COURSE SYLLABUS, SUMMER 2015 Tulsa Community College, SEC Campus CHEM 2145 - Organic Chemistry I INSTRUCTOR: William T. Briscoe, Ph.D. CHEM 2145-301 30368 Lecture: Recitation Lab: TR MW MW 8:00—10:50 11:30—12:20 12:30— 2:20 SE 8179 SE 8276 SE 8276 CHEM 2145-302 30369 Lecture: Recitation Lab: TR TR TR 8:00—10:50 11:30—12:20 12:30— 2:20 SE 8179 SE 8276 SE 8276 Science and Mathematics Division Instructor: William T. Briscoe, Ph.D. Office: SE 8265 Phone No.: 595-7680 e-mail: bill.briscoe@tulsacc.edu Science and Mathematics Division Associate Dean: Lyn Kent Office: SE 8125 Phone No.: 595-7742 OFFICE HOURS MTWR: 2:30-4:00 or by appointment COURSE PREREQUISITE: Organic Chemistry I is the first of two courses that cover the fundamental concepts of the chemistry of the compounds of carbon. See listings in the TCC catalog for other chemistry courses. This course has a pre-requisite of completion of Chemistry II (CHE 1415) with a “C” or better. COURSE DESCRIPTION Organic Chemistry I is a study of functional concepts of organic structure and bonding, reactions of principle functional groups, mechanisms, and nomenclature of hydrocarbons and their derivatives. Laboratory emphasis is on purification, separation, synthesis and instrumental methods of studying organic systems. Lecture: 3 hours. Recitation: 1 hour. Laboratory: 2 hours. NEXT COUSE IN SEQUENCE Organic Chemistry II (CHE 2245) TEXTBOOK AND OTHER MATERIALS Organic Chemistry, 11eth edition, 2014, T.W. Graham Solomons, Craig B. Fryhle & Scott Snyder John Wiley & Sons - Pub. Organic Chemistry Laboratory Experiments for Tulsa Community College Stapler with which to staple homework papers and lab reports together Safety Goggles and Lab Apron: are to be worn in the laboratory at all times!!!!! They are available in the TCC bookstore. flash drive Optional Materials: Study Guide to Solomons Organic Chemistry Molecular Model Set for Organic Chemistry, Molymod, Prentice Hall Organic Chemistry Nomenclature Study Cards, Vis-Ed Organic Chemistry Reactions Summary Cards, Vis-Ed Organic Chemistry Study Cards, Van DeGraaff, Morton Pub Co. COURSE WITHDRAWAL The deadline to withdraw from a course shall not exceed 3/4 the duration of any class. Contact the Counseling Office at any TCC campus to initiate withdrawal from a course ('W' grade) or to change from Credit to Audit. Check the TCC Academic Calendar for deadlines. It is the responsibility of the student to do this. Students who stop participating in the course and fail to withdraw may receive a course grade of “F,” which may have financial aid consequences for the student. COMMUNICATIONS Email communications: All TCC students receive a designated “MyTCC” email address (ex: jane.doe@mail.tulsacc.edu). All communications to you about TCC and course assignments will be sent to your MyTCC email address; and you must use MyTCC email to send email to, and receive email from, the instructor regarding this course. Inclement Weather: TCC rarely closes. If extreme weather conditions or emergency situations arise, TCC always gives cancellation notices to radio and television stations. This information is also posted on the TCC website (www.tulsacc.edu). GENERAL EDUCATION GOAL STATEMENT The General Education Goals are designed to ensure that graduates of Tulsa Community College have the skills, knowledge, and attitudes to carry them successfully through their work and their personal lives. General Education Goals relevant to this course include Critical Thinking, Effective Communication, Civic Responsibility, and Computer Proficiency. CLASSROOM ETIQUETTE Open and mutually respectful communication of varied opinions, beliefs, and perspectives during classroom or online discussion encourages the free exchange of ideas that is essential to higher learning and to the ability to learn from each other. Use of any electronic device is at the discretion of the