Science 20 Unit A Unit Test NAME:_____________________ DATE: _____________________ MARK: /45 % 1. When Calcium becomes an ion it a. Looses 2 electrons b. Gains 2 electrons c. Looses 2 protons d. Gains 2 protons GLO 1: explain how dissolving substances in water is often a prerequisite for chemical reactions and chemical changes; 2. Disassociation is a. The separation of molecular compounds into individual ions in a solution b. The separation of ionic compounds into individual ions in a solution c. The separation of molecular compounds into separate molecules in solution d. The separation of ionic compounds into separate molecules in solution 3. Disassociation is required for voltaic cells because a. There must be a supply of ions b. Metals cannot dissociate c. Nonmetals cannot dissociate d. There must be a supply of metals GLO 2: differentiate, on the basis of properties, between electrolytes and nonelectrolytes Use the following information to answer the next question 4. Which of the solutions above is a non-electrolyte? a. Solution 1 b. Solution 2 c. Solution 3 d. Solution 4 5. Na2SO2 is a/an ______i______ because it is a/an ________ii_______ solution The statement above are completed by the information in row Row A B C D i Electrolyte Electrolyte Nonelectrolyte Nonelectrolyte ii Ionic Molecular Ionic Molecular 6. Which of the following rows correctly completes the chart? Row A B C D Electrolyte H2O C6H12O6 NaCl NaOH Nonelectrolyte NO2 H2O KOH CO2 GLO 3: compare and explain how concentrations of solutions are expressed in moles per litre, percent by volume and parts per million Use the following information to answer the next question Numerical Response 1. Match each of the blanks numbered above with the data value to which it corresponds, as given below. Mass of ethanol (3.95 g) _____ (Record in the first column) Volume of ethanol (5.00 mL) _____ (Record in the second column) Mass of solution (2 495 g) _____ (Record in the third column) Volume of solution (2 495 mL) _____ (Record in the fourth column) (Record your answer in the numerical-response section on the answer sheet.) Use the following information for the next question 7. According to the information above the solvent is a. Flour b. Black pepper c. Sour cream d. Milk GLO 4: determine the concentration of solutions in moles per litre, percent by volume and parts per million Numerical Response 2. A mosquito repellent contains 65 ml of DEET in every 250 ml bottle. What is the percent by volume concentration of DEET in this repellent? ____ ____ ____ ____ (Record your answer in the numerical-response section on the answer sheet.) 8. A student takes 9.50g of potassium permanganate, KMnO4 (s), and dissolves it into 80.0 ml of water. How many moles of potassium permanganate are in the solution? a. 0.060 mol b. 0.119 mol c. 0.506 mol d. 8.421 mol 9. You dissolve 37.0g of sodium sulphate, NaCl (s) into 350 ml of water. What is the concentration of the solution? a. 0.11 mol/L b. 1.81 mol/L c. 6.17 mol/L d. 105.7 mol/L 10. A hair product requires you to make a solution of hydrogen peroxide and water. If you need 400 ml of hydrogen peroxide for every 350 ml of water what is the % by volume concentration? a. 13% b. 53% c. 88% d. 114% 11. A 250g bottle of water contains 3.5 x 10-3g of mercury. What is the concentration of mercury in parts per million? a. 0.014 ppm b. 14 ppm c. 52 ppm d. 71 ppm 12. You put 6.5 mol of KOH into 5.4L of water. What is the concentration of this solution? a. 0.01 mol/L b. 0.02 mol/L c. 0.83 mol/L d. 1.20 mol/L GLO 5: determine the concentration of diluted solutions and the quantities of a concentrated solution and of water to use when diluting. 