A11 Paper #6064 Disclaimer — This paper partially fulfills a writing requirement for first year (freshman) engineering students at the University of Pittsburgh Swanson School of Engineering. This paper is a student, not a professional, paper. This paper is based on publicly available information and may not be provide complete analyses of all relevant data. If this paper is used for any purpose other than these authors’ partial fulfillment of a writing requirement for first year (freshman) engineering students at the University of Pittsburgh Swanson School of Engineering, the user does so at his or her own risk. QUANTUM DOT SOLAR CELLS AS AN ALTERNATIVE TO CURRENT SOLAR TECHNOLOGY Alexander Houriet, ach75@pitt.edu, Sanchez 10:00, Bryan Welsh, bpw13@pitt.edu, Mahboobin 10:00 Revised Proposal — As the world continues to develop and grow at record rates, the need for a universal cheap, green energy source becomes ever more apparent. The use of quantum dot solar cells, QDSC’s, as an alternative to current dye-sensitive solar panels, could be the answer to this problem. Quantum dot solar cells are relatively new technology in the world of solar energy, and have only begun to see real attention and growth in the last six or seven years [1]. The main technology driving QDSC’s is the use of chemistry to coat a colloidal quantum dot with thin layers of light sensitive chemicals. The resulting product is a small, lightweight, and cheap solar cell [2]. The use of quantum dots allows the solar cells to be tunable to a wider range of light frequencies than other solar cells, increasing its potential efficiency to levels previously thought of as impossible [3]. In our paper, we will discuss and weigh the various advantages and disadvantages of QDSC’s, and provide our reasoning for supporting the technology as important. While they have promising theoretical efficiencies in the range of 4560%, outputs have never been achieved above 10% [4]. Therefore, a major component of our research will be devoted to determining the processes for increasing efficiency, and estimating how long the theoretical efficiency will likely take to be reached. We also plan to heavily research information about the cost effectivity of QDSC’s, since they would need to be an economically feasible option if they are to become the main generator of power for any large area. From our initial research it seems they are cost effective, but more information needs to be gathered for the sake of thoroughness [3]. We will be conducting research through the use of database journals and articles, all of which must be peer-reviewed and accepted as scholarly work. This topic is important not only to us, but to all members of our audience. It is important to current engineers and faculty as they have the power to continue research on perfecting and increasing the efficiency of QDSC’s. It is important to other engineering students to become educated about the future of energy in their lives, and it is important to other interested professionals due to the potential for QDSC’s to revolutionize the solar industry and greater energy industry. If the United States was able to capitalize on the opportunity of this technology, they could theoretically achieve energy independence. Given sufficient development time and University of Pittsburgh Swanson School of Engineering 1 January 29, 2016 resources, quantum dot solar cells can become the answer to powering communities across the United States and across the globe in an environmentally friendly manner. REFERENCES [1] “The History of Solar.” U.S. Department of Energy. (online factsheet). https://www1.eere.energy.gov/solar/pdfs/solar_timeline.pdf [2] C. Chuang, P. Brown, V. Bulovic, M. Bawendi. (06 December 2013). “Improved performance and stability in quantum dot solar cells through band alignment engineering.” Nature Materials. (online article). http://www.nature.com/nmat/journal/v13/n8/full/nmat3984.ht ml [3] H. Kim, J. Kim, C. Kumar, D. Punnoose, S. Kim, C. Gopi, S. Rao. (18 December 2014). “Facile chemical bath deposition of CuS nano peas like structure as a high efficient counter electrode for quantum-dot sensitized solar cells.” Journal of Electroanalytical Chemistry. (online article). http://www.sciencedirect.com/science/article/pii/S157266571 4005542 [4] F. Xu, X. Yang, S. Luo, Z. Lv, T. Yang. (3 October 2014). “Enhanced performance of quantum dot solar cells based on type II quantum dots.” Journal of Applied Physics. (online article). http://dx.doi.org/10.1063/1.4895476 ANNOTATED BIBLIOGRAPHY L. Chen, Y. Yin, T. Ho, Y. Chen. (June 2014). “Sensitized Solar Cells via Nanomaterials: A Recent Development in Quantum Dots-Based Solar Cells.” IEEE Nanotechnology Magazine. (online database article). http://ieeexplore.ieee.org/stamp/stamp.jsp?tp=&arnumber=68 09959 This is a peer-reviewed article that was published by IEEE. While this article talks about QDSC’s, the underlying focus is about the big picture of the energy economy in the world, and the importance of developing a strong renewable solar option for the benefit of humanity in