instructor. SYLLABUS CHANGES Occasionally, changes to the syllabus may be necessary. Students will be notified of any changes to the syllabus in class. STUDENTS WITH DISABILITIES TCC provides accommodations for qualifying students in compliance with the Americans with Disabilities Act. For information, students may contact the disabled Student Resource Center, 918-595-7115, or the Resource Center for the Deaf and Hard of Hearing, 918-595-7428V, 918-595-7434TTY. ACADEMIC DISHONESTY Academic dishonesty (cheating) is defined as the deception of others about one’s own work or about the work of another. Academic dishonesty or misconduct is not condoned or tolerated at campuses within the Tulsa Community College system. Tulsa Community College adopts a policy delegating certain forms of authority for disciplinary action to the faculty. Such disciplinary actions delegated to the faculty include, but are not limited to, the dismissal of disrespectful or disorderly students from classes. In the case of academic dishonesty a faculty member may: require the student to redo an assignment or test, or require the student to complete a substitute assignment or test; Record a "zero" for the assignment or test in question; Recommend to the student that the student withdraw from the class, or administratively withdraw the student from the class; Record a grade of "F" for the student at the end of the semester. Faculty may request that disciplinary action be taken against a student at the administrative level by submitting such request to the Dean of Student Services. Institutional Statement: Each student is responsible for being aware of the information contained in the TCC Catalog, the TCC Student Policies & Resources Handbook, and semester information listed in the class schedule. All information may be viewed on the TCC website: www.tulsacc.edu LEARNING SUPPORT SERVICES AND COMPUTER ASSISTED INSTRUCTION A complete set of computer programs for this General Chemistry text is available for use in the Math Lab, SE 8150. A variety of CD-Rom tutorials are available for purchase in the bookstore to aid in studying. The tutorials are extremely helpful in preparing for class and exams. Access to computing resources is a privilege granted to all TCC faculty, staff, and students. Use of TCC computing resources is limited to purposes related to the College’s mission of education, research, and community service. Student use of technology is governed by the Computer Services Acceptable Use Statements/Standards found in the TCC Student Code of Conduct Policy Handbook. These handbooks may be obtained by contacting any Student Activities or Dean of Student Services office. COURSE OBJECTIVES Chemistry is divided between theoretical and practical knowledge. This course will deal with the fundamental laws and theories that interrelate chemical and physical properties of organic compounds. The terminology and vocabulary used by the chemist will be developed and applied. The technique for solving quantitative problems relating to chemistry will be presented. Since the problems in chemistry are many and varied, an objective of this class is to develop the ability to study independently. The student will learn reactions and mechanisms necessary for the mastery of organic chemistry and will learn to synthesize, separate, purify and identify organic compounds. During the laboratory sessions the student will have the opportunity to perform simple laboratory procedures and practice safe handling of laboratory chemicals and equipment. During the first laboratory session a list of safety rules will be presented and discussed. Strict precautions and guidelines must be followed in the lab. PROFESSIONALISM: It is assumed that students enrolling in a course at this level are headed toward a professional career. Because prospective future employers, clients, patients, and admissions