Polarity and Intermolecular Forces Unit November 2-10 (2015) Day 1: VSEPR Lab Objectives (SWBAT): Physical Science 9- explain, predict, and draw VSEPR models for various covalent compounds Evaluated by: VSEPR Lab Class structure: Do Now: Draw the Lewis Dot diagram from NH4+. 1. Engage- Answer the pre-lab questions to begin thinking of structure as 3D. 2. Explore- Draw each of the Lewis structures (structural formulas) in question four then use the gumdrops and toothpicks to model these structures in 3 dimensions. 3. Explain- Students will draw the molecular geometry of the gumdrop models they’ve made then use the VSEPR shapes worksheet to name each of these structures. 4. Elaborate- Students will draw the Lewis structures of four additional compounds and predict their geometries without the gumdrops. The teacher will explain the effect of lone pairs on structure. Summary: VSEPR theory explains the shape of molecules in three dimensional space and assumes that electron pairs repel each other as far as possible. This creates either a linear, bent, trigonal planar, tetrahedral, trigonal bipyrimidal, or octahedral shape. Day 2: VSEPR Lab Continued Objectives (SWBAT): Physical Science 9- explain, predict, and draw VSEPR models for various covalent compounds Evaluated by: VSEPR Lab Class structure: Do Now: Draw the structural formulas for the seven compounds on page three of the lab. 1. Engage- Students will use gumdrops and toothpicks to model their Lewis structures in three dimensions then draw these in the column for molecular geometry. 2. Explore- Students will use new vocabulary (lone pairs and steric numbers) with the VSEPR shapes worksheet to write out the electron geometry and name the 3D model. 3. Explain- Students will draw the Lewis structures of two additional compounds and predict their geometries without the gumdrops. The students will then compare the predicted bond angles to explain the effect of lone pairs on the structure of a compound. 4. Elaborate- Students will draw the structural and molecular geometries for more complex compounds to complete the post-lab. Summary: Each pair of electrons on the central atom acts as another attached atom and under VSEPR theory, all atoms on the central atom repel to be as far away from each other as possible. This determines the 3D structure of a compounds which in turn affects its properties. Day 3: Polarity Objectives (SWBAT): Physical Science 22- predict the bond that will form between two elements based on electronic structure and electronegativity (ionic, polar covalent, or nonpolar covalent) Evaluated by: Polarity of Molecules Worksheet Class structure: Do Now: Draw the structural and molecular formulas for CO2 and H2O. 1. Engage- Students will explain why despite both compounds in the Do Now having 2 bonded atoms, one’s 3D geometry is linear and one is bent. The teacher will assign vocabulary to this difference a. Polar: an asymmetrical covalent compound that has an uneven charge distribution; one section of the compound is more negative than the rest giving the compound a partial positive side and partial negative side. b. Nonpolar: a symmetrical covalent compound that has even charge distribution. 2. Explore- Students will draw structural and molecular formulas for ten different compounds and use these pictures to determine symmetry and polarity. 3. Explain- Students will pair/share answers to check their work then the teacher will explain how to recognize whether a bond is polar or nonpolar (this is different than determining whether a compound is polar or nonpolar). Students calculate electronegativity differences in each bond of the classwork page and use this information to identify whether each bond is polar or nonpolar. 4. Elaborate-Students will draw the structural formulas, determine symmetry, and determine compound polarity for the compounds on the polarity of molecules homework sheet. Students will also highlight any polar bonds determined by electronegativity. Summary: Covalent compounds can be classified as polar (if the compound lacks overall symmetry) or nonpolar (if the compound is symmetric overall). Bonds can be classified as polar or nonpolar based on differences in electronegativity. Polar covalent bonds have a difference between 0.5 and 1.9 while nonpolar covalent bonds are different by less than 0.5. Day 4: Intermolecular Forces Objectives (SWBAT): Physical Science 24- Predict types of intermolecular forces present in molecules and rank these forces by strength Physical Science 46- Describe the influence of intermolecular forces on the physical and chemical properties of covalent compounds Evaluated by: IMF pre-lab Class structure: Do Now: Draw one polar and one nonpolar compound each with carbon as the central atom. Justify your drawing in terms of symmetry. 1. Engage- NOTES: Intermolecular forces (IMF) a. Ion-Ion force (electrostatic force): present between ionic compounds- the positive ion is very strongly attracted to the negative ion and vice versa b. Hydrogen bond: present between polar covalent compounds that contain a highly electronegative element (N, O, F, Cl, Br, and I)- The uneven charge distribution leaves Hydrogen with a partial positive charge and the other element with a partial negative charge. The partial negative charge on this element is strongly attracted to the partial positive charge on the hydrogen of a neighboring compound and vice versa. c. Dipole-Dipole Force: present between polar covalent compounds- The uneven charge distribution leaves one element with a partial positive charge and another element with a partial negative charge. The partial negative charge on this element is attracted to the partial positive charge on a neighboring compound and vice versa. d. London Dispersion Force: present between nonpolar compounds- The even charge distribution means that there is no partial positive or partial negative portion of the compound. Instead, neighboring compounds are only attracted to each other when the random movement of electrons causes one section of a molecule to be more negative than another and the same thing happens in a neighboring compound at the same time. At this point, the compounds’ positive and negative portions are attracted to each other. This is a very weak force. 2. Explore- Students will use the classwork sheet from day 3 to practice identifying IMFs. 3. Explain- Students will pair/share their answers then, as a group, try to order these compounds from strongest attraction to weakest attraction. 