone which is particularly evident on 7 September immediately south of South America, and proceeded to propagate eastwards to be between the Australian Antarctic stations of Mawson and Davis by 11 September. The Australian Antarctic stations were within or on the edge of the 220 DU contour for most of the 5-11 September period. NASA MERRA heat flux and temperature The MERRA 45-day mean 45-75°S heat fluxes at 50 & 100 hPa are shown in Figure 5. A less negative heat flux usually results in a colder polar vortex, while a more negative heat flux indicates heat transported towards the pole (via some meteorological disturbance/wave) and results in a warming of the polar vortex. The corresponding 60-90°S zonal mean temperatures at 50 & 100 hPa are shown in Figure 6, these usually show an anti-correlation to the heat flux. During June the 45-75°S heat flux at 50 & 100 hPa was in the lower 10-30% of the 1979-2014 range, indicating a larger amount of heat transported towards the pole than average. During July, at both the 50 & 100 hPa levels, this transitioned to be in the upper 10% range at 50 hPa and 70-90% range at 100 hPa, indicating a strong reduction in the heat transported towards the pole. By the end of the third week of August, the 45-75°S heat flux at 50 hPa was at the maximum seen for the 1979-2014 range for this time of year, and at 100 hPa was at the 90th percentile mark of the 1979-2014 range, both continuing to indicate reduced heat transport towards the pole. During the fourth week of August, the 45-75°S heat flux at 50 hPa was higher than the maximum seen for the 1979-2014 range for this time of year, and at 100 hPa was in the highest 10th percentile mark of the 1979-2014 range, both continuing to indicate reduced heat transport towards the pole. The last few days of August saw the 45-75°S heat flux at 50 & 100 hPa remain in the highest 10th percentile mark of the 1979-2014 range. The first twelve days of September saw the 45-75°S heat flux at 50 & 100 hPa either exceed the maximum seen for the 1979-2014 range for this time of year or be in the highest 10th percentile mark of the 19792014 range, both continuing to indicate reduced heat transport towards the pole. Correspondingly, the 60-90°S zonal mean temperatures at 50 & 100 hPa were, overall, similar to the 19792014 average, with some deviations above and below this line in June & July. The beginning of August saw the 60-90°S zonal mean temperatures at both 50 & 100 hPa to be at or just below the previous recorded lowest minimums for this time of year. By mid-August the temperatures had trended up to once again be close to the long-term averages. The third week of August saw the 60-90°S zonal mean temperatures at both the 50 & 100 hPa levels drop to be at the lower 10% percent mark of the 1979-2014 range by 21 August, indicating quite cold conditions in the low-to-mid Antarctic stratosphere. The fourth week of August saw the 60-90°S zonal mean temperatures at both the 50 & 100 hPa levels remain quite cold in the lower 10-30% percent mark of the 1979-2014 range. The last days of August saw the 60-90°S zonal mean temperatures at both the 50 & 100 hPa levels remain quite cold, with the 50 hPa trace remaining in the lower 10-30% percent mark of the 1979-2014 range, and the 100 hPa trace just inside the lower 30-50% mark of the 1979-2014 range. The first twelve days of September saw 60-90°S zonal mean temperatures at both the 50 & 100 hPa levels remain quite cold either in the lower 10-30% percent mark of the 1979-2014 range or just inside the lower 30-50% mark of the 1979-2014 range. At 50 hPa, the type 1 PSC (HNO3.3H2O) formation threshold temperature (195 K) was reached in late June. At 100 hPa, the threshold temperature was reached during the second week of July. Note a brief description of MERRA is given in the Definitions at the end of this report. Summary: WMO Antarctic Ozone Bulletins – No. 1, 1 September 2015 The 2015 (and previous years) WMO Antarctic Ozone http://www.wmo.int/pages/prog/arep/gaw/ozone/index.html Bulletins are available from Temperatures and PSCs Stratospheric temperatures over Antarctica have been below the PSC type I (nitric acid trihydrate: NAT) threshold of 194.6 K since 11 May and below the PSC type II threshold of 187.8 K since 3 June. The daily minimum temperatures at the 50 hPa level have been below the 1979-2014 average since mid April. On several