committees will make decisions of your future association with them based on, among other things, your reputation of projecting a professional image, it is important to be projecting that image now. A professional image includes such character traits as attendance, punctuality, thoroughness, attentiveness, attitude toward authority, honesty, and appearance (dress and grooming). ATTENDANCE POLICY Attendance is mandatory. Class participation and attendance will be included in the grading procedure. Absences not only deprive you of opportunity to gain understanding of the subject necessary to perform well in this class, but excessive absences can also reduce your participation portion of the grade. Absences of more than 10% of the lectures and/or 2 laboratory sessions is considered excessive. If you anticipate absences beyond these amounts, you may want to consider withdrawing from this course at this time. INSTITUTIONAL STATEMENT Each student is responsible for being aware of the information contained in the TCC Catalog, TCC Student handbook, TCC Student Code of Conduct Policy Handbook, and semester information listed in the Class Schedule. STUDENT CODE OF CONDUCT All policies and procedures will be followed by the enrolled student. No phones or pagers allowed in the lecture. In the programmable calculators, no equations may be stored in its memory during testing. PLAGIARISM POLICY Plagiarism is claiming, indicating, or implying that the ideas, sentences, or words of another writer are your own; it includes having another writer do work claimed to be your own, copying the work of another and presenting it as your own, or following the work of another as a guide to ideas and expression that are then presented as your own. This includes copying another’s homework. The student should review the relevant sections of the TCC Student Code of Conduct Policy Handbook. TEACHING METHODS All lecture and laboratory material must be read prior to class presentation or laboratory period. Problems from the textbook should be worked. Specific problems may be assigned to be handed in for grading. EVALUATION TECHNIQUES A. Tests - Four (4) 115 points each. The examinations will cover the lecture material and all the material in the assigned chapters in the textbook. The exact formats will be explained in class. 1. No make-up tests will be given, unless in case of extreme emergency and at the discretion of the instructor (my phone number and e-mail address in at the first of this syllabus). If you miss a scheduled exam for a legitimate reason, it is your responsibility to contact me within one school day to arrange to take the exam. In the event of a make-up exam, the exam will be available to be taken during normal operating hours in the Math Lab Testing Center and should be taken within 1 day of the student’s return to class. 2. The final exam is mandatory and CANNOT be made up. B. Laboratory 1. Laboratory work will be completed during the assigned laboratory period. It is very highly recommended that all laboratory notes and data be recorded in ink, in a notebook, not on 2. 3. 4. 5. scraps of paper. The lab procedure should be studied prior to coming to lab. A typed lab report in standard laboratory format will be handed in for grading within 7 calendar days of completion of a lab. Included in the grade will be an evaluation of laboratory practices, safety habits, overall effort and lab write-up. The last lab reports are due before final exam. Late lab reports will NOT be accepted. Laboratory experiments cannot be made up. An absence during one of the lab periods will result in the forfeit of all points associated with that laboratory exercise. Students are advised to exercise extreme caution in the laboratory and to follow all guidelines listed on the "Safe Lab Practices" handout. Students MUST purchase and wear goggles and a lab apron during