Chemistry Review: 1st Quarter Name: _____KEY__________________ PART I: You should know the basics (terms & basic facts) about… Hypothesis theory law scientific method mass weight volume physical change chemical change mixture element compound molecule heterogeneous homogeneous states of matter Dalton’s Atomic Theory precision accuracy proton neutron Electron isotope atomic number mass number average atomic mass frequency wavelength photons Aufbau principle Pauli exclusion principle Ground state Excited state Energy level Orbitals Electron spin ion atom molecule compound alpha particles beta particles gamma ray Half-life fission fusion octet rule PART II - You should be able to complete the following problems (MUST SHOW WORK for MATH calculations) PHYSICAL OR CHEMICAL CHANGE boiling water: ___PHYSICAL____ burning wood: ____CHEMICAL___________ melting aluminum: __PHYSICAL____ EXTENSIVE OR INTENSIVE PROPERTIES Boiling point: __INTENSIVE_____ Volume: __EXTENSIVE___________ CONVERSIONS: Convert 54 millimeters to Megameters separating sand from water: _ PHYSICAL____ Energy (heat content): __EXTENSIVE________ Density: ____INTENSIVE___________________ 5.4 X 10-8 Megameters Convert 9.2 X 10-5 Kg to g. 0.092 grams Convert 1234 meters to miles 0.77 miles HINT Basic Conversion Units: 2.54cm = 1 inch, 0.946 L = 1 quart, 454 g = 1 lb, 1 mile = 5280 ft SIGNIFICANT DIGITS How many significant figures number are expressed in the following examples? 0.0003040 mm __4____ 29000. __5____ 9.10 x 1045 L __3______ 1.05 g __3____ Round 8.9456 to 3 significant digits: ___8.95_____ Round 513431 to 2 significant digits: _5.1 x 10 5_ or 510 000 Determine the answer for each of the following. Be sure to use the correct number of significant figures. 17.34 + 4.900+ 23.1 = __45.3__ 9.80 – 4.762 = ___5.04__________ 3.9 x 6.05 x 420 = __9900___ 14.1 / 5 = ___3__________________ COUNTING PROTONS, NEUTRONS, AND ELECTRONS HYPHEN NOTATION NUCLEAR SYMBOL 201 80 PROTONS NEUTRONS ELECTRONS CHARGE 4 5 0 47 61 0 16 17 -2 13 15 +3 Hg 48 60 28 36 +1 Ni 80 34 Se -2 16 8 O -2 BALANCE NUCLEAR REACTION EQUATIONS ANSWERS: Calcium-40, Magnesium-26 & Thorium-234 aluminum-26 undergoes positron emission: ___________________________________________ potassium-40 undergoes beta decay: _________________________________________________ uranium-238 undergoes alpha decay: _________________________________________________ ELECTRON CONFIGURATIONS Write the electron configuration for Carbon: _____________________________________ Write the noble gas notation for Platinum: ______________________________________ DENSITY What is the volume of a solid with a density of 7.8 g/mL and a mass of 11.8 g ? 1.5 mL HALF-LIFE Tritium (H-3) is a radioactive isotope of hydrogen with a half-life of 12.3 years. How long would it take for a 40.0 g sample to decay down to 1.25 g? 61.5 years Fe-61 has a half-life of 6.00 min. Of a 100.0 mg sample, how much will remain after 18.0 min? 12.5 mg MOLES, MOLECULES & GRAM CONVERSIONS How many grams are in 6.8 moles of H2O? 122.45 g H2O 4.33 x 1022 atoms NaCl How many atoms are there in 4.2 grams of NaCl? How many grams are there in 5.62 x 1023 atoms of CH 4? 14.98 grams CH4 VALENCE ELECTRONS & OXIDATION NUMBER Elements Number of Valence Electrons ANSWERS: -3 , -1, 2, +2, 3, +3, 5, 7 Oxidation Number (charge) Strontium Phosphorus Boron Iodine QUANTUM NUMBERS Quantum numbers for the following elements are Y: _______, _______, _______, _______ Identify the following elements: ANSWERS: -2, - ½ , + ½ , 0, 1, 2, 4, 4, Pb, Rh Br: ______, ______, ______, ______ 6, 1, 0, + ½ : _________________ 4, 2, -1, - ½ : _______________ WAVE PARTICLE PROBLEM Ultraviolet light causes a chemical reaction in your skin and darkens the pigments in your skin. If the wavelength of these photons is 200 nanometers, 2 x 10-7 meters Find the wavelength in meters (convert nanometers to meters): 1.5 x 10 15/s Find the frequency 9.94 x 10-19 J Find the energy of these photons CONCEPT QUESTIONS: Identify the letter of the choice that best completes the statement or answers the question. ANSWERS: A, B, B, B, B, B, C, C ____ 1. Most of the mass of an atom is found a. In the electron cloud. c. in the number of protons. b. in the nucleus. d. in the outer region of an atom. ____ 2. A spherical electron cloud surrounding an atomic nucleus would best represent a. an s orbital. c. a combination of px and py orbitals. b. a px orbital. d. a combination of an s and a px orbital. ____ 3. For an electron in an atom to change from the ground state to an excited state, a. energy must be released. b. energy must be absorbed. c. radiation must be emitted. d. the electron must make a transition from a higher to a lower energy level. ____ 4. Which two compounds are examples of the law of multiple proportions? a. FeCl3 and Fe2(SO4)3 c. CO and CO2 b. O2 and O3 d. FeCl2 and Fe(NO3)2 ____ 5. The energy of a photon, or quantum, is related to its a. mass. b. speed. c. frequency. ____ 6. Written in scientific notation, the measurement 0.000 065 cm is a. 65 x 10–4 cm. c. 6.5 x 10–6 cm. –5 b. 6.5 x 10 cm. d. 6.5 x 10–4 cm. ____ 7. Atoms of the same element that have different masses are called a. moles. b. isotopes. c. nuclides. ____ d. size. d. neutrons. 8. A nuclear particle that has about the same mass as a proton, but with no electrical charge, is called a(n) a. nuclide. b. neutron. c. electron. d. isotope. Answers: 9.945 x 10-19 5.4 x 10-8 2 x 10-7 0.092 0.77 45.3 61.5 122.45 9900 1.5 3 1.5 x 1015 5.04 12.5 22 4.3 x 10 14.98