4. Elaborate- Students will complete the pre-lab for day 5’s IMF lab. Summary: There are four types of intermolecular forces that, in order from weakest to strongest, include Dipole interactions, London Dispersion forces, Hydrogen bonds and Ionic bonds. Day 5: Intermolecular Forces Lab Objectives (SWBAT): Physical Science 24- Predict types of intermolecular forces present in molecules and rank these forces by strength Physical Science 46- Describe the influence of intermolecular forces on the physical and chemical properties of covalent compounds Evaluated by: IMF lab Class structure: Do Now: Get into safety compliance (goggles, aprons, sleeves, hair, and shoes) while your pre-lab is checked. 1. Engage- The class will review lab safety and buret usage. Remember these chemicals are flammable and several have strong odors- be safe or be banned from labs. 2. Explore- Students will follow the steps at the stations around the room and record observations about polarity, surface tension, evaporation rate, and boiling point. (approximately 8 minutes per station) 3. Explain- Students will explain their results in terms of intermolecular forces. 4. Elaborate- Students will compare their predictions to their results by answering the post-lab questions. Summary: Covalent compounds have a lower melting point and boiling point than ionic compounds because the ionic bond is the strongest of the four bond types. The stronger the force holding the molecule together, the higher the melting point, higher the surface tension, and longer evaporation rate. Day 6: Review and Tie the Lab in Objectives (SWBAT): Physical Science 24- Predict types of intermolecular forces present in molecules and rank these forces by strength Physical Science 46- Describe the influence of intermolecular forces on the physical and chemical properties of covalent compounds Evaluated by: IMF flipbook Class structure: Do Now: Which compounds, CBr4 or HBr would have a higher boiling point and why? 1. Engage- Students will compare the properties of ionic and covalent compounds then relate this to the structure and IMFs of these compounds. 2. Explore- Students will make a flip book for each of the four intermolecular forces (ion-ion, hydrogen bond, dipole-dipole, and London Dispersion Force) that orders the forces by strength then gives an example, states how to recognize the force, defines the force, and describes the effect on the properties of the compound. 3. Explain- The teacher will review the vocabulary on day 7’s test then provide each group with a set of practice problems. The group will complete the problems then come to the board to explain their answer to the class. 4. Elaborate- Students will continue to study the material at home for day 7’s test. Summary: Covalent compounds are weak than ionic compounds but there are differences among covalent compounds that stem from differences in their three dimensional structure. Unlike ionic compounds which are all held together by strong ion-ion forces (electrostatic attraction) and have a crystalline structure. Covalent compounds share electrons and the evenness of this sharing affects the properties. If the electrons are shared evenly (nonpolar), there is nothing attracting one molecule to another, leading to low surface tension, quick evaporation/boiling (low boiling point and high evaporation rate). If the electrons are shared unevenly (polar) or very unevenly (hydrogen bond), there is a partial positive side to the compound and a partial negative side to the compound which leads to one molecule attracting another. This attraction holds the molecules together leading to high surface tension and slow evaporation/boiling (high boiling point and low evaporation rate). Day 7: Test- Polarity and IMF Objectives (SWBAT): Physical Science 5, 9, 13, 16, 22, 23, 24, and 46- Demonstrate at least 75% proficiency over the material from this unit. Evaluated by: Test- Polarity and IMF Class structure: Do Now: Take out a calculator and something to write with, open your binder to the table of contents and place it on the back bench, move your bags to the A/C, and clear your calculator RAM TEST Summary: This unit built on the last unit (Lewis Structures) and the previous unit (Periodic Table) and we will continue to build on this information with the next unit (Naming) and every unit after that. Do not get behind or allow yourself to let information fall to the back of your mind. If you keep reviewing this material and asking questions when you do not understand, the class will be much easier for you as we move forward. GLE Objective Day(s) Addressed Physical Science 9 Draw accurate valence electron configurations and Lewis dot diagrams for selected molecules, ionic and covalent compounds, and chemical equations 1, 2, 3, 4 Physical Science 13 Identify the number of bonds an atom can form given the number of valence electrons 1, 2, 3, 4 Physical Science 22 Predict the kind of bond that will form between two elements based on electronic structure and electronegativity of the elements 3, 4 Physical Science 23 Model chemical bond formation by using Lewis dot diagrams for ionic, polar, and nonpolar compounds 1, 2, 3, 4 Physical Science 24 Describe the influence of intermolecular forces on the physical and chemical properties of covalent compounds 4, 5, 6 Physical Science 46 Identify and compare intermolecular forces and their effects on physical and chemical properties 4, 5, 6 Vocabulary Structural Formula Polar Dipole-Dipole Molecular Geometry Nonpolar London Dispersion Force Electron Geometry Ion-Ion Force (electrostatic) Intermolecular Force VSEPR Theory Hydrogen Bond Assessment Design- Unit 7 Basic: 6 Questions Standard: 12 Questions Essential Skills and Learning Objectives Expanded: 6 Questions Type of Question (MC, CR, P) Basic (Remember & Understand) Standard (Apply & Analyze) Expanded (Evaluate & Create) Draw accurate Lewis dot diagrams for selected molecules 1 MC 3 CR 1 CR Model chemical bond formation of polar and nonpolar compounds through VSEPR 2 MC 3 CR 1 MC 2 CR Predict the kind of bond (polar, nonpolar, ionic) that will form between two elements based on electronic structure and electronegativity of the elements 1 MC 2 CR 1 CR Identify and compare intermolecular forces and their effects on physical and chemical properties 2 CR 1.5 CR 2 MC 1.5 CR 1 MC