days in April, May, July and August the 50 hPa minimum temperature was below the 1979-2014 minimum. The average temperature at 50 hPa over the 60-90°S region was oscillating around the long term mean until mid-July, after which it has been below the long term mean. In early August it was close to the 1979-2014 minimum. At 10 hPa, the 60-90°S mean temperature has been close to or above the long term mean on most of the days during the April to August time period, with a few days below the mean. Since the onset of NAT temperatures in early May, the NAT area was oscillating around the long term mean in May and June and remained close to the average in July. In August the NAT area has been well above the long term mean on most days. On 5th August the NAT area reached a maximum for the season with 28.2 million km2, which is higher than the maximum reached in recent years. One has to go back to 2009 to find a higher PSC area maximum (28.4 million km2). The NAT volume was relatively low between late May and early August: It was below the long-term mean and also below the NAT volume of recent years. During August the NAT volume was similar to that of recent years (2011, 2013 and 2014) and superior to that of 2012. Heat Flux During May the 45-day mean of the heat flux at 100 hPa was lower than or close to the 1979-2014 average. In June it was somewhat larger than the long term average. In July and August the heat flux has been noticeably smaller than the long term mean. This is an indication of a stable vortex. At the 46.5 hPa level (altitude of ~18.5-19.5 km) the vortex is now almost entirely depleted of hydrochloric acid (HCl), one of the reservoir gases that can be transformed to active chlorine. The area affected by HCl removal in 2015 is similar to or larger than in recent years (2010-2014). In the sunlit collar along the vortex edge there are regions with 2.0-2.1 ppbv of active chlorine (chlorine monoxide, ClO), and ozone depletion has started. Satellite Observations Satellite observations show that the area where total ozone is less than 220 DU (“ozone hole area”) has been significantly above zero since 18 August. This is a relatively late onset of ozone depletion. The ozone hole area on 27 August was approx. 5.1 million km2, about half the long term average. The date of the onset of ozone depletion varies considerably from one year to the next, depending on the position of the polar vortex and availability of sunshine after the polar night. In 2015, the vortex has been relatively stable and concentric around the South Pole. This can explain the late onset of ozone depletion. As the sun returns to Antarctica after the polar night, ozone destruction will speed up. It is still too early to give a definitive statement about the development of this year’s ozone hole and the degree of ozone loss that will occur. This will, to a large extent, depend on the meteorological conditions. However, the temperature conditions and the extent of polar stratospheric clouds so far indicate that the degree of ozone loss in 2015 will be similar to that observed in 2014 and 2013 and probably somewhat larger than in 2010 and 2012. Satellite Instrumentation OMI Data from the Ozone Monitoring Instrument (OMI) on board the Earth Observing Satellite (EOS) Aura, that have been processed with the NASA TOMS Version 8.5 algorithm, have been utilized again this year in our weekly ozone hole reports. OMI continues the NASA TOMS satellite record for total ozone and other atmospheric parameters related to ozone chemistry and climate. On 19 April 2012 a reprocessed version of the complete (to date) OMI Level 3 gridded data was released. This is a result of a post-processing of the L1B data due to changed OMI row anomaly behaviour (see below) and consequently followed by a re-processing of all the L2 and higher data. These new data have now been reprocessed by CSIRO, which has resulted in small changes in the ozone hole metrics we calculate, and as such, these metrics may be slightly different for previous years for OMI data (2005-2011). In 2008, stripes of bad data began to appear in the OMI products apparently caused by a small physical obstruction in the OMI instrument field of view and is referred to as a row anomaly. NASA scientists guess that some of the reflective Mylar that wraps the instrument to provide thermal protection has torn and is intruding into the field