Conference Technical Program 2016 Organic Reactions Catalysis Society Meeting March 27-31 Miami, FL Monday Title Authors 8:20-8:30 Opening remarks Will Medlin, ORCS Chair 8:30-9:15 Rylander Award lecture Hydrogenation of Sodium Oleate in Aqueous Emulsion with Hoveyda-Grubbs 2nd Generation Catalyst Highly Organic Phase Soluble PolyisobutyleneBound Cobalt Phthalocyanines as Recyclable Catalysts for Nitroarene Reduction Coffee break BDO: Catalyst Technologies and Raw Materials; which technology will prevail? Supported colloidal ÒNanoSelectÓ catalysts: the role of the stabilizer in the catalyst preparation and its effect on the performance Functionalized Carbons Designed for Removal of Pd from Pharmaceutical Mixtures Joe Zoeller 9:15-9:40 9:40-10:05 10:05-10:35 10:35-11:00 11:00-11:25 11:25-11:50 12:00-1:30 Lunch break 1:30-2:15 Keynote Lecture Hydrogenation of amide acetals and iminium esters: Catalytic reduction of amides under very mild conditions Non-metal Catalyzed Hydrogenation of Polar Substrates in Organic Molecules using Thermally Frustrated Lewis Pairs 2:15-2:40 2:40-3:05 3:05-3:35 3:35-4:00 Coffee break Transition Metal Oxides are Efficient Catalysts 1 Affiliations Eastman Chemical (retired) 1 Hui Wang , Max Hamilton , Garry L. Rempel1* University of Waterloo Chih-Gang Chao* and David E. Bergbreiter Texas A&M University sponsored by Parr D. Ostgard Evonik Peter T. Witte*, Ramon van Maanen, Christien Groen BASF Girish Srinivas*, Steven D. Dietz, Steven C. Gebhard and Michael V. Mundschau TDA Research Tehshik Yoon University of Wisconsin Renat Kadyrov Evonik Adrian Houghton, Sean Whittemore, Abhi Karkamkar, Don Camaioni, Mark Bowden, Bojana Ginovska, Greg Schenter, Tom Autrey* sponsored by Parr Pacific Northwest National Laboratory O. Beswick1, I. Yuranov1, Linda 1 Ecole Polytechnique Fédérale de 4:25-5:00 for Selective Reduction of Nitroarenes to Anilines under Mild Conditions Ru/Fe-catalyzed Reduction of CO2 with C-C bond Formation Whither goest catalysis? 5:00-7:00 Poster session 4:00-4:25 Nikoshvili2, and L. Kiwi-Minsker1,2* Lausanne, 2Tver State University Yuehui Li, Kathrin Junge, Matthias Beller* Robert Augustine Leibniz Institute for Catalysis Jens Norskov Stanford University Seton Hall University Tuesday 8:20-9:15 9:15-9:40 Raney Award lecture Synthesis of 1,4-Diazabicyclo [2,2,2] Octane With Alkaline Earth Phosphate Catalysts 9:40-10:05 Renewable Isoprene by Dehydrodecarboxylation of Mevalonolactone 10:05-10:35 Coffee break Functionalized polymer-supported pyridine ligands in palladium catalyzed C(sp3)-H Arylation Aromatic Oxidations with H2O2 Catalyzed by Divanadium-Substituted γ-Keggin Polyoxotungstate: New Reactions and Mechanistic Insights 10:35-11:00 11:00-11:25 11:25-12:10 Keynote lecture 1 1 Li-Chen Lee1, Jian He2, Jin-Quan Yu2*, Christopher M. Jones1* 1 Oxana A. Kholdeeva1,2, Olga V. Zalomaeva1, Vasilii Y. Evtushok1,2, Irina D. Ivanchikova1, Nataliya V. Maksimchuk1,2, Gennadii M. Maksimov1, Igor Y. Skobelev1, Jordi J. Carbó3, Josep M. Poblet3 Huw Davies 1 Tuesday afternoon: Reactor design and selection short course, 1:30-4:30 5:00-7:00 Poster session Air Products and Chemicals (ret’d), 3RiversCatalysis, LLC, 3Honeywell (ret’d) Dupont James E Wells , Fredrick C Wilhelm1, James F White2*, Nance K Dicciani3 Joseph McAuliffea, Will Bazellab, Torren R.Carlsonb, Maggie Cervina, Rohan Durbalb James Ngaia, Annalisa Hargisb, Yu-Ling Hsiaob, Joseph Murphyb, Karl Sanforda , Sourav K. Senguptab, Gregory Whiteda and Joachim C. Ritterb* sponsored by Parr 2 Georgia Institute of Technology, Scripps Research Institute 2 Boreskov Institute of Catalysis, Novosibirsk State University, 3 Universitat Rovira i Vigili Marcel·lí Domingo 2 Emory University Wednesday 8:30-9:15 9:15-9:40 9:40-10:05 10:05-10:35 10:35-11:00 Rylander Award lecture Hydrogenation of Chloronitrobenzene over AuPd/TiO2 Catalysts Pd-Containing Catalysts for Suzuki CrossCoupling Based on Polymeric