Experiment: Acids and Metals Aim: To determine the product of an acid and metal reaction. Equipment: - 1M Hydrochloric acid (in dropper bottle) - Vinegar - 6 test tubes - Test tube rack - Distilled water (in wash bottle) Magnesium, Iron, Zinc Stoppers Matches Safety glasses Method: 1. Place six test-tubes in the test-tube rack. 2. Add a 2–3 cm depth of 0.1M hydrochloric acid to the first three tubes, and a 2–3 cm depth of vinegar to the remaining three tubes. 3. Add a small piece of a different metal to each of the tubes with hydrochloric acid in them. Record which metal you add to each tube. 4. Put a stopper in these test tubes. Do not hold the stoppers down as the glass could break. 5. Test that hydrogen has been produced in the test tubes with Hydrochloric Acid. Test for hydrogen: The light of a flame will ‘pop’ and go out when it is put over the gas. 6. Add a small piece of the same metals to each of the tubes with vinegar in them. Record which metal you add to each tube. 7. When you are done list the order of reactivity by numbering the reactions from highest to lowest (1 - highest reactivity). Risk Assessment: Table 1: Risk Assessment Potential Hazards Standard Handling Procedures Results: Note your observations in the table below. Metal Zinc Magnesium Iron Table 2: Results Observations Hydrochloric Acid Vinegar Reactivity Questions and Discussion: What gas did the reactions produce? How did you test for this? What do all acids contain? When a metal and an acid react together they make . SALT - a SALT is formed when the Hydrogen of an Acid is replaced by a metal Naming SALTS Remember metals (except copper and some others) push out (displace) the hydrogen of acids to make SALTS. ACID TYPE of SALT made Hydrochloric acid HCl(aq) CHLORIDES e.g. sodium chloride NaCl(s) Sulphuric acid H2SO4(aq) SULPHATES e.g. magnesium sulphate MgSO4(s) Nitric acid HNO3(aq) NITRATES e.g. potassium nitrate KNO3(s) Carbonic acid H2CO3(aq) CARBONATES e.g. zinc carbonate ZnCO3(s) Phosphoric acid H3PO4(aq) PHOSPHATES e.g. calcium phosphate Ca3(PO4)2(s) So, a SALT contains: a CATION e.g. Na+ (usually from a METAL) And an ANION e.g. Clfrom an ACID e.g. hydrochloric acid HCl(aq) 1. Magnesium + hydrochloric acid magnesium chloride + hydrogen Mg + 2HCl MgCl2 + H2 + hydrochloric acid ……………………….. + …………………………… 2. Iron Fe + HCl ……………………….. + …………………………… + hydrochloric acid ……………………….. + …………………………… 3. Zinc Zn + HCl ……………………….. + …………………………… 4. Aluminium + hydrochloric acid ……………………….. + ……………………… Al 5. Tin Sn + HCl ……………………….. + …………………………… + hydrochloric acid ……………………….. + …………………………… + HCl ……………………….. + …………………………… Homework Activity 1 Using the information in the picture below or otherwise, answer the following questions: 1. 2. 3. 4. 5. What is acid rain? What causes acid rain? Why is acid rain harmful? What is being done to prevent it? What can you do to prevent it? Experiment: Acids and Carbonates Aim: To determine the products of an acid and carbonate reaction. Equipment: - 4 test tubes - Test tube rack - Stoppers - Small beaker (100mL) - Limewater - Sodium carbonate - Ammonium carbonate - Calcium Carbonate Spatula 1M hydrochloric acid Vinegar Matches Safety glasses Method: 1. Add a small amount of each solid (about the tip of a spatula full) to two different test tubes. 2. Add 2 cm of hydrochloric acid to the first tube and quickly stopper. Remove the stopper and add a small amount of limewater. 3. Repeat steps 1–2 using vinegar instead of HCl Risk Assessment: Table 1: Risk Assessment Potential Hazards Standard Handling Procedures Results: Note your observations in the table below. Table 2: Results Reactivity Observations Metal Hydrochloric Acid Sodium Carbonate Ammonium Carbonate Calcium Carbonate Vinegar Questions 1. What products were formed during the reactions? 2. How did you test for these products? 3. Write out word equations to describe the chemical reactions you have observed. If possible also write out formula equations. 4. What effects can Carbon Dioxide have on the environment? 5. Homework Activity 2 When Carbon dioxide is dissolved in water it forms a weak carbonic acid. This is common in our waterways. What is the effect of carbonic acid on our environment? You may use the internet to help you answer this question. Experiment: Acids and Bases (Neutralisation) Aim: To investigate the neutralization of an acid by a base. Equipment: - 50mL measuring cylinder - 1M hydrochloric acid - 1M sodium hydroxide - Universal indicator Pasteur pipette Safety glasses Method: 1. Pour 25 ml of 1 M hydrochloric acid into the beaker. 2. Measure the pH using universal indicator. 3. Add 5 mL of 1 M sodium hydroxide. 4. Re-measure the pH of the solution in the beaker. 5. Repeat steps 3 and 4 until you have added 35 mL of the sodium hydroxide solution. Risk Assessment: Table 1: Risk Assessment Potential Hazards Standard Handling Procedures Results: Note your observations in the table below. Volume of Hydrochloric Acid Table 2: Results Volume of Sodium Hydroxide 25mL 0mL 25mL 5mL 25mL 10mL 25mL 15mL 25mL 20mL 25mL 25mL 25mL 30mL 25mL 25mL Colour pH Range Questions 1. At which point was the solution neutral. Why? 2. Construct the word equations to describe the reaction. Also complete a formula equation if possible. 3. Does adding the same amount of base to an acid always neutralize the acid? Explain why?