of view. On 24 January 2009 the obstruction suddenly increased and now partially blocks an increased fraction of the field of view for certain Aura orbits and exhibits a more dynamic behaviour than before, which led to the larger stripes of bad data in the OMI images. Since 5 July 2011, the row anomaly that manifested itself on 24 January 2009 now affects all Aura orbits, which can be seen as thick white stripes of bad data in the OMI total column ozone images. It is now thought that the row anomaly problem may have started and developed gradually since as early as mid-2006. Despite various attempts, it turned out that due to the complex nature of the row anomaly it is not possible to correct the L1B data with sufficient accuracy (≤ 1%) for the errors caused by the row anomaly, which has ultimately resulted in the affected data being flagged and removed from higher level data products (such as the daily averaged global gridded level 3 data used here for the images and metrics calculations). However, once the polar night reduces enough then this should not be an issue for determining ozone hole metrics, as there is more overlap of the satellite passes at the polar regions which essentially ‘fills-in’ these missing data. OMPS OMPS (Ozone Mapping and Profiler Suite) is a new ozone instrument on the Suomi National Polar-orbiting Partnership satellite (Suomi NPP), which was launched on 28 October 2011 and placed into a sunsynchronous orbit 824 km above the Earth. The partnership is between NASA, NOAA and DoD (Department of Defense), see http://npp.gsfc.nasa.gov/ for more details. OMPS will continue the US program for monitoring the Earth's ozone layer using advanced hyperspectral instruments that measure sunlight in the ultraviolet and visible, backscattered from the Earth's atmosphere, and will contribute to observing the recovery of the ozone layer in coming years. For the 2014 ozone hole season, we will also be using the OMPS total column ozone data by producing metrics from both OMI and OMPS Level 3 global gridded daily total ozone column products from NASA, and present both sets of results for comparison. NOTE that NASA receive the raw OMPS data from NOAA, and due to some operational delays, NASA have decided to delay the processing of data by 96 hours (4 days) from the time they obtain the first raw data for a given day. As a result, the OMPS Level 3 global gridded daily total ozone column products provided by NASA run 4-5 days behind the current day. Figure 1: Ozone hole area (top panel) and estimated daily ozone deficit (bottom panel) based on OMI (data up to 11 September 2015) and OMPS (data up to 6 September 2015) satellite data. Figure 2: Ozone hole depth (top panel) and average ozone amount within the ozone hole (bottom panel) based on OMI (data up to 11 September 2015) and OMPS (data up to 6 September 2015) satellite data. Figure 3: OMI ozone hole images for 27 August – 11 September 2015; the ozone hole boundary is indicated by the red 220 DU contour line. The Australian Antarctic (Mawson, Davis and Casey) and Macquarie Island stations are shown as green plus symbols. The white area over Antarctica is missing data and indicates the approximate extent of the polar night. The OMI instrument requires solar radiation to the earth’s surface in order to measure the column ozone abundance. The white stripes are bad/missing data due to a physical obstruction in the OMI instrument field of view. Figure 4: OMPS ozone hole images for 22 August – 6 September 2015; the ozone hole boundary is indicated by the red 220 DU contour line. The Australian Antarctic (Mawson, Davis and Casey) and Macquarie Island stations are shown as green plus symbols. The white area over Antarctica is missing data and indicates the approximate extent of the polar night. The OMPS instrument requires solar radiation to the earth’s surface in order to measure the column ozone abundance. Note that due to operational reasons, the OMPS Level 3 global gridded daily total ozone column products provided by NASA run 4-5 days behind the current day. Figure 5: 45-day mean 45°S-75°S eddy heat flux at 50 & 100 hPa. Images courtesy of NASA GSFC, downloaded 14 September 2015, data through to 12 September 2015: http://ozonewatch.gsfc.nasa.gov/meteorology/flux_2015_MERRA_SH.html Figure 6: 60°S-90°S zonal mean temperature at 50 & 100 hPa. Images courtesy of NASA GSFC, downloaded 14 