13. A chemical procedure requires 100 mL of 1.25 mol/L sulfuric acid. If a stock solution of sulfuric acid with a molar concentration of 6.00 mol/L is available, then the volume of the stock solution that must be diluted is a. 7.50 mL b. 20.8 mL c. 48.0 mL d. 1.25 mL 14. A large beaker contains 655 ml of a standard solution of sulphuric acid with a concentration of 10.0 mol/L. this beaker is placed in the fume hood where evaporation can occur. Determine the amount of water that would have to evaporate in order for the solution to have a concentration of 11.5 mol/L a. 98 ml b. 85 ml c. 570 ml d. 753 ml GLO 6: balance provided single-replacement reaction equations, building on knowledge from Science 10, Unit A 15. The coefficients to balance the following reaction are respectfully __ Ag2S + __ Al __Ag + __Al2S3 a. 3,2,6,1 b. 3,2,6,2 c. 6,4,6,2 d. 9,4,6,3 16. The coefficients to balance the following reaction are respectfully __ AlBr3 + __ Cl2 __AlCl3 + __Br2 a. 2,2,1,2 b. 3,3,1,3 c. 2,3,2,3 d. 4,4,3,4 GLO 7: determine the reactivity of metals by comparing their reaction in various aqueous solutions 17. An acid containing Hydrogen ions is poured over 3 metal strips. Which of the following would produce the largest reaction? a. Lead b. Copper c. Zinc d. They would all produce the same type of reaction 18. You have an aluminum boat which you launch into an unknown lake. Once it is in the water you notice a chemical reaction occurring on the surface where your boat touches the water. You see a nearby sign indicating that the lake contains high concentrations of sodium, iron, calcium and zinc ions. Based on this information you know your boat is reacting with the a. Sodium ions b. Iron ions c. Calcium ions d. Zinc ions GLO 8: relate single-replacement reactions to oxidation-reduction and apply mole ratios from given equations to predict moles of metals consumed or produced 19. 2 mol of nickel react in the following reaction. 2 AgNO3 + Ni Ni(NO3)2+ 2 Ag How many moles of silver are produced? a. 1 b. 2 c. 3 d. 4 20. 16 mol of Oxygen gas is consumed in the following reaction 2 C4H10 + 13 O2 8 CO2 + 10 H2O How many moles of C4H10 is also consumed? a. 16 mol b. 8.0 mol c. 2.5 mol d. 1.2 mol 21. You create the following voltaic cell Ag|Ag+||Sn2+|Sn If 1.6 mol of Sn are consumed by the cell, how many moles of Ag are produced? a. 0.8 mol b. 1.6 mol c. 3.2 mol d. 4.8 mol GLO 9: define, operationally, oxidation and reduction and spontaneous and nonspontaneous reactions; 22. A metal atom loses electrons. In effect it is said to be a. Oxidized b. Reduced 23. A sodium ion is plated onto a cathode. According to this information Sodium is undergoing a. Oxidation reaction b. Reduction reaction 24. A metal rod is placed into a solution containing metal ions. A student touches it and receives a small electric shock. According to this information the reaction is a. Spontaneous b. Nonspontaneous 25. A nickel rod is placed into a solution containing Cu2+. According to this information the reaction would be a. Spontaneous b. Nonspontaneous Use the following information to answer the next Question 26. As depicted on the activity series, a mercury(II) ion must i electrons in order to be converted to the mercury atom. In addition, their position on the activity series indicates that a mercury(II) ion is ii reactive than a mercury atom The statements above are completed by the information in row Row A B C D i Gain Gain Lose Lose ii More Less More Less GLO 10: apply the principles of oxidation-reduction and half-reactions to describe, in general terms, the operation of voltaic and electrolytic cells; reaction equations; Use the following information to answer the next question 27. You create the following voltaic cell Zn2+|Zn||Mg|Mg2+ Which letter indicates the position of Zn? a. A b. B c. C d. D Use the following information to answer the next question 28. Assuming that there are copper ions in the beaker with the copper strip and zinc ions in the beaker with the zinc strip. The copper electrode is the _____i_____ and the electrons flow _____ii_____ The statements above are completed by the information in row Row A B C D i Cathode Anode Cathode Anode ii Left to right Left to right Right to left Right to left Use the following information to answer the next question Numerical Response 3. Match four of the parts of the cell numbered above with the correct descriptions as given below. Reactant that gains electrons _____ (Record in the first column) Structure that enables ions to move within the cell _____ (Record in the second column) Structure that enables electrons to move _____ (Record in the third column) Cathode (positive electrode) _____ (Record in the fourth column) (Record your answer in the numerical-response section on the answer sheet.) Use the Following information to answer the next question Numerical Response 4. Voltaic and electrolytic cells have similar