5.10 Molecular Compoundsfill

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Molecular Compounds- Covalent Bonding

Molecular compounds are created when two or more unstable non-metals chemically react with each other to obtain stable valence shells. It is easier for non-metals to gain valence electrons to obtain a full valence shell since they have at least 4,5,6 or 7. When two _______________react, both want to have full valence shells but neither want to donate valence electrons. The only happy medium is if both______ the valence electrons they have amongst each other.

The type of chemical bond that exists through sharing of valence electrons between ____________ is called a _____________________.

Because there is no exchange of valence electrons, only sharing, no ions are formed (no criss-

cross rule)

 valence electrons shared between the two non-metals

Lets show this bonding using Bohr-Rutherford diagrams

* remember: the number of valence electrons an atoms has lets you know how many it needs to obtain a full valence shell.

Properties: They are 3-D compounds that can be solids, liquids or gases. They have low melting points and boiling points compared to ionic compounds. Most do not easily dissolve in water. They do not conduct electricity when dissolved in water.

Diatomic Compounds

Some elements are too reactive (unstable) to exist on their own

 these elements are non-metals and will combine with themselves by sharing valence electrons so each can have full valence shells (full octet)

 the following elements always form diatomic compounds when they are combining with other elements

HOFBrICl

Element

Hydrogen

Oxygen

Fluorine

Bromine

Iodine

Nitrogen

Chlorine

Chemical Formula

Naming molecular compounds-use prefixes

Some molecular compounds are always known by their common name

H

2

O -____________

NH

3

- ____________

H

2

O

2

-____________

CH

4

-_____________

Most molecular compounds are named using a prefix system

 prefixes are used to indicate the number of atoms in the compound (no criss-cross rule)

 the prefix is placed in front of the name of the element you are emphasizing

1.

The atom closest to the bottom left corner of the periodic table is named first.

2.

The atom closest to the top right is named second.

Prefix

Mono

Di

Tri

Tetra

Penta

Hexa

Number

1

2

3

4

5

6 ex As

2

O

3

Both are non-metals, therefore we use prefixes: diarsenic trioxide

SIO

2

NO

2

N

2

SiH

4

PCl

P

2

S

3

3

Li

2

O

Writing Formulas for Molecular Compounds

The prefixes used tell you exacty the number of atoms in the formula

There are no ions and no criss-cross rule used ex. diphosphorus pentoxide

2- phosphorus 5-oxygens : P

2

O

5

Carbon tetrabromide

Diboron trioxide

Dinotrogen monixide

Iodine hexafuoride

Oxygen

Carbon terahydride

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