Chemical Reactions Lesson Author: Alison Hapka, Elkton High School, Cecil County Public Schools Background Information Subject: Identify the course the unit will be implemented in. Grade Band: Identify the appropriate grade band for the lesson. Duration: Identify the time frame for the unit. Overview: Provide a concise summary of what students will learn in the lesson. It explains the unit’s focus, connection to content, and real world connection. Background Information: Identify information or resources that will help teachers understand and facilitate the challenge. STEM Specialist Connection: Describe how a STEM Specialist may be used to enhance the learning experience. STEM Specialist may be found at http://www.thestemnet.com/ This lesson could be used in a high school chemistry course in the unit on chemical reactions. 9-12 Two ninety minute periods. Students will observe and collect data on the mass of the reactants vs. the products of a simple chemical reaction to investigate the conservation of mass during the reaction. This exploration of a reaction in a flask with the top covered by a deflated balloon to see if mass is conserved during a chemical reaction. The liquid remaining in the flask will be heated to evaporate the water and yield the mass of the solid that precipitates. Students will demonstrate their understanding by developing a concept cartoon that demonstrates the movement of atoms before, during, and after a chemical reaction. When a chemical reaction occurs, bonds between atoms are broken and formed which results in a transfer of energy but the same number of atoms of each element that were present before the reaction will also be present after the reaction and therefore the mass of the total reactants will equal the mass of the total products. A STEM Specialist can enhance the learning experience by engaging students in applied learning experiences that demonstrate the importance of understanding chemical reactions and making relevant connections to the workplace. Enduring Understanding: Identify discrete facts or skills to focus on larger concepts, principles, or processes. They are transferable - applicable to new situations within or beyond the subject. Mass is conserved in a chemical reaction. Energy is required to break bonds between the elements. Page 1 of 10 Chemical Reactions Lesson Essential Questions: Identify several open-ended questions to provoke inquiry about the core ideas for the lesson. They are grade-level appropriate questions that prompt intellectual exploration of a topic. Student Outcomes: Identify the transferable knowledge and skills that students should understand and be able to do when the lesson is completed. Outcomes must align with but not limited to Maryland State Curriculum and/or national standards. 1. 2. 3. 4. Background Information How does the total mass of the products of a chemical reaction compare to the total mass of the reactants of the reaction? How does the total number of atoms of the products of a chemical reaction compare to the total number of atoms of the reactants of the reaction? How does the total number of molecules of products of a chemical reaction compare to the total number of molecules of the reactants of the reaction? How can one demonstrate that mass is conserved during a chemical reaction? Students will be able to: gather qualitative and quantitative data before, during, and after a reaction to compare the mass of the reactants and products of a chemical reaction. calculate the necessary mass of the second reactant to complete a chemical reaction. calculate the theoretical yield of each of the products of a chemical reaction. measure the actual yield of each of the products of a chemical reactions. calculate the percent yield of each of the products of a chemical reaction. create a concept cartoon that represents what is happening to the atoms before, during, and after the chemical reaction. Product, Process, Action, Performance, etc.: Identify what students will produce to demonstrate that they have met the challenge, learned content, and employed 21st century skills. Additionally, identify the audience they will present what they have produced to. Standards Addressed in the Unit: Identify the Maryland State Curriculum Standards addressed in the unit. Students will create a concept cartoon that represents what is happening to atoms before, during, and after the chemical reaction. The cartoon will represent atoms, energy transfer, chemical bonds, and the kinetic energy of the moving atoms and molecules. Next Generation Science Standards: HS-PS1 Matter and It’s Interactions HS-PS1-7.Use mathematical representations to support the claim that atoms, and therefore mass, are conserved during a chemical reaction. Page 2 of 10 Chemical Reactions Lesson Background Information Common Core Reading in Science and Technical Subjects: RST.11-12.3 Follow precisely a complex multistep procedure when carrying out experiments, taking measurements, or performing technical tasks; analyze the specific results based on explanation in the text. Common Core Writing in Science and Technical Subjects: WHST.11-12.2 Write informative/explanatory texts, including the narration of historical events, scientific procedures/experiments, or technical processes. Suggested Materials and Resources: Identify materials needed to complete the unit. This includes but is not limited to websites, equipment, PowerPoints, rubrics, worksheets, and answer keys. Equipment: (for each lab group of 2-3 students) • erlenmeyer flask • balance • weighing dish • two reactants • balloon For the reactants there are many different chemical reactions that can be used for this investigation and calculation. One good