S3 – Revision Notes and Summer Assignment The concepts listed below are some of the basics which are essential for the learning of chemistry. All students taking chemistry in S4 are expected to revise and master them during the summer so as to secure a solid foundation in chemistry. All these concepts will be assessed in the first week of September. 1. Classify common elements as metals or non-metals 2. Write names and chemical symbols for the first 20 elements 3. Show by means of numbering and electron diagram the electronic arrangements of elements with atomic numbers 1 to 20 4. Define period and group of an element in the Periodic Table 5. Remember the order of the first 20 elements 6. Recall the period and group to which an element of known atomic number belong 7. Describe the group trend of group I, II, VII and O. 8. Understand that metal atoms tend to lose electrons, forming positive ions 9. Understand that non-metal atoms tend to gain electrons, forming negative ions 10. Understand that ionic bond is formed by complete transfer of electrons 11. State the formulae of common ions (see the table on P.2) 12. Deduce the chemical formulae of ionic compounds. 13. Draw electron diagrams to show the formation of ions 14. Draw electron diagrams of ionic compounds 1 Common Ions (*** VERY VERY IMPORTANT ***) Positive ion (Cation) Name Ion of group I element Negative Ion (Anion) formula potassium ion K sodium ion Na Name Ion of group VII element formula fluoride ion F chloride ion Cl bromide ion Br I iodide ion Ion of group II element magnesium ion Mg 2 calcium ion Ca 2 Ion of group III element aluminium ion Al 3 copper (I) ion Cu copper (II) ion Cu 2 lead (II) ion Pb 2 Ion of transition iron (II) ion metal which forms more than 1 type iron (III) ion cobalt (II) ion of ion Fe 2 nickel (II) ion Ni 2 Fe 3 Name of cation: S Ion of group V element nitride ion N 3 phosphide ion P 3 hydroxide ion OH nitrate ion NO3 nitrite ion NO2 sulphate ion SO4 Polyatomic anion sulphite ion SO3 carbonate ion CO3 hydrogencarbonate ion HCO3 permanganate ion MnO4 dichromate ion Cr2O7 Ag Ion of transition silver ion metal which forms zinc ion only 1 type of ion non-metal cation sulphide ion Co 2 Cr 3 O 2 manganese (II) ion Mn chromium (III) ion oxide ion Ion of group VI element Zn 2 hydrogen ion H ammonium ion NH4 use the name of the element Note: Some elements can forms more than one type of ions. For example, copper forms Cu+ and Cu2+ ions. To distinguish them, their names must indicate the charge they carry. Name of anion: (i) For simple ion: end with “ide” (ii) For polyatomic ion: names depend on the composition of ion e.g. containing O, end with “ate” or “ite”. The polyatomic anion with more O is named as –ate, and that with less O as -ite, e.g. SO4 sulphate, SO3 sulphite. 2 Block: __________ Class: _________ Name: _____________________________ Exercise (To be submitted in the first chemistry lesson after the summer holiday) 1. Give the chemical symbols for the following elements and classify them as metal, non-metal or semi-metal. a) Oxygen h) Silicon b) Calcium i) Chlorine c) Sulphur j) Phosphorous d) Carbon k) Beryllium e) Neon l) Aluminium f) Sodium m) Hydrogen g) Boron n) Argon 2. Give TWO examples of elements for each of the following. a) Group I e) b) Group II f) c) Group III g) d) Group IV h) Group V Group VI Group VII Group 0 3. For each of the elements below, state its group number (without referring to Periodic Table). a) Carbon k) Nitrogen b) Fluorine l) Sodium c) Magnesium m) Sulphur d) Nitrogen n) Lithium e) Iodine o) Calcium f) Oxygen p) Silicon g) Helium q) Phosphorous h) Aluminium r) Chlorine i) Potassium s) Argon j) Boron 4. Give the chemical formula for each of the following ions (without referring to reference materials). a) Sulphide ion l) Permanganate ion b) Calcium ion m) Dichromate ion c) Oxide ion n) Sulphate ion d) Sodium ion o) Hydroxide ion e) Nitride ion p) Sulphite ion f) Chloride ion q) Carbonate ion g) Magnesium ion r) Hydrogencarbonate ion h) Phosphide ion s) Ammonium ion i) Fluoride ion t) Nitrate ion j) Calcium ion u) Nitrite ion k) Potassium ion 3 5. State the number of protons, neutrons and electrons for each of the following Number of protons a) 81 35𝐵𝑟 b) 81 − 35𝐵𝑟 c) 55 25𝑀𝑛 d) 55 2+ 25𝑀𝑛 e) 1 + 1𝐻 f) 127 − 53𝑋 g) 127 + 53𝑌 Number of neutrons Number of electrons Steps for drawing electron diagram 1. 2. State the symbol of the metal and non-metal respectively. Recall the group to which each belongs, hence work out the number of electrons to be lost or gained to obtain noble gas electronic structure. Hence, represent the electrons in the outermost shell of the ions using symbols and . 3. State the charge of the ions formed on the top right hand corner. For metal ion: positively charged. For non-metal ion: 4. negatively charged. Deduce the ratio of the ions in the formulae so that the total positive charges balance that of negative charges. 4 5. Draw the electron diagrams for each of the following ionic compounds. In all cases, show only the outer-shell electrons. Compound Electron Diagram of Ionic Compound Chemical formula a) calcium bromide b) magnesium oxide c) aluminium oxide d) sodium sulphide e) calcium nitride 5 Steps for Deducing Chemical Formulae of Ionic Compounds using the “Cross Method” e.g. Give the formula of ionic compound formed by magnesium and chlorine. Step 1 : State the formulae of the ions Step 2: Copy the numerical value of the charge to the diagonals as shown as subscripts Step 3: Rewrite the formula (i) with the charge omitted. (ii) The subscripts of should be simplified to simplest ratio (iii) Brackets are only used if there is more than 1 polyatomic ion in the formula Example 1 Magnesium chloride Mg2+ and Cl- Mg2+ Example 2 Calcium oxide Ca2+ and O2- Cl - Ca2+ 2 2 1 MgCl2 O22Ca2O2 CaO Example 3 Calcium hydroxide Ca2+ and OH- Ca12+ OH- 2 Ca(OH)2 *bracket is needed for OH- as 2 polyatomic ion (hydroxide ions)are involved. 6. Give the chemical formulae of the following ionic compounds a) Magnesium oxide m) Calcium nitrate b) Potassium chloride n) Sodium hydroxide c) Aluminium oxide o) Aluminium sulphate d) Magnesium bromide p) Iron (II) hydroxide e) Calcium nitride q) Iron (III) oxide f) Calcium carbonate r) Copper (II) sulphate g) Ammonium chloride s) Lithium oxide h) Sodium sulphate t) Calcium chloride i) Magnesium hydroxide u) Magnesium sulphate j) Calcium hydrogencarbonate v) Potassium dichromate k) Sodium carbonate w) Potassium permanganate l) Ammonium dichromate x) Sodium sulphite 6