MOTION OF PARTICLE TROUGH FLUID : FLUIDIZATION (a) Fluidization is one of the processes involving the movement of particles through fluid. (i) Define ‘ Fluidization ‘ Fluidization is a process whereby a granular material is converted from a static solid-like state to a dynamic fluid-like state. (ii) Describe the purpose of fluidization The most common reason for fluidizing a bed is to obtain vigorous agitation of the solids in contact with the fluid, leading to an enhanced transport mechanism (diffusion, convection, and mass/energy transfer). (iii) Sketch the schematic diagram depicts the fluidization process occurred in the granular bed column. (b) Catalyst pellets 5 mm in diameter are to be fluidized with 45 000 kg/h of water with density 985 kg/m3 at 50 ºC in a vertical cylindrical vessel. The density of the catalyst particles is 1760 kg/m3 and their sphericity is 0.86. Particle: Pellet Dp = 5 x 10-3 m ρp = 1760 kg/m3 Φ = 0.86 Take εM = 0.45 Fluid: Water m = 45000 kg/h ρ = 985 kg/m3 µ = 0.6 x 10-3 kg/m.s ( at T=50 ºC) (i) Calculate the minimum velocity ̅̅̅̅̅ 𝑉𝑂𝑀 of the water used to fluidized the catalyst pellets ̅̅̅̅𝟐 ̅ 𝑶𝑴 (𝟏 − 𝜺𝑴 ) 𝟏. 𝟕𝟓𝝆𝑽 𝟏𝟓𝟎𝝁𝑽 𝑶𝑴 𝟏 + = 𝒈(𝝆𝒑 − 𝝆) 𝜱𝒔 𝑫𝒑 𝜱𝟐𝑺 𝑫𝟐𝒑 𝜺𝟑𝑴 𝜺𝟑𝑴 ̅ 𝑶𝑴 (𝟏 − 𝟎. 𝟒𝟓) 𝟏. 𝟕𝟓(𝟗𝟖𝟓)̅̅ 𝟏𝟓𝟎(𝟎. 𝟔 𝐱 𝟏𝟎−𝟑 )𝑽 𝑽̅̅𝟐 𝑶𝑴 𝟏 + 𝟎. 𝟖𝟔𝟐 (𝟓 𝐱 𝟏𝟎−𝟑 )𝟐 𝟎. 𝟒𝟓𝟑 𝟎. 𝟖𝟔(𝟓 𝐱 𝟏𝟎−𝟑 ) 𝟎. 𝟒𝟓𝟑 = 𝟗. 𝟖𝟏(𝟏𝟕𝟔𝟎 − 𝟗𝟖𝟓) ̅̅̅̅̅ Solving for 𝑉 𝑂𝑀 ̅ 𝑶𝑴 = 𝟎. 𝟎𝟑𝟖𝟒 𝒎/𝒔 𝑽 (ii) 𝑨= Estimate the diameter of the vertical cylindrical vessel 𝒎̇ ̅̅̅̅ 𝝆𝑽𝑶𝑴 𝟒𝟓𝟎𝟎𝟎 𝒌𝒈 𝟏 𝒉𝒓 𝒎𝟑 𝒔 𝑨= × × × 𝒉𝒓 𝟑𝟔𝟎𝟎𝒔 𝟗𝟖𝟓 𝒌𝒈 𝟎. 𝟎𝟑𝟖𝟒𝒎 𝑨 = 𝟎. 𝟑𝟑𝟎𝟓 𝒎𝟐 (Area of cylinder) 𝝅𝑫𝟐 𝑨= 𝟒 𝝅𝑫𝟐 𝟎. 𝟑𝟑𝟎𝟓 = 𝟒 𝑫 = 𝟎. 𝟔𝟓 𝒎 FLOW OF FLUID THROUGH GRANULAR BEDS (a) The specific surface area of particle (S) in one of the parameters affecting the pressure drop of the fluid flows through a granular beds or porous medium. In considering the effect of surface area, there is a difference between the specific surface or particle (S) and the specific surface area of bed (SB). Explain why these two parameters cannot be assumed similar. S and SB are not equal due to the voidage which is present when the particles are packed into a bed. (b) Adsorption process has been conducted in a packed column whereas air was subjected to flow through beds of granular activated carbon at 130 º C under the atmospheric pressure. A pore space which approximately 25% of granular bed form a channel like-tube with diameter of 5.56 x10-4 (L). Based on Carman-Kozeny, the pressure drop per length of the column is given by 1048.48 (Pa/m). Air properties at T= 130 º C, (interpolation from table appendix A.3.3) ρ = 0.8768 kg/m3 µ = 2.3020 x 10-5 kg/m.s or Pa.s ε = 0.25 de = 5.56 x10-4 m ∆𝒑 𝑳 = 𝟏𝟎𝟒𝟖. 𝟒𝟖 (𝐏𝐚/𝐦). i) Estimate the average size (Dp (m)) of the activated carbon granule packed in the column. 𝒅𝒆 = 𝟒𝜺 𝑺𝑩 𝟓. 𝟓𝟔 × 𝟏𝟎−𝟒 = 𝟒(𝟎. 𝟐𝟓) 𝑺𝑩 𝑺𝑩 = 𝟏𝟕𝟗𝟖. 𝟓𝟔𝟏𝟐 𝑺𝑩 = 𝑺 (𝟏 − 𝜺) 𝟏𝟕𝟗𝟖. 𝟓𝟔𝟏𝟐 = 𝑺 (𝟎. 𝟕𝟓) 𝑺 = 𝟐𝟑𝟗𝟖. 𝟎𝟖𝟏𝟔 𝑺= 𝟔 𝑫𝑷 𝟐𝟑𝟗𝟖. 𝟎𝟖𝟏𝟔 = 𝟔 𝑫𝑷 𝑫𝒑 = 𝟐. 𝟓𝟎𝟐 × 𝟏𝟎−𝟑 𝒎 (c) Calculate the Reynolds number of the gas flow through the column and state the types of flow occurred in the process. (𝟏 − 𝜺)𝟐 𝑺𝟐 ∆𝒑 ̅̅̅𝟎̅ =𝑲 𝝁𝑽 𝑳 𝜺𝟑 𝟏𝟎𝟒𝟖. 𝟒𝟖 = 𝟓 (𝟎. 𝟕𝟓)𝟐 𝟐𝟑𝟗𝟖. 𝟎𝟖𝟏𝟔𝟐 ̅𝟎 𝟐. 𝟑𝟎𝟐𝟎 × 𝟏𝟎−𝟓 𝑽 𝟎. 𝟐𝟓𝟑 ̅ 𝟎 = 𝟎. 𝟎𝟒𝟒 𝒎/𝒔 𝑽 𝑹𝒆 = ̅𝟎 𝝆𝑽 𝟎. 𝟖𝟕𝟔𝟖 (𝟎. 𝟎𝟒𝟒) = = 𝟎. 𝟗𝟑 𝑺(𝟏 − 𝜺)𝝁 𝟐𝟑𝟗𝟖. 𝟎𝟖𝟏𝟔 (𝟎. 𝟕𝟓)( 𝟐. 𝟑𝟎𝟐𝟎 × 𝟏𝟎−𝟓 ) Laminar flow because Re < 1