Material Name: Polyester Resin Material Safety Data Sheet ID: 2202
Issue Date: 01/10/01 Revision: 1.0100
Other Sections:
02 03 04 05 06 07 08 09 10 11 12 13 14 15 16
Section 1 - Chemical Product and Company Identification
Product Name Polyester Resin
CAS# Mixture/None Assigned
Generic Name Organic Resin
Formula Polymer
Chemical Name: Polyethylene terephthalate polymer
Hazard Label PET-001
Manufacturer Information
Johns Manville Engineered Products Group
Mats and Reinforcements Division
P.O. Box 5108
Denver, CO 80127, CO 80127
Telephone: 303-978-2000
Internet Address: http://www.jm.com
Emergency: 800-424-9300 (Chemtrec)
Trade Names: Polyester Resin Type (17,18,26,32,38)
Section 2 - Composition / Information on Ingredients
CAS #
Component
Percent
25038-59-9
Polyethylene terephthalate polymer (PET)
100
75-07-0
Acetaldehyde*
*
Additional Component Information
* May be released when product is heated above 383ºF (195ºC).
Section 3 - Hazards Identification
Emergency Overview
APPEARANCE AND ODOR: Product form varies: chips, dice noodles or lace.Colors vary:
milky white to black; several levels of translucence or luster.
Under normal conditions of use, this product is not expected to create and unusual emergency
hazards.
Polyesters can burn if exposed to flame.Molten polymer generates small amounts of volatile
degradation products (off-gases), one of which is acetaldehyde.Acetaldehyde vapors form
explosive mixtures with air that can spontaneously ignite (auto-ignite) at temperatures above
347ºF (175ºC).Combustion products may include compounds of carbon, hydrogen, and oxygen;
exact composition depends on conditions of combustion.
In the event of fire, use normal fire fighting procedures to prevent inhalation of smoke and gases.
Potential Health Effects
Summary
Nuisance dust hazards are associated with the dry resin.Heating resin above 383ºF (195ºC) may
cause gas and vapor that are potent irritants.
Inhalation
Irritation of the upper respiratory tract, coughing, and congestion may occur.
Skin
Molten resin will cause thermal burns.
Absorption
Not applicable
Ingestion
Not applicable
Eyes
Temporary irritation (itching) or redness may occur.
Target Organs
Upper respiratory passages, skin, and eyes.
Primary Routes of Entry (Exposure)
Respiratory system, skin, and eye.
Section 4 - First Aid Measures
First Aid: Inhalation
Remove to fresh air.Drink water to clear throat, and blow nose to remove dust.
First Aid: Skin
If contact with molten resin occurs the affected area should be flushed with plenty of
water.Prompt medical attention is advised for burns.
First Aid: Ingestion
Not applicable
First Aid: Eyes
Flush eyes with large amounts of water for 5-15 minutes.If irritation develops, or persists, seek
medical attention.
Section 5 - Fire Fighting Measures
Flash Point: Not applicable
Method Used: Not applicable
Upper Flammable Limit (UFL): Not applicable
Lower Flammable Limit (LFL): Not applicable
Auto Ignition: Not determined
Flammability Classification: Not determined
Rate of Burning: Not determined
General Fire Hazards
Polyesters can burn if exposed to flame.Molten polymer generates small amounts of volatile
degradation products (off-gases), one of which is acetaldehyde.Acetaldehyde vapors form
explosive mixtures with air that can spontaneoulsy ignite (auto-ignite) at temperatues above
175ºC (347ºF).Combustion products will be comprised of compounds of carbon, hydrogen, and
oxygen.The exact composition will depend on the conditions of combustion.
Hazardous Combustion Products
Acetaldehyde, carbon, hydrogen and oxygen.
Extinguishing Media
Class A or Class B fire extinguishers or water fog.
Fire Fighting Equipment/Instructions
Firefighters should wear full-face, self contained breathing apparatus and impervious protective
clothing.Firefighters should avoid inhaling any combustion products.
Section 6 - Accidental Release Measures
Containment Procedures
Sweep up small spills and put into an appropriate container.Stepping or walking on resin chips or
pellets can cause falls; avoid accumulation on floors and walkways.Pick up large pieces.
Clean-Up Procedures
Wastes are not hazardous as defined by the Resource Conservation and Recovery Act (RCRA;
40 CFR 261).Comply with state and local regulations for disposal of these products.If you are
unsure of the regulations, contact your local Public Health Department, or the local office of the
Environmental Protection Agency (EPA).
Section 7 - Handling and Storage
Handling Procedures
Customary personal hygiene measures, such as washing hands after working with these products
are recommended.
Storage Procedures
No special precautions are required.
Section 8 - Exposure Controls / Personal Protection
Exposure Guidelines
No information available for the product.
A: Component Exposure Limits
OSHA: 100 ppm TWA; 180 mg/m3 TWA
150 ppm STEL; 270 mg/m3 STEL B: Exposure Limits for Chemicals which may be
generated during processing
This material has no components listed.
PERSONAL PROTECTIVE EQUIPMENT
Personal Protective Equipment: Eyes/Face
Wear safety glasses with side shields.
Personal Protective Equipment: Skin
Leather or cotton gloves should be worn to prevent skin contact and irritation.
Personal Protective Equipment: Respiratory
Respiratory protection is not required when using this product.However, exposure to chemcial
substances may occur as a result of heating this resin.Use a NIOSH-approved full-face respirator
to protect against toxic gases.
