Session A11 Paper # 6102 Disclaimer — This paper partially fulfills a writing requirement for first year (freshman) engineering students at the University of Pittsburgh Swanson School of Engineering. This paper is a student, not a professional, paper. This paper is based on publicly available information and may not be provide complete analyses of all relevant data. If this paper is used for any purpose other than these authors’ partial fulfillment of a writing requirement for first year (freshman) engineering students at the University of Pittsburgh Swanson School of Engineering, the user does so at his or her own risk. THE IMPORTANCE AND APPLICATIONS OF CARBON CAPTURE SEQUESTRATION THROUGH SELECTIVE MEMBRANES Zachary Dissen, zpd2@pitt.edu, Mahboobin 10:00, Tanner Prime, tjp50@pitt.edu, Mahboobin 4:00 Revised Proposal-- Carbon capture sequestration (CCS) is a method of capturing carbon emissions within pollutants before they reach the atmosphere, and then reusing the Carbon Dioxide (CO ) gas for various purposes. CCS is one of the subgoals of environmental engineering that aims to reduce the amount of greenhouse gas pollution and help slow global warming [1]. There are many methods that have achieved various levels of success, but this paper will discuss the membrane approach, a method of CCS that uses various levels of pressurization and filtration to separate the CO from the other gasses in pollutants and harvest them for reuse while using minimal resources and space. Specifically, this paper will discuss the various benefits and applications of CCS through selective membranes, and the re use of this harvested carbon. The process of carbon capture by membrane involves the use of exhaust gas from common sources such as coalburning power plants, automobiles, and any machinery that consumes fossil fuels, even natural gas or propane appliances. The process involves the insertion of a mechanism into the exhaust line of a vehicle or plant that filters the CO component of the gas out, and collects it in a solvent to be stored for later use [2]. Membranes are an attractive method for CCS due to their generally small and modular designs, as well as their high efficiency and selectivity (in membranes with less permeability) [3]. The most popular application of CCS is Enhanced Oil Recovery (EOR), which involves pumping CO into bedrock to force out trapped oil deposits. The CO can even dissolve in the crude oil and make it easier for it to flow to the collection reservoir, improving oil harvests drastically and reducing the strain on the environment that would appear in methods such as chemical injection [4]. The impact of the ability to install CCS in nearly any vehicle or other small pollution source is that the level of carbon emissions could be drastically decreased in the coming decades, implying a sizeable decrease in the effects of global warming by the year 2050 [5]. The structure of this paper will first focus on the intricacies of membrane technology and how membranes can extract CO from pollutants. Then the application of membrane technology to existing infrastructure will be discussed, and 2 finally, the benefits and application of harvested carbon will be explained-thus illustrating CCS’s ethical impact on the world today. To accomplish this multiple scientific papers that concern CCS and membrane technology will be consulted. In addition, professors, who have been working on this particular aspect of CCS, will be interviewed and their opinions on CCS through selective membranes will be assessed. REFERENCES 2 2 2 2 [1] University of Melbourne Public Lecture Program. (23 July 2010). “How CCS works – and why we need it”. CRC for Greenhouse Gas Technologies. (Online article). [2] J. Sullivan and M. Sivak. (May 2012). “Carbon Capture in Vehicles: A Review of General Support, Available Mechanisms, and Consumer-Acceptance Issues”. University of Michigan Transportation Research Institute. (Online article). http://deepblue.lib.umich.edu/bitstream/handle/2027.42/909 51/102855.pdf [3] K. Simons. (2010). “Membrane technologies for CO2 capture”. University of Twente. (Online article). https://www.utwente.nl/tnw/mtg/publications/mstpublication s/pdf/2010_Simons.pdf [4] United States Department of Energy. (2016). “Enhanced Oil Recovery”. (Online article). http://energy.gov/fe/science-innovation/oil-gasresearch/enhanced-oil-recovery [5] J. Wilcox. (2014). “Carbon Capture using NitrogenSelective Membrane Processes”. Department of Energy Resources Engineering, Stanford University. (Video). http://www.istc.illinois.edu/about/SustainabilitySeminar201 41027.cfm [6] United States Bureau of Labor Statistics (2014). “Environmental Engineers.” (Online article). http://www.bls.gov/ooh/architecture-andengineering/environmental-engineers.htm 2 University of Pittsburgh Swanson School of Engineering 1 2016/01/29 ANNOTATED BIBLIOGRAPHY Zachary Dissen Tanner Prime This video focused on the ability for CCS to be applied to any small source of carbon emissions. It explained how CCS could be implemented on various carbon emissions and the all-around effects it could cause on society, including global warming. We