labs. Students NOT wearing the above will NOT be allowed to participate in the laboratory and will forfeit all points associated with that laboratory exercise. C. Homework 1. Specific homework problems from the text will be assigned throughout the course. These problems will aid the student in obtaining a thorough understanding of the material. D. Late Work 1. Late homework and labs will be accepted up to one week after the scheduled turn-in date at a 10% reduction in grade, up to two weeks with a 25% reduction in grade, but not accepted after the final exam. Late homework due to excused absence on the date due may be turned in on the next class day attended without penalty. The instructor may waive penalties for valid extenuating circumstances at his sole discretion. No work will be accepted after the last day of classes. GRADING SYSTEM Exam Grades (4 @ 115 pts. ea.) Homework (11 @ 8-10 pts. ea.) Laboratory Reports (best 10 @ 30 pts. ea.) Professionalism (40 pts.) Final exam (100 pts.—mandatory) GRADING SCALE 90 -100% 80 - 89% 70 - 79% 60 - 69% Below 60% = = = = = 460 points 100 points 300 points 40 points 100 points 1000 points A B C D F Homework Assignments: HW Chapter 1: 8ceh(pg 11),18ab, 21bc, 27cdfh, 29gh, 30ad, 33b, 34b, 35abcegjmop, 36d, 37 HW Chapter 2: 9, 10, 18b, 29abcd, 30b, 34abcdef, 35, 42, 43abcdij, 46ceg HW Chapter 3: 5abdf, 4, 11, 18abef, 19abef, 20abdf, 22a, 32ab, 33ab, 35abce HW Chapter 4: 5a, 6a, 7a, 8d, 9be, 10bf, 11bi, 16, 23dghn, 24cfh, 28, 35, 39, 43 HW Chapter 5: 4bd, 6, 11, 12, 13, 19, 27, 29, 30 HW Chapter 6: 3bc, 8, 14, 16, 19a, 20ab, 21ad, 22abd, 23cg, 27, 28aij, 32, 33abdefh HW Chapter 7: 26adhl, 27a, 28cf, 30c, 31b, 32de, 38, 40 HW Chapter 8: 17bc, 20a, 22ac, 24, 26, 39cd, 40cd HW Chapter 10: 4, 8, 10ab, 29abe HW Chapter 11: 2a, 3c, 7, 8c, 12, 13b, 19a, 25bf, 26a, 29, 34, 35 HW Chapter 12: 1, 3abc, 5, 13abcdfghi, 14 TENTATIVE LECTURE & LABORATORY SCHEDULE CHE 2145 SUMMER 2015 ½ WEEK OF: READING ASSIGNMENTS Jun. Jun. Jun. Jun. Jun. 2 4 9 11 16 Ch. 1 Ch. 2 Ch. 2/3 Ch. 3/4 EXAM 1 Carbon Compounds and Chemical Bonds Representative Carbon Compounds: Functional Groups Functional Groups (cont.)/ Organic Reactions: Acids and Bases Organic Reactions: Acids and Bases (cont.)/Alkanes Ch. 1-3 Jun. Jun. Jun. Jun. Jun. 16 18 23 25 30 Ch. 4 Ch. 5 Ch. 5/6 Ch. 6/7 EXAM 2 Alkanes: Conformational Analysis, intro to Synthesis Alkanes: Conformational Analysis/ Stereochemistry Stereochemistry/ Ionic Reactions—Nucleophilic Substitution Ionic Reactions--Nucleophilic Substitution and Elimination/Alkenes Ch. 4-6 Jun. 30 Jul. 2 Ch. 7 Ch. 7 Alkenes & Alkynes I: Properties & Synthesis; Elimination Rxns. Alkenes & Alkynes I: Properties & Synthesis; Elimination Rxns. Jul. 7 Jul. 9 Jul. 14 Jul. 16 Ch. 8 Ch. 8 Ch. 8/10 EXAM 3 Alkenes & Alkynes II: Properties & Synthesis; Elimination Rxns. Alkenes & Alkynes II: Addition Rxns. Alkenes & Alkynes II: Addition Rxns./ Radical Reactions Ch. 7-8 Jul. 16 Jul. 21 Jul. 23 Ch. 11 Ch. 12 EXAM 4 Alcohols & Ethers Alcohols & Ethers Ch. 10-12 Jul. 23 FINAL EXAM Tentative Laboratory Schedule—Summer 2015 DATE LABORATORY EXPERIMENT Jun. 2 Jun. Jun. Jun. Jun. Jun. Jun. Jun. Jun. Jul. Jul. Jul. Jul. Jul. Jul. 4 9 11 16 18 23 25 30 2 7 9 14 16 21 PAGE NUMBER Safety Film/lab notebooks & reports p 3-5 Physical Properties-Exp. 1 p 6 Two-Component Mixture-Exp. 2 p 10 Solvent Extraction-Exp. 3 p 12 Infrared Spectroscopy-Exp. 4 p 15 Isolation of Caffeine-Exp. 5 p 17 Specific Rotation-Group experiment-Exp. 8 p 30 Separation of Acidic, Basic and Neutral Cmpd-Exp. 6. p 20 Separation of Acidic, Basic and Neutral Cmpd-cont p 20 Open-Column Chromatography-Exp. 7 p 27 INDEPENDENCE DAY—no labs SN2 Reaction of 1-Octanol-Exp. 9 p 32 SN1 Reaction of t-Pentyl Alcohol-Exp. 10 p 35 Acid Catalyzed Dehydration of 2-Octanol-Exp. 11 p 38 Synthesis of 2-Bromooctane-Exp. 13 p 45 Synthesis of 2-Bromooctane-Exp. 13(cont) p 45