Matrix of Hypercrosslinked Polystyrene Coffee break Lattice-Mismatched PtFe Nanocatalysts for Aqueous Phase Oxidation of Biomass to ValueAdded Chemicals 11:00-11:25 Selective aqueous-phase hydrogenation of levulinic acid to pentanediol over bimetallic catalysts: the influence of the promoter 11:25-11:50 Mechanistic Investigation of Acetic Acid Ketonization over Stable ZrO2-based Catalysts under Hydrothermal Reaction Conditions Lunch Keynote lecture: Continuous Reactors for Homogeneous and Heterogeneous Catalysis 12:00-1:30 1:30-2:15 2:15-2:40 Amination of 1,6-Hexanediol 2:40-3:05 Selecting the appropriate test for a given catalytic problem Coffee break Hybrid Polymer/Oxide Hollow Fibers as Versatile and Scalable Flow Reactors for 3:05-3:35 3:35-4:00 Anil Guram Art of Elements, LLC Yu-Wen Chen*, Ya-Ting Chu National Central University Taiwan Linda Zh. Nikoshvili1*, Nadezhda A. Nemygina1, Valentina G. Matveeva1, Lioubov Kiwi-Minsker1,2, Esther M. Sulman1 sponsored by Parr 1 Xin Jin, Meng Zhao, Pallavi Bobba, Chun Zeng, Prem S. Thapa, Bala Subramaniam, Raghunath V. Chaudhari* Louis Corbel-Demailly1, Alicia Wilhelm1, Amandine Cabiac2, Emmanuelle Guillon2, Michèle Besson1, Catherine Pinel1* University of Kansas Juan A. Lopez-Ruiz1, Alan R. Cooper1, Qiuxia Cai1,2, Donghai Mei1, Karl O. Albrecht1* 1 Martin D Johnson*, Scott A May, Joel R Calvin, Timothy M Braden, Douglas P Kjell, Ryan J Linder, Nikolay Zaborenko, Matthew H Yates, Shon R Pulley Sourav K. Sengupta*, Joachim C. Ritter, William B. Bazela, Alan M. Allgeier, and Yu-Ling Hsiao Erik-Jan Ras*, Roel Moonen, Pieter Imhof sponsored by Parr Eli Lilly Eric G. Moschetta1, Solymar Negretti2, Kathryn M. Chepiga2, 1 Tver Technical University, Ecole Polytechnique Fédérale de Lausanne 2 1 CNRS-Université Lyon, 2IFPen-Lyon Pacific Northwest National Laboratory, 2Zhejiang University of Technology Dupont Avantium Georgia Institute of Technology, Emory University 2 Heterogeneously Catalyzed Organic Reactions 4:00-4:25 4:25-4:50 Green Reactor Technologies for Process Intensification of Biodiesel Processes: Cost, Energy Savings and Emissions Abatement Asymmetric Hydrogenation of α-Amino Ester: A Spectroscopic View Banquet Nicholas A. Brunelli1,2, Ying Labreche1, Yan Feng1, Fateme Rezaei1, Ryan P. Lively1, William J. Koros1, Huw M. L. Davies2, and Christopher W. Jones1* Aashish Gaurav, Flora Ng*, Garry Rempel University of Waterloo Long Zhang, Mehdi Lohrasbi, Uma Tumuluri and Steven S.C. Chuang* University of Akron Gadi Rothenberg University of Amsterdam Glen A. Ferguson, Michael B. Griffin, Daniel A. Ruddy, Mary J. Biddy, Gregg T. Beckham*, and Joshua A. Schaidle* Ashley McVeigh, Florent Bouxin, Michael C. Jarvis and S David Jackson* sponsored by Parr National Renewable Energy Laboratory Elie Derrien1, Jialu Li1, Philippe Marion2, Catherine Pinel1, Michèle Besson1* Rebecca A.L. Baylon1, Colin Smith1, Junming Sun,1* Changjun Liu1, and Yong Wang1,2* T. Salmi1*, V. Hrobar1, P. MäkiArvela1, K.Eränen1, F. Sandelin2 1 Thursday 8:30-9:15 9:15-9:40 9:40-10:05 10:05-10:35 10:35-11:00 11:00-11:25 11:25-11:50 11:50-12:00 Keynote lecture: Break the Bark: New Catalytic Routes From Biomass to Chemicals The role of the support and reaction conditions on the mechanism of vapor phase m-cresol hydrodeoxygenation over Pt/TiO2 and Pt/C catalysts Conversion of Lignin to Functionalized Aromatic Monomers Over Pt/alumina Coffee break Valorization of sugars in hemicellulose hydrolysates by catalytic aerobic oxidation Rational Design of ZnxZryOz Catalysts for the Conversion of Ethanol to Isobutene with Improved Selectivity and Stability Kinetics and Modelling of Esterification of Levulinic Acid – Batch and Continuous Operation Closing remarks Will Medlin, ORCS Chair University of Glasgow CNRS Univ. Lyon, 2Solvay Research and Innovation Center Lyon 1 Washington State University, 2Pacific Northwest National Laboratory 1 Åbo Akademi, 2TF-Engineers Finland