Ventilation
Local exhaust ventilation should be provided at areas of cutting to remove airborne dust and
fibers.General dilution ventilation should be provided as necessary to keep airborne dust and
fibers below the applicable exposure limits and guidelines.The need for ventilation systems
should be evaluated by a professional industrial hygienist, while the design of specific ventilation
systems should be conducted by a professional engineer.
Personal Protective Equipment: General
Loose-fitting, long-sleeved clothing should be worn to protect the skin from irritation.Exposed
skin areas should be washed with soap and warm water after handling.
Section 9 - Physical & Chemical Properties
Appearance: Products in form of chips, dice noodles or lace. Colors range from
Odor: Odorless
milky white to black; variable translucence or luster .
Physical State: Solid
pH: Not applicable
Vapor Pressure: Not applicable
Vapor Density: Not
applicable
Boiling Point: Not determined
Melting Point:
260ºC/500ºF
Solubility (H2O): Nil
Specific Gravity: 1.331.45
Freezing Point: Not applicable
Evaporation Rate: Not
applicable
Viscosity: Not applicable
Percent Volatile: 0
VOC: Not applicable
Section 10 - Chemical Stability & Reactivity Information
Chemical Stability
This is a stable material.This product is not reactive.
Hazardous Decomposition
Combustion products will be comprised of compounds of acetaldehyde, carbon, hydrogen, and
oxygen.
Hazardous Polymerization
Will not occur.
Section 11 - Toxicological Information
Acute Toxicity
Acetaldehyde can cause irritation to eyes, nose and upper respiratory tract; eye, skin burns;
dermatitis; conjunctivitis; cough; central nervous system depressant/depression; delayed
pulmonary edema.
A: Component Analysis - LD50/LC50
Acetaldehyde* (75-07-0)
Inhalation LC50 Rat : 13300 ppm/4H
Inhalation LC50 Mouse : 23 gm/m3/4H
Oral LD50 Rat : 661 mg/kg
Oral LD50 Mouse : 900 mg/kg
Dermal LD50 Rabbit : 3540 mg/kg
Carcinogenicity
The Occupational Safety and Health Administration (OSHA), National Toxicology Program
(NTP), International Agency for Research on Cancer (IARC), and American Conference of
Governmental Industrial Hygienists (ACGIH) have not classified this product in its entirety as a
carcinogen.
A: Component Carcinogenicity
Suspect Carcinogen (Possible Select Carcinogen)
NTP:
Monograph 71, 1999; Supplement 7, 1987; Monograph 36, 1985 (Group 2B
(possibly carcinogenic to humans))
Chronic Toxicity
No long-term health hazards are associated withpolyester or polyethylene terephthalate polymer.
In animals acetaldehyde has caused: kidney, reproductive, teratogenic effects.The International
Agency for research on cancer classified acetaldehyde a Group 2B possible carcinogen.The
National Toxicology Program classifies it a suspect carcinogen.The American Conference of
Governmental Industrial Hygienists classified acetaldehyde an A3 animal carcinogen.
IARC:
Section 12 - Ecological Information
Ecotoxicity
No data available for this product.
A: Component Analysis - Ecotoxicity - Aquatic Toxicity
Section 13 - Disposal Considerations
US EPA Waste Number & Descriptions
This product is not regulated as a hazardous waste by the U.S.Environmental Protection Agency
(EPA) under Resource Conservation and Recovery Act (RCRA) regulations.
A: Component Waste Numbers
Disposal Instructions
Dispose of waste material according to Local, State, Federal, and Provincial Environmental
Regulations.
Section 14 - Transportation Information
US DOT Information
Shipping Name: This product is not classified a hazardous material for transport.
Section 15 - Regulatory Information
US Federal Regulations
No information on this product as a whole.
A: Component Analysis
This material contains one or more of the following chemicals required to be identified under
SARA Section 302 (40 CFR 355 Appendix A), SARA Section 313 (40 CFR 372.65) and/or
CERCLA (40 CFR 302.4).
CERCLA: final RQ = 1000 pounds (454 kg)
State Regulations
No information available for the product.
A: Component Analysis - State
The following components appear on one or more of the following state hazardous substances
lists:
Component
CAS #
CA
FL
MA
MN
NJ
Acetaldehyde*
75-07-0
Yes
Yes
Yes
Yes
Ye
The following statement(s) are provided under the California Safe Drinking Water and Toxic
Enforcement Act of 1986 (Proposition 65):
WARNING! This product contains a chemical known to the state of California to cause cancer.
Other Regulatory Information
No information available for the product.
A: TSCA Status
This product and its components are listed on the TSCA 8(b) inventory. None of the components
listed in this product are listed on the TSCA Export Notification 12(b) list.
B: Component Analysis - Inventory
Component
CAS #
TSCA
DSL
EIN
Polyethylene terephthalate polymer (PET)
25038-59-9
Yes
Yes
No
Acetaldehyde*
75-07-0
Yes
Yes
Yes
A: Component Analysis - WHMIS IDL
No components are listed in the WHMIS IDL.
Section 16 - Other Information
Other Information
Prepared for:
Johns Manville Engineered Products Group
Mats & Reinforcements Division
P.O. Box 5108
Denver, CO 80217-5108
Prepared by:
Johns Manville Technical Center
P.O. Box 625005
Littleton, CO USA 80162-5005
The information herein is presented in good faith and believed to be accurate as of the effective
date given.However, no warranty, expressed or implied, is given.It is the buyer's responsibility to
ensure that its activities comply with Federal, State or provincial, and local laws.
Date
MSDS #
Reason
08/01/00
2202-1.0000
New MSDS authoring system.