combination is acetic acid (vinegar) and sodium bicarbonate (baking soda). Website: Concept cartoon example: http://www.iupac.org/fileadmin/user_upload/news/2013/cartoon_prizewinners/cartoon13_Bilb rey.pdf People, Facilities: STEM Specialist Materials (rubrics, worksheets, PowerPoints, answer keys, etc.): Chemistry Concept Cartoon Rubric An alternate concept cartoon rubric can be found here >>> Cartoons – An Alternative Learning Assessment Page 3 of 10 Chemical Reactions Lesson Learning Experience 5E Component Identify the 5E component addressed for the learning experience. The 5E model is not linear. ☐Engagement x Exploration ☐Explanation ☐Extension ☐Evaluation Details Materials:(for each lab group of 2-3 students) • erlenmeyer flask • balance • weighing dish • two reactants • balloon • hot plate • hot hands or flask tongs For the reactants there are many different chemical reactions that can be used for this investigation and calculation. One good combination is acetic acid (vinegar) and sodium bicarbonate (baking soda). If another reaction is selected, check the safety of both the reactants and products, and be sure that evaporating the liquid solution that remains by using a hot plate will not product a hazardous condition in the laboratory. Preparation: Be sure to test out the ratio of acetic acid to sodium bicarbonate to make sure the gas produced is enough to partially fill the balloon but not pop the balloon off of the flask. Students will be calculating the quantities of each reactant to use, but depending on the concentration of acetic acid you are using, you need to limit the quantity of one of the two reactants to avoid having the balloon overfill and pop off of the flask. Science and Engineering Practices ☒Asking questions (for science) and defining problems (for engineering) ☐Developing and using models ☒Planning and carrying out investigations ☐Analyzing and interpreting data ☒Using mathematics and computational thinking ☐Constructing explanations (for science) and designing solutions (for engineering) Facilitation of Learning Experience: Introduce students to the erlenmeyer flask if students have not previously used them, and demonstrate the technique of putting ☐Engaging in argument an empty balloon over the mouth of the flask before mixing the chemicals. The Page 4 of 10 Chemical Reactions Lesson Learning Experience 5E Component Identify the 5E component addressed for the learning experience. The 5E model is not linear. Details choice of whether to put the liquid or solid reactant in the balloon before mixing should be left to the students. Science and Engineering Practices from evidence ☒Obtaining, evaluating, and communicating Before beginning the investigation, have students predict what they think will happen to the total mass of the container during the reaction and after the reaction information is complete. To test their prediction, students will measure and record the mass of each piece of their apparatus as well as their reactants before the reaction, and monitor the mass of the entire system during the reaction. Then using the mass of one reactant, calculate how much of the second reactant they will use for their reaction. After the reaction, students should again mass the components of the reactions. To determine the mass of the gas collected, students can carefully tie off the balloon and find the mass of the filled balloon. Some of the gas will also be in the top of the flask which students can discuss as part of the error analysis of the lab. To separate the water from the dissolved solid, heat the solution on a hot plate. When the liquid is mostly evaporated be prepared to remove the flask from the hot plate so that the hot solid does not pop out of the flask or burn. Be sure to use either flask tongs or hot hands to remove the hot flask from the hot plate and turn off the hot plate once the flask has been removed. For best results, student lab groups should repeat the experiment three times. Transition: The data from this exploration lab will be used in the analysis in the next portion of the lab. Page 5 of 10 Chemical Reactions Lesson Learning Experience 5E Component Identify the 5E component addressed for the learning experience. The 5E model is not linear. ☐Engagement ☐Exploration x Explanation ☐Extension ☐Evaluation Details Science and Engineering Practices Materials: Students will need access to their lab data. ☒Asking questions (for science) and defining Preparation: Practice a few stoichiometry problems to prepare for the introduction problems (for to this technique. engineering) Facilitation of Learning Experience: Guide students through the writing and balancing of the chemical equation for the reaction that they used in their investigation. For acetic acid and sodium bicabonate the equation is: ☐Developing and using models CH3COOH + NaHCO3 → NaCH3COO + CO2 + H2O ☐Planning and carrying out investigations Next, have the groups use their lab data to determine: What is the theoretical yield of carbon dioxide gas from my reactants? What is the theoretical yield of sodium acetate from my reactants? What is the theoretical yield of water from my reactants? What was the actual yield of sodium acetate? What was the actual yield of water? What was the actual yield of carbon dioxide? Compare the theoretical and actual yield for each of the three products to calculate the percent error for your experiment. 8. Discuss your results and whether or not they make sense. 9. How did the total mass of the reactants and apparatus compare to the total mass of everything after the reaction? 10. How many molecules of acetic acid did you use in your reaction? 11. How many molecules of sodium bicarbonate did you use in your reaction? 