the near and far future. This article will be useful for us because it gives valuable data about Alexander Houriet Bryan Welsh the world’s energy needs and puts a strong valuation on solar energy. use this source to discuss a potential direction for the future of QDSC production and innovation. C. Chuang, P. Brown, V. Bulovic, M. Bawendi. (06 December 2013). “Improved performance and stability in quantum dot solar cells through band alignment engineering.” Nature Materials. (online article). http://www.nature.com/nmat/journal/v13/n8/full/nmat3984.ht ml This article comes from an accredited journal and describes a new process for manufacturing quantum dot solar cells. Using their method of adjusting band alignments within the cell has yielded efficiencies of up to 9%. While it is still nowhere close to theoretical limits, it is still an improvement over solar panels used currently. The team from MIT has found several different ways of making these adjustments. This is important because recognizing that there are many ways to produce these cells is crucial to finding the best possible technology. “Solar Energy Development Environmental Considerations.” Solar Energy Development Programmatic EIS. (online article). http://solareis.anl.gov/guide/environment/ This article comes from the Argonne National Laboratory, a government agency and it outlines the environmental impact of solar energy. Some of these things include taking up land for solar farms. There is also some impact to the soil, due to the covered land. However, solar certainly does cut a ton of emissions from fossil fuels and its positives greatly outweigh the negatives in solar energy. Knowing the impact solar energy has from all angles, both good and bad is important because it allows us to make an informed decision for the future. H.L. Weng, H.Y. Ueng, C.P. Lee. (February 2015). “Efficiency of quantum dot solar cell enhanced by improving quantum dots performance.” Physica Status Solidi (A) Applications and Materials Science. (online database article). http://onlinelibrary.wiley.com/doi/10.1002/pssa.201431261/f ull This article is also scholarly, peer-reviewed, and has been published. The authors of this article focus specifically on enhancing the performance of the quantum dot portion of QDSC’s in order to improve overall efficiency. They plan to do this by altering the Quantum Dot to absorb a wider spectrum of light. We will use this article in the section for discussing another potential innovation options for the future of QDSC’s. A. El-Maaty Aly, A. Nasr. (2014). “Theoretical Study of OneIntermediate Band Quantum Dot Solar Cell.” International Journal of Photoenergy. (online database article). http://www.hindawi.com/journals/ijp/2014/904104/ This source is a scholarly, peer-reviewed article from an international journal. The main focus of the article is to talk about the maximum potential efficiency of QDSC’s and how that makes them a superior alternative to current photovoltaic technologies. We plan to use this source to talk about the endgoal for Quantum Dot Solar technology, and why we think it would be a strong investment in the long run. “The History of Solar.” U.S. Department of Energy. (online factsheet). https://www1.eere.energy.gov/solar/pdfs/solar_timeline.pdf This graphic was published by the United States Department of Energy. It gives a very broad timeline on the history of solar energy, dating all the way back to 700 B.C. to show how far the technology has come from its origin. It also offers a lot of information on important legislations and researchers in the field, crucial for background information. F. Xu, X. Yang, S. Luo, Z. Lv, T. Yang. (3 October 2014). “Enhanced performance of quantum dot solar cells based on type II quantum dots.” Journal of Applied Physics. (online article). http://dx.doi.org/10.1063/1.4895476 The Journal of Applied Physics is a well-known and respected journal. This article discusses the implementation of type II quantum dot solar cells, which also have the modified bands, but are made of other materials. Knowing the theoretical possibilities of these is an important promotion tool, even if those levels cannot be attained. They produce similar voltage levels, but have a theoretical efficiency of 63.2% once the perfect starting materials are found. H. Kim, J. Kim, C. Kumar, D. Punnoose, S. Kim, C. Gopi, S. Rao. (18 December 2014). “Facile chemical bath deposition of CuS nano peas like structure as a high efficient counter electrode for quantum-dot sensitized solar cells.” Journal of Electroanalytical Chemistry. (online article). http://www.nature.com/nmat/journal/v13/n8/full/nmat3984.ht ml This peer-reviewed scholarly article focuses on the specific process of ion deposition for the improvement of efficiency in quantum dot solar cells. They specifically describe the process required for creating cells in this way, and its benefits to overall efficiency. They also talk about current drawbacks of the process, such as reduced performance over time. We will University of Pittsburgh Swanson School of Engineering January 29, 2016 2