Page 1 Name Chemistry 2 Standard Set 2 deals with two distinct topics: chemical bonds and intermolecular attractive forces, such as hydrogen bonds. A logical place to begin the study of this standard is with a discussion of the chemical bond. A key point to emphasize is that when atoms of two different elements join to form a covalent bond, energy is almost always released. Conversely, breaking bonds always requires the addition of energy. Students should understand that the sum of these two processes determines the net energy released or absorbed in a chemical reaction. This standard set requires a basic knowledge of electrostatics and electro-negativity and a thorough knowledge of the periodic table. After studying standards for chemistry for the elementary grades, students should know that matter is made of atoms and that atoms combine to form molecules. Students can also be expected to know that atoms consist of protons, neutrons, and electrons. Although knowledge of complex mathematics is not required for this standard, some background in three-dimensional geometry will be helpful. CH 2. Biological, chemical, and physical properties of matter result from the ability of atoms to form bonds from electrostatic forces between electrons and protons and between atoms and molecules. As a basis for understanding this concept: Standard CH 2. a. Students know atoms combine to form molecules by sharing electrons to form covalent or metallic bonds or by exchanging electrons to form ionic bonds. Framework In the localized electron model, a covalent bond appears as a shared pair of electrons contained in a region of overlap between two atomic orbitals. Atoms (usually nonmetals) of similar electronegativities can form covalent bonds to become molecules. In a covalent bond, therefore, bonding electron pairs are localized in the region between the bonded atoms. In metals valence electrons are not localized to individual atoms but are free to move to temporarily occupy vacant orbitals on adjacent metal atoms. For this reason metals conduct electricity well. When an electron from an atom with low electronegativity (e.g., a metal) is removed by another atom with high electronegativity (e.g., a nonmetal), the two atoms become oppositely charged ions that attract each other, resulting in an ionic bond. Chemical bonds between atoms can be almost entirely covalent, almost entirely ionic, or in between these two extremes. The triple bond in nitrogen molecules (N2) is nearly 100 percent covalent. A salt such as sodium chloride (NaCl) has bonds that are nearly completely ionic. However, the electrons in gaseous hydrogen chloride are shared somewhat unevenly between the two atoms. This kind of bond is called polar covalent. (Note that elements in groups 1, 2, 16, and 17 in the periodic table usually gain or lose electrons through the formation of either ionic or covalent bonds, resulting in eight outer shell electrons. This behavior is sometimes described as “the octet rule.”) Standard CH 2. b. Students know chemical bonds between atoms in molecules such as H2, CH4, NH3, H2CCH2, N2, Cl2, and many large biological molecules are covalent. Framework Organic and biological molecules consist primarily of carbon, oxygen, hydrogen, and nitrogen. These elements share valence electrons to form bonds so that the outer electron energy levels of each atom are filled and have electron configurations like those of the nearest noble gas element. (Noble gases, or inert gases, are in the last column on the right of the periodic table.) For example, nitrogen has one lone pair and three unpaired electrons and therefore can form covalent bonds with three hydrogen atoms to make four electron pairs around the nitrogen. Carbon has four unpaired electrons and combines with hydrogen, nitrogen, and oxygen to form covalent bonds sharing electron pairs. The great variety of combinations of carbon, nitrogen, oxygen, and hydrogen make it possible, through covalent bond formation, to have many compounds from just these few elements. Teachers can use ball and stick or gumdrop and toothpick models to explore possible bonding combinations. Standard CH 2. c. Students know salt crystals, such as NaCl, are repeating patterns of positive and negative ions held together by electrostatic attraction. Framework The energy that holds ionic compounds together, called lattice energy, is caused by the electrostatic attraction of cations, which are positive ions, with anions, which are negative ions. To minimize their energy state, the ions form repeating patterns that reduce the distance between positive and negative ions and maximize the distance between ions of like charges. ICS 1 sem2 block 2 Bonding Standards CH 2 a, b, c Vocabulary 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. 13. 14. 15. 16. 17. 18. Chemical bonds Intermolecular attractive forces Hydrogen bond Covalent bond Chemical reaction Electrostatics Electro-negativity matter atoms molecules protons neutrons electrons geometry 2. a. Covalent bond metallic bonds Ionic bonds. N2 19. NaCl 20. HCl 21. Octet rule 2. b. 22. H2 23. CH4 24. NH3 25. H2CCH2 26. Cl2 27. 28. 29. 30. 31. 32. 33. 34. 35. 36. Organic molecules biological molecules Carbon Oxygen Hydrogen Nitrogen 2. c. salt crystals lattice energy cations Anions 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. 13. 14. 15. 16. 17. 18. 19. 20. 21. 22. 23. 24. 25. 26. 27. 28. 29. 30. 31. 32. 33. 34. 35. 