intend to use this source as a strong component for our argument of the importance of CCS in today’s world. “Develop Carbon Sequestering Methods”. (2016). National Academy of Engineering Grand Challenges for Engineers. (Online article). http://www.engineeringchallenges.org/9077.aspx This article from the National Academy of Engineering Grand Challenges provided information that outlines the current environmental dangers of carbon pollution. The source also provides a basic understanding of various approaches to solving carbon pollution, as well as, arguing for the importance of solving this issue as soon as possible. The information from this source will provide us with a basic understanding of CCS and open our eyes to the large scale meaning of these CCS membranes. K. Simons. (2010). “Membrane technologies for CO2 capture”. University of Twente. (Online article). https://www.utwente.nl/tnw/mtg/publications/mstpublication s/pdf/2010_Simons.pdf Simon's article from the University of Twente detailed two important membrane processes that capture Carbon dioxide; a gas-liquid membrane contactor and thin, dense gas separation membrane. In addition this article touched upon the big picture of CCS effects. The information from this source will be heavily used to understand how CCS exactly works when using a membrane. H. Zhai and E. Rubin. (March 2011). “Technical and Economic Assessment of Membrane-based Systems for Capturing CO2 from Coal from Coal-fired Power Plants fired Power Plants”. Department of Engineering and Public Policy Carnegie Mellon University. (Online presentation). http://www.cmu.edu/epp/iecm/rubin/PDF%20files/2012/Zha i,%20Rubin_Membrane_2011%20AIChE%20Spring%20Mt g_3-13-11.pdf Zhai and Rubin’s presentation, from Carnegie Mellon University, provides a reservoir of information on CCS from coal burning plants and the intricacies of membrane separation. This source also provides data for the economic impacts and implication of CSS. This source will serve as a tool to understand CCS and its components when applied to large Coal power plants, as well as, a reference to examine the economics of CCS. United States Bureau of Labor Statistics (2014). “Environmental Engineers.” (Online article). http://www.bls.gov/ooh/architecture-andengineering/environmental-engineers.htm This online article from the Bureau of Labor and Statistics gives a detailed summary of an environmental engineer. It provides a definition of environmental engineer and what environmental engineers do, as well as, various other aspects of environmental engineers such as pay, work environment, and job outlook. This source’s information allows us to identify with a specific engineering field, and opens us up to a specific group of people interested in the work that we are doing. J. Sullivan and M. Sivak. (May 2012). “Carbon Capture in Vehicles: A Review of General Support, Available Mechanisms, and Consumer-Acceptance Issues”. University of Michigan Transportation Research Institute. (Online article). http://deepblue.lib.umich.edu/bitstream/handle/2027.42/909 51/102855.pdf This online article, from the University of Michigan, focused on worldwide views of CSS and its growing popularity. It also examined the capturing of carbon dioxide using three different mechanisms; absorption, membrane separation, and adsorption. The paper mainly focused on the capturing of carbon dioxide from post combustion reactions. Bringing this source to our paper will add the dimension of application. It provides us information on applying this new technology of CCS to already existing infrastructures. United States Department of Energy. (2016). “Enhanced Oil Recovery”. (Online article). http://energy.gov/fe/science-innovation/oil-gasresearch/enhanced-oil-recovery This source provided a detailed explanation of the uses of captured carbon dioxide, specifically enhanced oil recovery. The article explained how enhanced oil recovery is performed currently, possible new approaches to enhanced oil recovery, and where enhanced oil recovery is heading. Understanding all the effects and uses of CCS are very important to us and our paper. Therefore we will use this source’s information to explain a specific use of CCSenhanced oil recovery. University of Melbourne Public Lecture Program. (23 July 2010). “How CCS works – and why we need it”. CRC for Greenhouse Gas Technologies. (Online article). http://www.co2crc.com.au/dls/media/10/PublicLectureJuly.p df The University of Melbourne's article described the overall impact and problems with CCS. This source sheds J. Wilcox. (2014). “Carbon Capture using Nitrogen-Selective Membrane Processes”. Department of Energy Resources Engineering, Stanford University. (Video). http://www.istc.illinois.edu/about/SustainabilitySeminar201 41027.cfm 2 Zachary Dissen Tanner Prime light into the CCS’s ability to maintain the carbon dioxide levels, as well as its impact in reducing global warming. In addition, this article examined the economic problems with CCS through the eyes of Mr. Barry Hooper, CO2CRC Chief Technologists. This source will serve as a general base line for the effects and implications of CCS. 3