1.What is the meq/L if my analytical value for Ca+2 is 60.0 mg/L? Molar mass of Calcium= 40 g/mol , Valency = +2 mEq = (mg X valence)/atomic weight = ( 60 x 2 ) / 40 = 3 mEq/L 2.What is the mmol/L if my analytical value for Cl- is 87.0 mg/L? Molar mass of Cl = 35.453 g/mol To go from mmol/L to mg/L, multiply by the molecular weight. To go from mg/L to mmol/L, divide by the molecular weight. 87/35.5 = 2.45 mmol/L 3.I am measuring 22.2 mg/L of Si. What is the equivalent concentration of SiO4? Molar Mass of Si= 28.09 g/mol 22.2 mg/L = 0.0222 g / L Number of moles = Amount in grams / Molar Mass = 0.0222 / 28.09 = 0.00079 moles /L Equivalent concentration of SiO4 = Moles of Si x Molar mass of SiO4 = 0.00079 moles/Lx 92.08 g / mol = 0.073 g/L 4.What is the concentration of Hydronium ions in mg/L for a water sample with a pH of 1? pH= - log ( H^+ ) 1= - log ( H^+) ( H^+ ) = 1.0 x 10^-1 = 0.1 M = 0.1 moles / L Mass = 0.1 mole x 18 g/mol = 1.8 g = 1800 mg Final answer= 1800 mg/L 5. I am measuring 136.7 mg/L of Na. What is the equivalent concentration of NaAlSi3O8? Molar Mass of Na= 23 g/mol 136.7 mg/L = 0.1367 g / L Number of moles = Amount in grams / Molar Mass = 0.1367 / 23 = 0.00594 moles /L Equivalent concentration of NaAlSi3O8 = Moles of Na x Molar mass of NaAlSi3O8 = 0.00594 moles/L x 262.2 g / mol = 1.558 g/L 6. Combining Calcium and Sulfate Ions would make which of the following compounds? CaSO4 CaS Ca(SO4)2 CaS2 Ca2SO4 Ca2(SO4)2 Ca3(SO4)2 Ca2(SO4)3 7.An unknown water sample shows a sulfate absorbance of 0.57. What is the sulfate concentration of the water sample in mg/L? < 61.0 mg/L 61.0 mg/L 61.5 mg/L 62.0 mg/L 62.5 mg/L 63.0 mg/L 63.5 mg/L > 63.5 mg/L Absorbance value= A+B× Sulfate concentration (in mg/L) 8.An analysis of a water sample yields data as shown. What would be the best hydrochemical classification for the water? Answer: Sulfate because its concentration is the largest. Na 335.0 mg/L K 13.3 mg/L Ca 52.1 mg/L Mg 3.0 mg/L Cl 222.0 mg/L SO4 490.0 mg/L HCO3 88.5 mg/L a. Sodium and/or Potassium b. Calcium c. Magnesium d. Chloride e. Sulfate f. Bicarbonate and/or Carbonate