Name: _____________________________________________ Date: ___________________________ Period: ________ Unit 5 Test Study Guide Nuclear & Quantum Chemistry Nuclear Equations Write nuclear equations for the following scenarios: 1. Alpha emission by plutonium-239, one of the substances formed in nuclear power plants. 2. Beta decay by sodium-24, used to detect blood clots 3. Oxygen-15 undergoes positron emission, used to assess the efficiency of the lungs. 4. Copper-64 goes through electron capture, used to diagnose lung disease. 5. A radioactive isotope is bombarded with an alpha particle to produce Polonium-84. 6. A silver-117 undergoes three beta emissions before it reaches a stable nuclide. What is the final product? Complete the following nuclear equations and identify which type of nuclear decay it is. 90 7. Sr 90 Y + ____ This is ___________________________________. 38 39 17 8. F 17 O + ____ This is ___________________________________. 9 8 9. 222 Rn 86 218 Po + ____ 84 10. 18 F + _____ 9 11. 235 U 92 12. 118 Xe 54 _______ + _____ 13. 204 Sr 84 + 18 O 8 42He + ____ 0 e −1 ____ This is ___________________________________. This is ___________________________________. This is ___________________________________. This is positron emission. This is ___________________________________. Radioactivity & Half-Lives 14. One of the radioactive nuclides formed in nuclear power plants is hydrogen-3, called tritium, which has a halflife of 12.26 years. How long before a sample decreases to 1/8 of its original amount? 15. Uranium-238 is one of the radioactive nuclides sometimes found in soil. It has a half-life of 454 years. What percentage of a sample is left after 2270 years? 16. Cesium-133, which is used in radiation therapy, has a half-life of 30 years. What was the size of the original sample if after 120 years you now have 16.0 grams? 17. Phosphorus-32, which is used for leukemia therapy, has decayed to 1/16th of its original amount in 42.9 days. What is the half-life of phosphorous-32? 18. Iodine has a half-life of 8.07 days. Assuming you start with 90.5 grams, how much of the sample (in mg) would you have left after 24.21 days? Bohr Model Diagrams In the Bohr model diagrams show below, indicate the number of protons (p) and neutrons (n) in the nucleus of each atom. Write the number of electrons (e) on each energy level. Not all energy levels will be used for every element. 19. (a.) silicon-30 (b.) calcium-41 Electromagnetic Spectrum 20. List the seven colors of the visible spectrum from shortest to longest wavelength. __________________________________________________________________________________________ 21. What is the wavelength range of visible light? _____________ nm to ______________ nm. 22. Draw your interpretation of a long wavelength (above the time frame) and a short wavelength (below the time frame). Indicate which has higher frequency and higher energy. 23. 10 second time frame (a) Which has a longer wavelength, orange or blue? _____________________________ (b) Which has a lower frequency, green or red? _________________________________ (c) Which has more energy, indigo or yellow? __________________________________ Quantum Mechanics Explain each of the following rules or terms associated with quantum mechanics. 24. Hund’s Rule __________________________________________________________ 25. Aufbau Principle __________________________________________________________ 26. Pauli Exclusion Principle __________________________________________________________ 27. Heisenberg’s Uncertainty Principle __________________________________________________________ 28. orbital __________________________________________________________ 29. identify the three (of the four) quantum numbers _____________________________________________ Orbital Diagrams Draw the orbital diagrams (boxes and arrows) for each of the following elements. 30. silicon 31. zinc Electron Configuration 32. Identify the element described by each electron configuration. (a.) 1s22s22p63s2 _________________ (b.) 1s22s22p63s23p64s23d104p65s24d3 _________________ (c.) 1s22s22p63s23p64s23d8 _________________ (d.) [Kr] 5s24d6 _________________ (e.) [Ar]4s23d104p4 _________________ Electron Configuration Continued 33. Write the full electron configuration for the following atoms/ions (do NOT use the Noble Gas shortcut method). (a.) P ____________________________________________________________________________ 34. (b.) Y ____________________________________________________________________________ (c.) Ca+2 ____________________________________________________________________________ (d.) Br- ____________________________________________________________________________ Write the Noble Gas (shortcut) electron configuration for each of the following. (a.) Te ______________________________________________________________________________ (b.) Sb ______________________________________________________________________________ (c.) Bi ______________________________________________________________________________ Relating Bohr’s Diagram and Electron Configurations to the Quantum Numbers 35. Which quantum number tells you the main energy level? _______ 36. In the atom, 1s22s22p4 – what is the highest every level that holds an electron? _______ 37. How many orbitals are in the p-sublevel? ________ How many electrons? ________ 38. How many orbitals are in the d-sublevel? ________ How many electrons? ________ 39. Which quantum mechanical principle states that (choose from Pauli Exclusion Principle, Aufbau Principle, and Hund’s Rule): (a) electrons will fill orbitals from lowest to highest energy? _________________________ (b) no two electrons can have the same set of quantum numbers? __________________________ (c) electrons will avoid pairing in an orbital if an orbital of equal energy is available? (the sharing rule) _________ 40. How many electrons can be accommodated in each of the following: (a) one d orbital _______ (b) a set of f orbitals _______ (d) the 7s orbital ______ (c) the n = 4 shell _______ (e) one p orbital ______ Important Vocabulary & Concepts to review Define the following words Trajectory ______________________________________________________________________________ quantum ______________________________________________________________________________ entail ______________________________________________________________________________ valence electrons ________________________________________________________________________ frequency ______________________________________________________________________________ Wavelength ______________________________________________________________________________ Explain the following concepts (you can use words and pictures) 1. Nuclear decay 2. Radioactivity 3. Radioactive particle 4. Half-Life 5. Fission 6. Fusion 7. Electron orbital diagram 8. Electron configuration 9. Bohr model of the atom 10. The relationship between wavelength, frequency and energy 11. The relationship between energy levels, sublevels and orbitals 12. The relationship between an element’s electron configuration & its position on the periodic table