Shear banding behaviour of a multifunctional titanium alloy during high strain rate deformation Xianghai An a, Emmanuel Flores Johnson b, Yulin Hao c, Luming Shen b and Xiaozhou Liao a* aSchool of Aerospace, Mechanical & Mechatronic Engineering, the University of Sydney, NSW 2006, Australia bSchool of Civil Engineering, the University of Sydney, NSW 2006, Australia cShenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, People’s Republic of China Contact's e-mail address: xianghai.an@sydney.edu.au Abstract: As an emerging class of multifunctional titanium alloys, Gum Metals with the single body-centre cubic phase possess superior mechanical properties, including the combination of low Young’s modulus, large-scale non-linear elasticity and high strength, which are not possible in conventional materials. These extraordinary properties are attributed to their unique deformation through mechanisms that include ideal shear deformation, nanodisturbance and conventional dislocation slip, twining, and phase transformation. Details of the deformation mechanisms of Gum Metals have not been fully understood. In this research, we explore the deformation mechanisms of a Gum Metal under high strain rates, focusing more on its shear banding behavior. A typical Gum Metal, Ti–24Nb–4Zr–7.9Sn (wt%) alloy was selected and processed by hot rolling and annealing to acquire microstructures with a bimodal grain size distribution and with large uniform grains, respectively. The two types of samples were deformed under the strain rates of ~2700 s-1 and 5500 s-1 using a split Hopkinson compression bar. Microstructural characterisation was conducted using electron backscatter diffraction and transmission electron microscopy. It was found that the strength of the two types of samples is significantly enhanced when the materials are deformed under high strain rates. Both materials are susceptible to adiabatic shear banding. Different microstructures presented in the shear bands in the two types of samples. Uniform equiaxed dynamic recrystallized grains were seen in the annealed sample. The microstructures in the shear bands in the hot rolled sample are highly sensitive to the shear band position: very fine dynamic recrystallized grains elongated along the shear banding direction presented in areas away from shear cracks, while both equiaxed grains and very fine elongated grains co-existed in areas near shear cracks. The effects of original microstructures on the microstructural evolution in shear bands will be discussed in details.