12. How many molecules of water theoretically formed in your reaction? 1. 2. 3. 4. 5. 6. 7. ☒Analyzing and interpreting data ☒Using mathematics and computational thinking ☒Constructing explanations (for science) and designing solutions (for engineering) ☐Engaging in argument from evidence Page 6 of 10 Chemical Reactions Lesson Learning Experience 5E Component Identify the 5E component addressed for the learning experience. The 5E model is not linear. Details 13. How many molecules of carbon dioxide theoretically formed in your reaction? 14. How many molecules of sodium acetate theoretically formed in your reaction? 15. How many atoms of each element were present in the reactants for the reaction? 16. How many atoms of each element were present in the products for the reaction? 17. How does the number of total molecules present in the reactants compare to the total number of molecules present in the products compare? 18. How does the number of total atoms present in the reactants compare to the total number of atoms present in the products compare? 19. How does the number of atoms of each element present in the reactants compare to the number of atoms of the same element in the products? 20. Was the number of molecules conserved in the reaction? 21. Was the mass conserved in the reaction? 22. Was the number of atoms conserved in the reaction? Science and Engineering Practices ☒Obtaining, evaluating, and communicating information Transition: Once the data has been analyzed, students will next use their lab results to create a three segment concept cartoon about what is happening on a microscopic scale during the reaction. Page 7 of 10 Chemical Reactions Lesson Learning Experience 5E Component Identify the 5E component addressed for the learning experience. The 5E model is not linear. ☐Engagement ☐Exploration ☐Explanation x Extension x Evaluation Details Materials: Colored pencils or markers Rulers Chemistry Concept Rubric Science and Engineering Practices ☐Asking questions (for science) and defining problems (for engineering) Preparation: Review examples of concept cartoons and select one to share with ☒Developing and using the class. Make sure that the cartoon that depicts a concept that has been already covered with this class, but not one that will fit the assignment. Here is a possible models candidate (many others will be revealed by a google search of “chemistry concept ☐Planning and carrying cartoons”): out investigations http://www.iupac.org/fileadmin/user_upload/news/2013/cartoon_prizewinner ☐Analyzing and s/cartoon13_Bilbrey.pdf interpreting data Facilitation of Learning Experience: Review the reaction students investigated ☐Using mathematics and computational thinking in the lab. Introduce the concept cartoon project and distribute the rubric. Inform students that they will create a concept cartoon that represents what is happening ☒Constructing to the atoms before, during, and after the chemical reaction. The cartoon will represent atoms, energy transfer, chemical bonds, and the kinetic energy of the explanations (for moving atoms and molecules. science) and designing solutions (for After students prepare a rough draft of their cartoons, have them do a peer review engineering) using the rubric and write three clarifying questions they would like the other student to address in their cartoon. Then have students revise their cartoons, and ☐Engaging in argument do a gallery walk of the finished work by all students. Facilitate a class discussion from evidence focusing on what was happening during the reaction and how that was best depicted and most accurately represented in the cartoons produced by the class. Page 8 of 10 Chemical Reactions Lesson Learning Experience 5E Component Identify the 5E component addressed for the learning experience. The 5E model is not linear. Details Science and Engineering Practices ☒Obtaining, evaluating, and communicating information Page 9 of 10 Chemistry Concept Cartoon Rubric (prepared using rubi star rubric generator) Category 4 3 2 1 Title is informative and centered. The title is incomplete and does not clearly indicate what organism is pictured. Almost all assigned details (at least 85%) have been added. The details are clear and easy to identify. Almost all assigned details (at least 85%) have been added. A few details are difficult to identify. Fewer than 85% of the assigned details are present OR most details are difficult to identify. Accuracy (12 points) 95% or more of the assigned structures are drawn accurately and are recognizable. All assigned structures are labeled accurately. 94-85% of the assigned structures are drawn accurately and are recognizable. All assigned structures are labeled accurately. 94-85% of the assigned structures are drawn accurately and are recognizable. 9485% of the assigned structures are labeled accurately. Less than 85% of the assigned structures are drawn AND/OR labeled accurately. Labels (8 points) Every item that needs to be identified has a label. It is clear which label goes with which structure. Almost all items (90%) that need to be identified have labels. It is clear which label goes with which structure. Most items (75-89%) that need to be identified have labels. It is clear which label goes with which structure. Less than 75% of the items that need to be identified have labels OR it is not clear which label goes with item. Title (4 points) Title is informative, Title is informative centered, and larger and larger than than other text. other text. All assigned details Drawing Details (12 have been added. The details are clear points) and easy to identify. An alternate rubric can be found here >>> Cartoons – An Alternative Learning Assessment