Chemistry First Semester Study Guide 1. Circle which of the following are pure substances: bread dough, vinegar (5% acetic acid), vitamin C (ascorbic acid), sea water, air, gasoline, stainless steel, silver. 2. Which groups from the periodic table contain only metals? _____________________________________________ 3. What is similar about elements in the same group? ______________________________________________________ 4. Which elements are very unreactive? ______________________________________________________________________ 5. What are the properties of metals? ________________________________________________________________________ 6. What are some physical properties of water? ____________________________________________________________ 7. Circle which of the following are physical properties: color, odor, melting point, boiling point, malleability, hardness. 8. Describe the composition of a compound and describe how compounds are separated. _________________________________________________________________________________________________________________ 9. Compare/contrast properties of compounds to their component elements. ___________________________ 10. What distinguishes a substance from a mixture? _________________________________________________________ 11. If 4 g of element A combine with 10 g of element B, then 12 g of element A combine with _________ g of element B. 12. In oxides of nitrogen, atoms combine in small whole-number ratios supporting the law of _______________________________________________________________________________________________________. 13. According to the law of definite proportions, any two samples of a compound have __________________ _________________________________________________________________________________________________________________ 14. The principles of atomic theory recognized today were conceived by _________________________________. 15. What does Dalton’s atomic theory state? __________________________________________________________________ _________________________________________________________________________________________________________________ _________________________________________________________________________________________________________________ 16. How does the present atomic theory disagree with Dalton’s theory? ___________________________________ _________________________________________________________________________________________________________________ 17. Experiments with cathode rays led to the discovery of the ______________________________________________. 18. Rutherford’s experiments led to the discovery of the ____________________________________________________. 19. What did Rutherford conclude about the structure of the atom? ________________________________________ _________________________________________________________________________________________________________________ 20. A nuclear particle that has about the same mass as a proton, but with no electrical charge, is called a(n) __________________________________________________. 21. Which part of an atom has a mass approximately equal to 1/2000 of the mass of a common hydrogen atom? ____________________________________ 22. Chlorine has atomic number 17 and mass number 35. it has __________ protons, ___________ electrons, and _____________ neutrons. 23. According to the particle model of light, certain kinds of light cannot eject electrons from metals because ______________________________________________________________________________________________________. 24. What phenomenon was the wave model of light unable to explain? ___________________________________ 25. The Bohr model of the atom was an attempt to explain hydrogen’s ___________________________________. 26. According to Bohr’s theory, what would an excited atom do? ___________________________________________ 27. How did Bohr’s model describe the location of the electrons? __________________________________________ 28. How did the quantum theory describe the location of electrons? _______________________________________ 29. What did de Broglie’s research suggest? ___________________________________________________________________ 30. Which model of the atom explains the orbitals of electrons as waves? _________________________________ 31. What is the significance of both the Heisenberg uncertainty principle and the Schrodinger wave equation? _____________________________________________________________________________________________________ 32. An atom with atomic number 50 and mass number 125 has ___________ protons, ___________ electrons, and _____________ neutrons. 33. Compare and contrast protons, neutrons, and electrons. ________________________________________________ _________________________________________________________________________________________________________________ 34. What is necessary to calculate the atomic mass of an element? _________________________________________ _________________________________________________________________________________________________________________ 35. Which scientist developed the quantum mechanical model of the atom? ______________________________ 36. in the modern periodic table, elements are ordered according to ______________________________________. 37. Elements to the right side of the periodic table (p-block) have properties most associated with ___________________________________________________. 38. Elements in which the d-sublevel is being filled have properties of ___________________________________. 39. The elements that border the zigzag line in the periodic table are ____________________________________. 40. Within the p-block, the elements at the top of the table compared with those at the bottom have _______________________ radii, ______________________ ionization energies, and are ________________ metallic. 41. In nature, alkali metals occur as ________________________________________________. 42. The most reactive group of the nonmetals are the _______________________________________________________. 43. Compared to the alkali metals, the alkaline earth metals are __________________ reactive, _______________ dense, have __________________ melting points, and combine ________________ readily with nonmetals. 44. The element that has the greatest electronegativity is __________________________________________________. 45. In a row in the periodic table, as the atomic number increases the atomic radius generally _________. 46. Within a group, as the atomic number increases the atomic radius ____________________________________. 47. In the alkaline earth group, atoms with the smallest radii are the ________________ reactive, have the ________________________ volume, and have the ________________________ ionization energies. 