September 2015, data through to 12 September 2015: http://ozonewatch.gsfc.nasa.gov/meteorology/temp_2015_MERRA_SH.html Definitions CFCs: chlorofluorocarbons, synthetic chemicals containing chlorine, once used as refrigerants, aerosol propellants and foam-blowing agents, that break down in the stratosphere (15-30 km above the earth’s surface), releasing reactive chlorine radicals that catalytically destroy stratospheric ozone. DU: Dobson Unit, a measure of the total ozone amount in a column of the atmosphere, from the earth’s surface to the upper atmosphere, 90% of which resides in the stratosphere at 15 to 30 km. Halons: synthetic chemicals containing bromine, once used as fire-fighting agents, that break down in the stratosphere releasing reactive bromine radicals that catalytically destroy stratospheric ozone. Bromine radicals are about 50 times more effective than chlorine radicals in catalytic ozone destruction. MERRA: is a NASA reanalysis for the satellite era using a major new version of the Goddard Earth Observing System Data Assimilation System Version 5 (GEOS-5). The project focuses on historical analyses of the hydrological cycle in a broad range of weather and climate time scales. It places modern observing systems (such as EOS suite of observations) in a climate context. Since these data are from a reanalysis, they are not up-to-date. So, NASA supplement with the GEOS-5 FP data that are also produced by the GEOS-5 model in near real time. These products are produced by the NASA Global Modeling and Assimilation Office (GMAO). Ozone: a reactive form of oxygen with the chemical formula O3; ozone absorbs most of the UV radiation from the sun before it can reach the earth’s surface. Ozone Hole: ozone holes are examples of severe ozone loss brought about by the presence of ozone depleting chlorine and bromine radicals, whose levels are enhanced by the presence of PSCs (polar stratospheric clouds), usually within the Antarctic polar vortex. The chlorine and bromine radicals result from the breakdown of CFCs and halons in the stratosphere. Smaller ozone holes have been observed within the weaker Arctic polar vortex. Polar night terminator: the delimiter between the polar night (continual darkness during winter over the Antarctic) and the encroaching sunlight. By the first week of October the polar night has ended at the South Pole. Polar vortex: a region of the polar stratosphere isolated from the rest of the stratosphere by high west-east wind jets centred at about 60°S that develop during the polar night. The isolation from the rest of the atmosphere and the absence of solar radiation results in very low temperatures (< -78°C) inside the vortex. PSCs: polar stratospheric clouds are formed when the temperatures in the stratosphere drop below -78°C, usually inside the polar vortex. This causes the low levels of water vapour present to freeze, forming ice crystals and usually incorporates nitrate or sulphate anions. TOMS, OMI & OMPS: the Total Ozone Mapping Spectrometer (TOMS), Ozone Monitoring Instrument (OMI), and Ozone Mapping and Profiler Suite (OMPS) are satellite borne instruments that measure the amount of back-scattered solar UV radiation absorbed by ozone in the atmosphere; the amount of UV absorbed is proportional to the amount of ozone present in the atmosphere. UV radiation: a component of the solar radiation spectrum with wavelengths shorter than those of visible light; most solar UV radiation is absorbed by ozone in the stratosphere; some UV radiation reaches the earth’s surface, in particular UV-B which has been implicated in serious health effects for humans and animals; the wavelength range of UV-B is 280-315 nanometres. Acknowledgements The TOMS and OMI data are provided by the TOMS ozone processing team, NASA Goddard Space Flight Center, Atmospheric Chemistry & Dynamics Branch, Code 613.3. The OMI instrument was developed and built by the Netherlands's Agency for Aerospace Programs (NIVR) in collaboration with the Finnish Meteorological Institute (FMI) and NASA. The OMI science team is lead by the Royal Netherlands Meteorological Institute (KNMI) and NASA. The OMPS Level 3 data used in this report were created from a research dataset developed by NASA's NPP Ozone Science Team using nadir measurements from SuomiNPP's Ozone Mapping and Profiler Suite(OMPS). All data were downloaded from ftp://jwocky.gsfc.nasa.gov/pub.