CHEMISTRY HONORS QUARTER 2 REVIEW (chapter numbers correspond with textbook chapters order) CHAPTER 8 Define term ion Differentiate between a cation and anion Describe the composition of ionic compounds and list their characteristics Determine the probable charge of an element based on its periodic placement Construct the electron configuration for various ions Define and give examples for: o Ionic bonds o Metallic bonds Name compounds containing ions and polyatomic ions Construct chemical formulas based on chemical name CHAPTER 9 Name covalent compounds using numeric prefixes Name acids (binary and oxyacid) Write the formula for a covalent compound from its name Write the formula for a binary and oxyacid from its name Construct Lewis structures for compounds Determine: o Shape o Bond angle o Polarity o Hybrid orbital Define covalent bond and explain how one works Use electronegativity to predict bond polarity Compare the relative bond energy and length of single, double and triple bonds Define coordinate covalent bond and explain how one works VSEPR theory Define hybrid orbitals Describe the polarity of molecules and the formation of bonds between them List the characteristics of covalently bonded molecules Explain resonance. Draw resonance structures for molecules. CHATPER 11 Convert the number of: o Moles to grams o Grams to moles o Molecules to moles o Moles to molecules o Grams to molecules o Molecules to grams Determine the: o Molar mass of compounds o Percent composition o Molecular formula o Hydrates o Empirical formula CHEMISTRY HONORS QUARTER 2 REVIEW (chapter numbers correspond with textbook chapters order) CHAPTER 13 Define/ describe following terms: surface tension crystalline vs. amorphous capillary action sublimation volatility diffusion vapor pressure effusion boiling point hydrogen bond London-dispersion forces dipole-dipole forces viscosity phase diagram Kinetic molecular theory Graham’s law of effusion Dalton’s law of partial pressures Manometer Barometer Boyle’s law Charles’s law Gay- Lussac's law Combined gas law CHAPTER 14 CHAPTER 16 Heating curves Specific heat capacity Heat of fusion Heat of vaporization Calorimetry endothermic exothermic MULTIPLE CHOICE: Choose the best answer for each question. 1. Calculate the molecular weight of CrSO4? A. 100 g/mol B. 244 g/mol Cr = 52; S = 32; O =16 C. 400 g/mol D. 148 g/mol 2. What is the number of total atoms in a molecule of Fe3(PO4)2? A. 3 B. 5 C. 13 D. 12 3. The mass of 0.10 mol of H2O A. 18 g B. 180 g D. none of the above H = 1; O = 16 C. 1.8 g 4. How many mole(s) are in 300 g of CaCO3? A. 3 B. 300 Ca = 40; C = 12; O = 16. C. 9 D. 900 5. The mole is A. 1,000 grams. B. The number of C-atoms in 12.0 g of Carbon C. The SI unit for the amount of substance in Chemistry D. B and C 6. Which of the following element is diatomic? A. Iodine B. Copper C. Silicon D. Potassium 7. What is the electron configuration of Al3+? A. 1s2 2s2 2p6 3s2 3p6 B. 1s2 2s2 2p6 3s2 3p6 4d2 C. 1s2 2s2 2p6 3s2 D. 1s2 2s2 2p6 8. Which of the following has a linear shape? A. CH4 B. BCl4- C. CO2 D. All of these 9. If chlorine has an electronegativity of 3.0, what type of bond is formed in Cl2? A. ionic B. polar covalent C. nonpolar covalent D. Metallic 10. The concept used in writing the electron-dot structures of certain molecules that oscillate between two or more possible structures is called: A. hybridization B. electrostatic repulsion C. resonance D. electronegativity 11. Which of the following compounds violates the octet rule? A. NF3 B. CCl4 C. SbCl5 D. Cl2 12. Which of the following is the most polar bond? EB = 2.0; EC = 2.5; EO = 3.5; ES = 2.5 A. B-C B. S-O C. C-O D. B-O 13. Which substance below is composed of cations surrounded by a “sea of mobile electrons”? A. Mn B. Si C. NaCl D. CH4 14. The VSEPR Theory basically: A. explains why bonds form B. helps predict the shape of the molecules C. has to do with why hybrid orbitals form D. allows scientist to calculate the bond energies 15. A triple bond is made of sharing of _____ electrons between two atoms. A. 2 B. 4 C. 6 D. 3 FREE RESPONSE: 16. A compound is found to be 40.00% carbon, 6.67% hydrogen, and 53.33% oxygen. Its molar mass is 210.0 g/mol. What is the molecular formula of this compound? 