Science 8: Chapter 3 Naming polyatomic ions (notes) Polyatomic ions Prefix “poly” means many. A ____________________________ ion is an ion _________________________of more than one type of atom joined by ________________________ bonds. Polyatomic ions carry an _________________________ charge, they cannot exist on their own. Example of polyatomic ions: 1. 2. 3. 4. 5. hydroxide ion OH⁻ ammonium ion ________________ ________________________ NH₄⁺ carbonate ion ________________ ________________________ NO₃⁻ Use of polyatomic ions (Read page 79 and 80 to fill the table) Use 1. 2. 3. 4. 5. Tests for alcohol on driver’s breath Forms the delicate shell of an egg Major component of bones and DNA Forms fertilizers Forms the enamel of teeth Name of polyatomic ion dichromate ion Formula Cr₂O₇²⁻ Use phosphate ion (PO₄³⁻), as an example to answer the following questions 1. What kind of chemical bond holds each oxygen atom to the phosphorous atom? __________________________ 2. How many atoms does the phosphorous atom connect to? ___________________________________________ 3. What is the general term for an ion such as phosphate, which is a molecule that has an overall electric charge? _________________________________________________________________________________________ 4. In phosphate ion where are the covalent bonds and where are the ionic bonds? __________________________________________________________________________________________________________________ __________________________________________________________________________________________________________________ Science 8: Chapter 3 Naming polyatomic ions (notes) Rules for writing FORMULAS of a compound with polyatomic ions Steps sodium hydroxide 1. Identify each ion and its charge , using periodic table and the list of polyatomic ions 2. Determine total charge needed to balance positive and negative 3. Note the ratio of positive ions to negative ions 4. Use brackets and subscripts to write the formula. Omit brackets if only one ion is needed. Na⁺ OH⁻ Na⁺ = 1+ OH⁻ =1- 1 Na⁺ for 1 OH⁻ NaOH ammonium iron(III) potassium hydroxide hydroxide dichromate tin(II) nitrate ammonium sulfate Science 8: Chapter 3 Naming polyatomic ions (notes) Write the NAME of compounds with polyatomic ions Steps Cu(OH)₂ 1. Identify the positive copper(Cu) ion(using periodic table or polyatomic list) 2. Verify that it can form Cu ⁺ Cu ⁺² more than one kind of ion by checking the periodic table 3. Identify the negative OH⁻ ion (using the list of polyatomic ions) 4. Determine the ratio of ions in the formula Cu(OH)₂ means 1 Copper ion for every 2 OH⁻ ion 5. The positive and negative charges must balance out. Determine what the charge needs to be on the metal ion to balance the negative ion Each of the three copper ions must have a +1 charge to balance the 2 OH⁻ ions Therefore, copper(I) 6. Write the name compound in lower case copper(I) hydroxide MgSO₄ Ba₃(PO₄)₂ NH₄NO₃ Mn(ClO₃)₃ Science 8: Chapter 3 Naming polyatomic ions (notes)