Solutions CW 3 1. Determine the solubility of NH4Cl at 50°C in 100 g of H2O. 2. Calculate the mass of Ca(OH)2 (molar mass = 74.093 g/mol) present in 275 mL of 11.0 M solution. 3. What volume of 12.0 M solution should be used in order to prepare a 2.5 L solution that is 1.5 M? 4. How much more KNO3 can be dissolved at 60°C than at 30°C? 5. Calculate the volume, in mL, of a 3.0 M solution containing 25 g of Li2S (molar mass = 45.95 g/mol). 6. 30 g of KClO3 is added to 100 g of water at 80°C, is the solution saturated or unsaturated? 7. While preparing a 350 mL 2.2 M solution you accidentally pour in 530 mL. What is the concentration of the resulting solution? 8. Calculate the volume of a 4.0 M solution containing 0.25 moles of solute. 9. How many moles of KCl (molar mass = 74.5513 g/mol) are present in 1.25 L of 5.0 M solution 10. What is the minimum temperature required to dissolve 40 g of KCl in 100 g of water? 11. Determine the concentration of a 785 mL solution containing 294.2 g of KNO3 (molar mass = 101.1032 g/mol). 12. If 30 g of KClO3 is added to 100 g of water at 30°C how much will not dissolve? 13. If 80 g of NaCl is added to 100 g of water at 70°C, is the solution saturated or unsaturated? Solutions CW 3 Answers 1. Determine the solubility of NH4Cl at 50°C in 100 g of H2O. 50 g 2. Calculate the mass of Ca(OH)2 (molar mass = 74.093 g/mol) present in 275 mL of 11.0 M solution. 11.0 = n / 0.275 n = 3.0 moles 3.0 (74.093) = 220 g 3. What volume of 12.0 M solution should be used in order to prepare a 2.5 L solution that is 1.5 M? (12.0) (V1) = (1.5) (2.5) V1 = 0.31 L or 310 mL 4. How much more KNO3 can be dissolved at 60°C than at 30°C? (102 – 45) = 57 g 5. Calculate the volume, in mL, of a 3.0 M solution containing 25 g of Li2S (molar mass = 45.95 g/mol). 25 / 45.95 = 0.54 moles 3.0 = 0.54 / V V = 0.18 L 180 mL 6. 30 g of KClO3 is added to 100 g of water at 80°C, is the solution saturated or unsaturated? Unsaturated (solubility = 40 g at 80°C) 7. While preparing a 350 mL 2.2 M solution you accidentally pour in 530 mL. What is the concentration of the resulting solution? (2.2) (350) = M2 (530) M2 = 1.5 M 8. Calculate the volume of a 4.0 M solution containing 0.25 moles of solute. 4.0 = 0.25 / V V = 0.063 L 63 mL 9. How many moles of KCl (molar mass = 74.5513 g/mol) are present in 1.25 L of 5.0 M solution 5.0 = n / 1.25 n = 6.3 moles 10. What is the minimum temperature required to dissolve 40 g of KCl in 100 g of water? 50°C 11. Determine the concentration of a 785 mL solution containing 294.2 g of KNO3 (molar mass = 101.1032 g/mol). 294.2 / 101.1032 = 2.910 moles 2.910 / 0.785 = 3.71 M 12. If 30 g of KClO3 is added to 100 g of water at 30°C how much will not dissolve? 10 g will dissolve so 20 g will not dissolve 13. If 80 g of NaCl is added to 100 g of water at 70°C, is the solution saturated or unsaturated? Solubility is 38 g, so it is Saturated