A Process-Based Greenhouse Gas (GHG) Inventory Model for Landfill CH4 Emissions Inclusive of Seasonal Soil Microclimate and CH4 Oxidation Jean Bogner (’69), Dept. Earth & Environmental Sciences (EAES), Univ. Illinois at Chicago (UIC), Chicago, IL Kurt Spokas, Agricultural Research Service-USDA, St. Paul, MN Jeffrey Chanton, Florida State University, Tallahassee, FL Margaret Corcoran, Graduate Student, EAES, UIC, Chicago, IL Methane (CH4) is a potent GHG, with landfills currently estimated to be the 3rd largest source of anthropogenic CH4 in the U.S. after natural gas leakages and ruminant animals. Current IPCC (Intergovernmental Panel on Climate Change) national GHG inventory models for landfill CH4 emissions based on theoretical CH4 generation have high uncertainties and lack comprehensive field validation. Moreover, literature over the last decade has emphasized that the major factors controlling landfill CH4 emissions are the presence of engineered gas extraction, gaseous transport rates as affected by the thickness and physical properties of cover soils, and microbial CH4 oxidation in cover materials as a function of seasonal soil microclimate. Therefore we developed and field‐validated an annual inventory model for California landfill CH4 emissions that incorporates site‐specific cover soil properties and soil microclimate modeling coupled to 0.5° scale global climatic models. Based on 1‐D diffusion with CH4 oxidation rates scaled to temporal soil temperature and moisture [2.5-cm depth increments; 10-min. time increments], CALMIM (California Landfill Methane Inventory Model) is a JAVA tool which models a typical annual cycle for CH4 emissions from site‐specific daily, intermediate, and final landfill cover soil properties. This new approach, which is compliant with IPCC “Tier III” criteria, has been field‐validated at two California sites (Monterey County; Los Angeles County), with limited field validation at three additional California sites. CALMIM accurately predicts soil temperature and moisture trends with emission predictions within the same order of magnitude as field measurements, indicating an acceptable initial model comparison in the context of published literature for small-scale CH4 emission measurements spanning 7 orders of magnitude. In addition to default values for inventory purposes, CALMIM permits user‐selectable parameters and boundary conditions where site-specific data exist. Current project work is focusing on international field validation and structural improvements. CALMIM is freely available at www.ars.usda.gov/services/software/download.htm?softwareid=300. For more information, please consult the following publications: Spokas, K., Bogner J., and Chanton, J., A Process-Based Inventory Model for Landfill CH4 Emissions Inclusive of Soil Microclimate and Seasonal Methane Oxidation, J. Geophysical Research-Biogeosciences, 116: paper G04017, 19 p. (2011). Bogner, J., Spokas, K., and Chanton, J., Seasonal Greenhouse Gas Emissions (methane, carbon dioxide, nitrous oxide) from Engineered Landfills: Daily, Intermediate, and Final California Landfill Cover Soils, J. Environ. Quality 40:10101020 (2011). Spokas, K., and Bogner, J., Limits and dynamics of methane oxidation in landfill cover soils, Waste Management 31:823-832 (2011).