17. Name the following: a. P2O5 b. Ca(ClO3)2 c. NH4F d. AlN e. Fe(NO2)3 f. SnO2 g. H2SO3 h. H3P Write formulas for the following: a. lead (IV) sulfide b. hydrosulfuric acid c. dinitrogen trioxide d. chromium (III) hydroxide e. chromic acid f. sodium carbonate g. zinc oxalate h. sulfur hexafluoride 18. Fill in the following chart Formula Lewis Structure Geometry Bond Angles Hybridization Molecular Polarity PH3 H2S CCl4 CS2 CH2O AsI5 SeBr6 19. Find the mass of 2.25 x 1021 formula units of magnesium iodate. 20. Find the mass percent of water in nickel(II) cyanide tetrahydrate. 21. A 5.0g sample of nickel(II) cyanide is heated until all water is removed. What mass of anhydrous nickel(II) cyanide will remain? 22. Identify all types of intermolecular forces in a-d: a. Attraction between any two polar molecules _____________________ b. Very weak force that increases with molar mass ___________________ c. Attraction between two induced dipoles _________________________ d. Very strong attractive force between molecules with N-H, O-H, or F-H bonds_________ 23. Compare and contrast solids and liquids ___________________________________________________________________________ ___________________________________________________________________________ ___________________________________________________________________________ 24. Identify the type of solid in a-e: a. Every atom is covalently bonded to another atom ____________________ b. Atoms are surrounded by a sea of electrons _________________________ c. Particles are connected only by IMF ______________________________ d. There is no geometric pattern in the structure _______________________ e. Charged particles in a geometric pattern ___________________________ 25. Explain the relationship between strong intermolecular forces and the following properties – volatility, vapor pressure and boiling point: ___________________________________________________________________________ ___________________________________________________________________________ ___________________________________________________________________________ 26. Refer to the phase diagram below when answering the questions: a. What is the normal freezing point of this substance? ________ b. What is the physical state of this substance at 300°C and 0.50 atm ? ____________ c. If I had a quantity of this substance at a pressure of 1.25 atm and a temperature of 3000 C and lowered the pressure to 0.25 atm, what phase transition(s) would occur? _________ 27. Indicate whether a heating curve would be flat or rising in a-e. a. Liquid is boiling ___________ b. Potential energy is increasing ____________ c. Solid is warming ___________ d. Kinetic energy is increasing ______________ e. Solid is melting ______________ 28. How much heat does a 23.0 g ice cube absorb as its temperature increases from -17.4°C to 0.0°C? (use constants from homework sheets). 29. A 50.6 g sample of silver at 97.4°C is placed into 104 g of water at 19.7°C. What is the final temperature of the system? (CAg= 0.235J/g°C) 30. How much heat is required to change 20.0 g of ice at -13.0°C to steam at 125.0°C? (use constants from homework sheets) 31. 50.0 L of gas has a temperature of 75°C. What is the temp in Celsius when the volume changes to 110. L? 32. A balloon is filled with 3.0 L of helium at 1 atm. What is the volume when the balloon rises to an altitude where the pressure is only 0.25 atm? (assume temperature remains constant.) 33. The gas left in a used aerosol can is at a pressure of 1 atm at 27°C. If this can is thrown into a fire, what is the internal pressure of the gas when its temperature reaches 927°C? 34. 5.2 L of a gas is at STP. Find the new volume when the temperature rises to 38°C and the pressure drops to 600 mmHg. 35. Pressure and volume of a gas at constant temperature are __________________ proportional. Why? __________________________________________________ 36. Volume and temperature of a gas at constant pressure are __________________ proportional. Why? ______________________________________________________ 37. Which travels faster CO2 or O2? How much faster? 38. Gas A travels 4 times faster than Gas B. If the molar mass of Gas B is 80 g/mole, find the molar mass of Gas A. 39. A 250. ml sample of oxygen is collected over water at 25 ° C and 760.0 mmHg pressure. What is the pressure of the dry oxygen alone? (Vapor pressure of water at 25°C = 23.8 mmHg).