and unique aspects. Match each of the characteristics of electrochemical reactions shown above to its corresponding description as given below. Characteristic that is unique to _____ (Record in the first column) a voltaic cell Characteristic that is unique to _____ (Record in the second column) an electrolytic cell Characteristic that is common _____ (Record in the third column) to both voltaic and electrolytic cells Characteristic that is common _____ (Record in the fourth column) to both voltaic and electrolytic cells (Record your answer in the numerical-response section on the answer sheet.) GLO 11: compare modern and traditional methods for the extraction of metals and for protection from corrosion; 29. In order to purify copper metal in order to make copper wire. Which of the following is true a. A voltaic cell is used b. An electrolytic cell is used c. A polar cell is used d. None of the above GLO 12: identify materials used in daily life that are based upon Alberta’s petrochemical industry and that involve changes in energy; 30. Which of the following are created using petrochemicals? a. Fleece jackets b. Cosmetics c. Plastic bags d. All of the above GLO 13: identify the physical characteristics of hydrocarbons, including trends with respect to melting and boiling points and solubility of alkanes, alkenes and alkynes 31. You are given two samples one you are told is an alkane the other is an alkyne. In order to identify them you boil the two substances and find that substance A has a lower boiling point than substance B. According to this information you know a. Substance A is the Alkane b. Substance B is the Alkane 32. You are given two samples of Alkanes. At room temperature substance C is a solid and Substance D is a liquid. Based on this information you know a. Substance C has fewer carbons than substance D b. Substance D has fewer carbons than substance D GLO 14: provide International Union of Pure and Applied Chemistry (IUPAC) names and structural formulas for simple and noncyclic hydrocarbons in the homologous series of alkanes, alkenes and alkynes that contain up to eight carbon atoms in the parent chain 33. Given the formula C8H14 you know that this molecule is a a. Alkane b. Alkene c. Alkyne d. None of the above 34. Given the formula C6H12 you know that it is an ______i______ and also considered ______ii______ The statements above are completed by the information in row Row A B C D i Alkane Alkene Alkane Alkene ii Saturated Saturated Unsaturated Unsaturated Use the following picture for the next question 35. The name for the molecule depicted above is a. Hexane b. Hexene c. Hexyne Use the following picture for the next question 36. The name for the molecule depicted above is a. 2,4,4-methylpentane b. 2,4,4-trimethylpentane c. 2,2,4-methylpentane d. 2,2,4-trimethylpentane Use the following picture for the next question 37. The name for the molecule depicted above is a. 3,3-ethyl-4-hexyne b. 3,3-ethyl-2-hexyne c. 3,3-diethyl-4-hexyne d. 3,3-diethyl-2-hexyne Use the following picture for the next question 38. The name for the molecule depicted above is a. octane b. 4-ethylhexane c. 3-ethylhexane d. 2-ethyloctene GLO 15: identify hydrocarbons as a source of fossil fuels and explain the processes of fractional distillation to refine petroleum and catalytic cracking to produce ethene (ethylene) Use the following diagram to answer the next question 39. Which of the following Hydrocarbons would be present at the bottom of the distillation tower? a. C2H6 b. C4H8 c. C6H10 d. C8H18 GLO 16: classify, balance and apply mole ratios to important hydrocarbon reactions: Use the following information to answer the next question 40. When the equation above is balanced using whole-number coefficients, the coefficients for propane, oxygen, carbon dioxide, and water are, respectively, a. 1, 3, 4, and 5 b. 2, 5, 3, and 8 c. 1, 5, 3, and 4 d. 2, 3, 8, and 5 Use the following information to answer the next question Numerical Response 5. Match each of the unbalanced equations numbered above with its reaction type listed below. Hydrocarbon combustion _____ (Record in the first column) Catalytic cracking _____ (Record in the second column) Polymerization _____ (Record in the third column) Hydrogenation _____ (Record in the fourth column)