36. Bond between 2+ elements; forming a new compound / molecules between neighboring particles: atoms, molecules or ions attractive interaction of a hydrogen atom with an electronegative atom, such as nitrogen, oxygen or fluorine the sharing of pairs of electrons between atoms two or more particles have an effect upon one another phenomena / properties of stationary or slow-moving electric charges the tendency of an atom to attract electrons all objects with mass basic building blocks of particles: molecules, compounds electrically neutral group of 2+ atoms held together by bonds positively charged part of the atoms, nucleus neutral charged part of the atoms, nucleus negatively charged part of the atom, orbiting the nucleus the study of dimension, size, shape and position of objects sharing of pairs of electrons between atoms Delocalized electrons, called conduction electrons, gathered in an "electron sea", and the positively charged metal ions. Attraction between two oppositely charged ions. Ionic bonds are formed between a cation, usually a metal, and anion, nonmetal. Diatomic Nitrogen gas Sodium Chloride Hydrogen Chloride Combine; each have eight electrons in their valence shells, giving them the same electronic configuration as a noble gas molecular hydrogen composed of two hydrogen atoms methane Ammonia Simplest form of an alkene (a hydrocarbon that contains a carbon - carbon double bond) called ethene or ethylene Diatomic Chlorine gas contain carbon-hydrogen bonds, four classes include carbohydrates, proteins, lipids and nucleic acids DNA, RNA, cells, proteins… Atomic number 6, nonmetallic, forms covalent bonds Atomic number 8, nonmetallic, Chalcogen family Atomic number 1 Atomic number 7, nonmetallic, 78% of atmosphere essential for animal life in small quantities, but is harmful to animals and plants in excess measure of the strength of bonds in that ionic compound is an ion with fewer electrons than protons, giving it a positive charge is an ion with more electrons than protons, giving it a net negative charge Page 2 Block 2 Chemical Bonds http://www2.chemistry.msu.edu/faculty/reusch/virttxtjml/intro2.htm Covalent bonds- Polar like water, Non-polar like diesel fuel, Share electrons Lewis-dot for CO2 CO2 Lewis Dot Structure- Rules- remember the Cross-hairs and rotate Ionic bonds- like salt, trades electrons (transfer) Na + Cl = Na Cl Common Name Molecular Formula Methane CH4 Ammonia NH3 Ethane C2H6 Methyl Alcohol CH4O Ethylene C2H4 Formaldehyde CH2O Acetylene C2H2 Hydrogen Cyanide CHN Lewis Formula Kekulé Formula Page 3 Handout: Amazing Atoms 1. protons and neutrons 2. positive neutral 3. three 4. four 5. three 6. group 1 so 1 1. protons neutrons electrons 2. protons neutrons 3. electrons 4. positive and negative 5. neutral and positive 6. same 7. balance 8. no 9. different number, neutrons 10. valence Oxygen 8 16 8 8 8 6 Calcium 20 40 20 20 20 2 Bromine 35 80 35 45 35 7 Potassium 19 39 19 20 19 1 Carbon 6 14-10=4 e +6p Phosphorus 15 15-10=5 +15p Nitrogen 7 15-10=5 +7 Oxygen 8 16-10=6 +8 Sodium 11 group 1 so 1 Chlorine 17 needs 1 so -1 2. Sodium its easy to get rid of one 3. Chlorine needs 1 more for 8 4. +1-1=0 Magnesium 12 +2 Oxygen 8 -2 Mg O 1. 2 2. Because Mg is in group 2 3. +2-2=0 1. Boron is in group 13 13-10 = 3 … 3 bonds 2. Oxygen is in group 16 16-10 = 6 wants 8 for stability …so 2 more, this is also the number of bonds it forms 3. H O H Chlorine only needed one electron +2-2=0 1. 4 2. 2 it is the same number 3. 4. 5. 4 Brochure Next two pages IONIC bonds Chemical bonding formed through electrostatic attraction between two oppositely charged ions. Ionic bonds are formed between a metal and a nonmetal ion. 1 Name ______________________ Period ______ Date ____________ Block 2 Title Chemical Bonds COVALENT bonds Chemical bonding that is characterized by the sharing of pairs of electrons between atoms, and other covalent bonds. In short, the stable balance of attractive and repulsive forces between atoms when they share electrons METALLIC bonds Electromagnetic interaction between delocalized electrons, called conduction electrons, gathered in an "electron sea", and the metallic nuclei within metals. Standard Chemistry 2 a, b, c Biological, chemical, and physical properties of matter result from the ability of atoms to form bonds from electrostatic forces between electrons and protons and between atoms and molecules. As a basis for understanding this concept: CH 2. a. Students know atoms combine to form molecules by sharing electrons to form covalent or metallic bonds or by exchanging electrons to form ionic bonds CH 2. b. Students know chemical bonds between atoms in molecules such as H2, CH4, NH3, H2CCH2, N2, Cl2, and many large biological molecules are covalent. CH 2. c. Students know salt crystals, such as NaCl, are repeating patterns of positive and negative ions held together by electrostatic attraction. CH 2. a. atoms to CH 2. b. chemical bonds molecules 2 H2(g) + O2(g) → 2 H2O(l) + Energy Sharing electrons to form covalent/metallic bonds Exchanging electrons to CH4 + O2 → CO + H2 + H2O 2 NH4Cl + 2 CaO → CaCl2 + Ca(OH)2 + 2 NH3 form ionic bonds Ionic compounds-metals and non-metals Molecular (covalent) compounds-nonmetals H2CCH2 The simplest form of an alkene a hydrocarbon that contains a {carbon – carbon} double bond called ethene or ethylene Metallic compounds are between metals and other Another important difference between is that an 6 Li + N2 → 2 Li3N 3 Mg + N2 → Mg3N2 ionic compound is a crystalline solid at standard temperature and pressure (STP), where as a molecular compound can be in a solid, gas or liquid state at STP. Cl2 + H2O HClO HCl + CH 2. c. salt crystals NaCl Repeating patterns of positive and negative ions held together by electrostatic attraction. Page 4 Handout: periodic table Back side notes page below Bond types Ionic Bond Two oppositely charged ions bond, Give and receive electron to make bonds Metallic bonding "Electron sea" and the positively charged metal ions. Sharing of "free" electrons among a metallic bonding ex. Salts Covalent bond Neighboring atoms share electrons to form a bond neither atom hold electron tightly Compounds / Molecules Molecules is an electrically neutral group of two or more atoms held together by covalent chemical bonds Atoms / Bohr / Ruth Atom 1 type of nucleus/electron millions of atoms Bohr created the theory of “qua Compound Two or more different atoms bonded. All compounds are molecules Rutherford Gold foil experiment foun nucleus