Activity Series of Metals: Designing and conducting an experiment In this lab, you will be designing your own procedure to determine an activity series given available metals and solutions. 1. Your procedure will have to be approved before you do your experiment. 2. You will have to record your observations and final results on a separate piece of paper. 3. Please answer all the questions below as well and hand in. 4. Do not forget to include a safety component in your lab. Materials You have the following metals and solutions available to you; you do not have to use all of them. Metals: Magnesium Zinc Tin Copper Aluminum powder Fe Solutions: Fe (NO3)3/ FeSO4 AgNO3 CuSO4 ZnSO4/Zn(NO3)2 Na2SO4/NaCl HCl KCl Ni(NO3)2 BaCl2 Al(NO3)3 Pre-lab questions: 1. If you use magnesium as one of the metals to test, why would you clean it with sandpaper first? When we use Mg as one of the metals to test. We would clean it with sandpaper first, because Mg has been lying in the lab and will likely have a thin layer or covering of oxygen. It will be magnesium oxide, which slow the reaction. 2. What equipment could you use to best see any chemical reactions? The equipment we use to best see any chemical reactions are: 2 spot plates, and 4 test tubes to observe the chemical reactions. We use pipet to drop enough of the solution on metal to cover it. We also use test tube holder to hold our test tubes. 2. What safety precautions do you need to follow when using HCl? What do the WHMIS symbols mean? We need to wear goggles to protect our eye from chemicals. We have to wear apron while we do the lab to keep from spilling chemicals in our body. We would wear gloves to protect our hands from acids. 3. How will you dispose of the chemicals once you are finished? We use a glass container to dispose the waste chemicals and gently wash the equipment after. We shouldn’t mix solids and liquids in the same container. We will leave the washed equipment in air to dry and nicely put them back on its spot. Analysis: 1. Record all of your observations in a table format and provide your final activity series (from the most reactive metal to the least) on a separate piece of paper (stapled to this one). 2. For each single displacement reaction that occurred, write the corresponding balanced chemical equation (on a separate sheet of paper). 3. How can an activity series of metals be use to predict single displacement reactions. Activity series of metals is from the most reactive to less reactive one. When a metal reacts with the given solution or displace the other metal in the solution will be conceder as a reactive metal than the one, which has been displaced. Less reactive element won’t replace the most reactive one. Therefore, the activity series or metals can be used to predict the happening of single displacement reactions. 4. Given that lithium reacts with water and that magnesium does not, do you expect lithium to react with HCl? If so, what would be the balanced chemical equation? Yes, lithium reacts with HCl, because Li is more reactive than H. 2Li(s)+ 2HCl(aq) → 2LiCl(s) + H2 (g) 5. What would your metal of choice be for long-lasting pipes in your home – copper or iron? Why? The metal of choice for long-lasting pipes in our home is copper, because copper doesn’t react with the water or acid remainders in the pipes. Copper is less reactive than H in the activity series of metals. We also know that iron is reactive than hydrogen in the activity series of metals, and it does react with water. Therefore, the best choice is copper for our home pipes. Observation: Fe(NO3)3 / FeSO4 Mg Zn - Change of colour, Mg turned to brown -Change of colour Zn got darker (blackish) Sn NR Al NR -Change of colour to light yellow -Bubbles formed -Blue colour of copper sulfate appears to fade -Change of colour –minor bubbles -Change of colour -Sn got darker or black NR ZnSO4/Zn (NO3)2 NR NR NR Na2SO4/NaCl KCl NR NR NR NR NR NR NR NR NR NR NR NR Ni(NO3)2 BaCl2 NR Al(NO3)3 HCl Fe -Cu colour changed to silver -Ag was collecting away AgNO3 CuSO4 Cu -Bubbles formed -Bubbles formed NR NR -Change of colour -Ni(NO3)2 turned light green NR -Change of colour -Ni(NO3)2 turned light green NR NR NR -Fizzes and gets hot -Change of colour, iron got darker Metals that displace other metals 3Mg + 2Fe(NO3)3 → Metals that don’t react Metals displace H Mg + Na2(SO4) → NR Sn+2HCl → SnCl2+ H2 Sn + Fe(NO3)3 → NR Zn+ 2HCl → ZnCl2+H2 Cu + BaCl2 → NR Fe+ 2HCl → FeCl2+ H2 Al + Fe(NO3)3 → Al(NO3)3 + Fe Mg + BaCl2 → NR Mg+2HCl →MgCl2+H2 Sn + CuSO4 → Sn(SO4) + Cu Mg + KCl → NR Fe + Ni(NO3)2 → Fe(NO3)2 + Ni Cu + HCl → NR 3Mg(NO3)2+2Fe 3Zn + 2Fe(NO3)3 → 3Zn(NO3)2 + 2Fe 2Al + 3Ni(NO3)2 → 2Al(NO3)3+3Ni Cu + AgNO3 → Cu(NO3) + Ag Activity Series Of Metals K, Ba, Na, Mg, Zn, Al, Fe, Ni, Sn, H, Cu, Ag Conclusion: Metal reactivity increases from bottom to the top of the periodic table of elements.