48. Describe the force of attraction by group 1 metals for their valence electrons. _______________________ 49. As with main group elements, ionization energies of d-block elements generally ____________________ across a period. 50. Which groups have lower electronegativity than d-block elements? __________________________________ 51. To draw a Lewis structure, one must know the _________________________________________________________. 52. Compared with ionic compounds, molecular compounds have ______________________ boiling points, are ________________ brittle, have _____________________ melting points, and are harder/softer. 53. Compared with nonmetals, the number of valence electrons in metals is generally _________________. 54. Use VSEPR theory to predict the shape of the CI4 molecule. ____________________________________________ 55. Use the VSEPR theory to predict the shape of H2S. _______________________________________________________ 56. Use the VSEPR theory to predict the shape of CO2. _______________________________________________________ 57. The strong forces of attraction between the positive and negative regions of molecules are called _______________________________________________________________________________________________________________. 58. The intermolecular attraction between a hydrogen atom bonded to a strongly electronegative atom and the unshared pair of electrons on another strongly electronegative atom is called _________________________________________________________________. 59. The weak intermolecular forces resulting from instantaneous and induced dipoles are called _________________________________________________________________. 60. That the boiling point of water is higher than the boiling point of hydrogen sulfide is partially explained by ____________________________________________________________________________________________. 61. Which of the following molecules is/are nonpolar? HCl, H2O, CO2, NH3 62. Why does ICl have a higher boiling point than bromine? ________________________________________________ 63. What is the electron configuration of the calcium atom? ________________________________________________ 64. What is the electron configuration of the iodide ion? ____________________________________________________ 65. Write the balanced equation for the reaction between zinc hydroxide and acetic acid. _________________________________________________________________________________________________________________ 66. The reaction 2Mg + O2 2MgO is a _____________________________________________________________ reaction. 67. The reaction Mg + 2HCl H2 + MgCl2 is a ______________________________________________________ reaction. 68. The reaction 2HgO 2Hg + O2 is a _____________________________________________________________ reaction. 69. The reaction Pb(NO3)2 + 2KI PbI2 + 2KNO3 is a _____________________________________________ reaction. 70. Write the formulas for the products of the reaction between sodium hydroxide and sulfuric acid. ________________________________________________________________________________________________________________ 71. Write the balanced equation when aluminum reacts with copper (II) sulfate. ________________________________________________________________________________________________________________ 72. Predict what happens when calcium metal is added to a solution of magnesium chloride. ________________________________________________________________________________________________________________ 73. Predict what happens when lead is added to nitric acid. _________________________________________________ 74. Predict what happens when nickel is added to a solution of potassium chloride. _________________________________________________________________________________________________________________ 75. Magnesium bromide + chlorine yield ______________________________________________________________________ 76. Which of the following reactions do not occur? 2HF + Cl2 F2 + 2HCl, 2Na + ZnF2 2NaF + Zn, Fe + CuCl2 FeCl2 + Cu, 2HCl + Mg MgCl2 + H2 77. What are the weakest attractions between molecules? __________________________________________________ 78. According to the kinetic molecular theory, particles of matter are in motion in what states? _________________________________________________________________________________________________________ 79. The equation 2C3H7OH + 9O2 6CO2 + 8H2O is an example of a ________________________________________ reaction. 80. Compare and contrast the particles in liquids and gases. ________________________________________________ _________________________________________________________________________________________________________________ 81. Describe the particles within a solid. ______________________________________________________________________ 82. Contrast the intermolecular forces between particles in solids, liquids, and gases. ___________________ _________________________________________________________________________________________________________________ 83. When solutions of barium carbonate and iron (III) sulfate are combined, what precipitate(s) form? _________________________________________________________________________________________________________________ 84. When solutions of NH4OH and K2SO4 are combined, what precipitate(s) form? _______________________ 85. In the reaction 2K + Br2 2K+ + 2Br-, which species is reduced? _______________________________________ 86. In the reaction F2 + Mg 2F- + Mg2+, which species is oxidized? _______________________________________ 87. Which of the following are oxidation-reduction reactions? H2O + SO2 H2SO3, N2 + O2 2NO, H2 + Cl2 2HCl, 2NaBr + Cl2 2NaCl + Br2 88. What is the reducing agent in the reaction 2Na + 2H2O 2NaOH + H2? _______________________________ 89. What is the oxidizing agent in the reaction CH4 + 2O2 CO2 + H2O? ___________________________________ 90. In the unbalanced reaction H2O + Cl2 + SO2 HCl + H2SO4, which atom is reduced? _________________ 91. In the unbalanced reaction HNO3 + HBr NO + Br2 + H2O, which atom is oxidized? ________________ 92. Balance the equation 226 Rn 222 Ra + __________________ 93. Balance the equation 238 U + _______________ 239 U. 94. Write the equation showing beta decay of neptunium-239. _____________________________________________ 95. What form of nuclear radiation has the greatest penetrating power? __________________________________ 96. List the forms of nuclear radiation from most to least massive. ________________________________________ 97. What is the half-life of an isotope if 125 g of a 500 g sample of the isotope remains after 3.0 years? __________________________________________________ 98. What particle is emitted in alpha radiation? _____________________________________________________________ 99. What is a beta particle? ____________________________________________________________________________________