Problem HY.5 Questions team_name date 0. What is the reactor duty in kJ/h for this isothermal process? Is the chemical reaction endothermic or exothermic? Must heat be added to or removed from the reactor? The reactor duty is __________ kJ/h. Since it is ________ in value, the chemical reaction is ___________, and thus heat must be ______________ the reactor. 1. For the adiabatic reactor in the HYSYS session, only a vapor product stream was needed since the flow rate of the liquid was zero. For the isothermal case, both a vapor and a liquid product stream are required. Why? The exiting material at 25°C and 1 atm has two phases—vapor and liquid—since its ____________ is below the _____ point of __________°C. Above what reactor exit temperature will only a vapor product stream be required? Only a single phase of _______ for the product stream will exist above ________°C. 2. What is the acrylonitrile composition in the liquid product stream in mole fraction? In mass fraction? In parts per million (ppm)? In kg/m3? In kgmol/m3? In molarity (M)? xL , AN ____________ ______ of acrylonitrile per ______ of Stream L wL , AN ____________ ____ of acrylonitrile per ____ of Stream L ppm _____________ (____ of acrylonitrile per ____ of Stream L)×106 ____ __________ kg / h Cˆ L , AN VL , AN _________ m3 / h _________ kg / m ______ of acrylonitrile per ______ of Stream L 3 ____ __________ kgmol / h Cˆ L , AN VL , AN _________ m3 / h _________ kgmol / m M ________ kgmol ___ gmol m 3 ______ of acrylonitrile per ______ of Stream L 3 1 kgmol 1 m3 ___ L Molarity, ____ of acrylonitrile per L of Stream L ________ M Each property value was obtained by copying it from HYSYS and pasting it here. 3. What assumptions were used to solve the isothermal reactor simulation problem? continuous process _________________________ _________________________ _________________________ Page 1 of 3 Problem HY.5 Questions team_name date Compare these assumptions to those of the chemical reactor module in Appendix H of this instructional manual. Are the assumptions the same? If not, how do they differ? Compared to the reactor module in Appendix H, all but ____ of the assumptions are the _____. In Appendix H, the reactor is assumed to be an ________ process. 4. Write the total mole balance equation for the isothermal reactor problem. What are the value and units for the extent of reaction? ____________ 1 kgmol _______ _______ _______ _______ _______ h R _______ kgmol h 1 kg rxn nF _________________ 0 or R nV Each total molar flow value was obtained by copying it from HYSYS and pasting it here. What does the extent-of-reaction or R term in the total mole balance signify? Since __ molecules of products are formed for every __ molecules of reactants that react, a net of _____________ molecule is _________ per chemical reaction. 5. What is the energy relative imbalance (%RIB)? Show your calculations. The energy %RIB equals 100*(energy flow in – energy flow out) / (energy flow in). % RIBEB ___ ___ ___ ___ ___ EF E A 100 _______ _______ _______ _______ _______ kJ/h 100 _______ _______ kJ/h % RIBEB _______ % RIBEB Each energy flow value was obtained by copying it from HYSYS and pasting it here. In the HYSYS software, the Mass/Energy Balance page within the Flowsheet/Flowsheet Summary menu provides the relative imbalances for material and energy. 6. What is the material relative imbalance (%RIB) on a total molar basis? Show your calculations. The total molar %RIB equals 100*(total molar flow in – total molar flow out) / (total molar flow in). Page 2 of 3 Problem HY.5 Questions team_name ___ ___ ___ ___ % RIBMB nF nA date 100 _______ +_______ _______ _______ kgmol/h 100 _______ +_______ kgmol/h _______ % RIBMB % RIBMB Each total molar flow value was obtained by copying it from HYSYS and pasting it here. 7. What is the material relative imbalance (%RIB) on a total mass basis? Show your calculations. The material %RIB equals 100*(mass flow in – mass flow out) / (mass flow in). % RIBMB ___ ___ ___ ___ mF mA 100 ________ +________ ________ ________ kg/h 100 ________ +________ kg/h ________ ______ % RIBMB % RIBMB Each total mass flow value was obtained by copying it from HYSYS and pasting it here. How does this value compare with the %RIB on a molar basis? Explain. The relative imbalance based on total moles is ______%, while the relative imbalance based on total mass is _____%. Since total mass is ________ during chemical reactions, the relative imbalance based on total mass is the _____________ of the material relative imbalance. In general, total moles during chemical reactions are ____________, as indicated by the ______% and the fact that a net ______ of _____ molecule occurs per reaction event. Page 3 of 3