Reaction Dynamics Unit March 3- March 10 (2016) Day 1: Understanding Collision Theory in Reactions Objectives (SWBAT): Physical Science 31-Describe chemical changes and reactions using diagrams and descriptions of the reactants, products, and energy changes Evaluated by: Collision Theory Worksheet Class structure: Do Now: Under what circumstances does sugar dissolve best in tea. 1. Engage- The class will discuss why these factors increase the “reaction rate” of the sugar and the tea. 2. Explore- Students will use the phet simulation below to explore the molecular nature of reactions. https://phet.colorado.edu/en/simulation/reactions-and-rates 3. Explain- Students will explain how reactions are affected by energy and concentration using the worksheet for the day. 4. Elaborate- Students will use collision theory to predict relative reaction rates of equations and how the factors discussed in the Do Now might affect various reactions. Summary: The rate of a reaction can be defined as the disappearance in the amount of reactant over time or the appearance of product over time. This can be adjusted through temperature, number of particle (concentration), size of particles, or a catalyst. Day 2: Interpreting Reaction Rate from Graphs Using Collision Theory Objectives (SWBAT): Physical Science 31-Describe chemical changes and reactions using diagrams and descriptions of the reactants, products, and energy changes Inquiry 5- Use graphing skills to solve problems Evaluated by: Collision Theory Graphing Worksheet Class structure: Do Now: Draw an example of a potential energy graph for a reaction and label the reactants and products. 1. Engage- Class will review vocabulary (activation energy, activated complex, reactant, product) and introduce new vocabulary (inhibitor, catalyst) 2. Explore- Students will use graphs and data to determine the rate of a reaction. 3. Explain- Students will use collision theory to explain why one experiment’s rates might differ from another experiment’s rates. 4. Elaborate- Students will complete general multiple choice and open ended questions as practice/review of collision theory. Summary: The hill in the reaction progress diagram is the activation energy of the reaction. This is the amount of energy that a reaction must have to be able to pass through the in-between state, called the activated complex, and form products. The two things needed for a reaction to occur are reactants and energy. A higher concentration of reactants is better and energy above the activation energy is necessary. Day 3: Dynamic Equilibrium and Le Chatelier Objectives (SWBAT): Physical Science 37- Predict the direction of a shift in equilibrium in a system as a result of stress by using LeChatalier's principle Inquiry 5- Use graphing skills to solve problems Evaluated by: Prom Equilibrium Class structure: Do Now: Fill in the first two blanks on the sheet for today then explain which of these variables a catalyst affects. 1. Engage- Teacher will introduce forward and reverse reactions and the dynamic equilibrium between them using a prom simulation. Students will take notes and answer questions as they follow along. 2. Explore- Students will predict changes in the shape of the concentration vs time graph with changes to environment (music) or reactants (number of single boys, single girls, and couples). 3. Explain- Students will use the graphs they’ve drawn to explain dynamic equilibrium. 4. Elaborate- Students will apply their understanding of dynamic equilibrium and Le Chatelier’s Principle to chemical equations. Summary: The concentration of reactants and products at equilibrium is not equal but the rate of change for each side is equal. The reaction direction of a reversible reaction can be predicted if the equilibrium concentrations and current concentrations are known. Day 4: Virtual Equilibrium Lab Objectives (SWBAT): Physical Science 37- Predict the direction of a shift in equilibrium in a system as a result of stress by using LeChatalier's principle Inquiry 6- Students will use technology to enhance scientific investigations Evaluated by: Virtual Equilibrium Lab Class structure: Do Now: Students will log into their computer and find the virtual lab for the day. 1. Engage- Students will use the background section of the lab to refresh their memories on reversibility of reactions and dynamic equilibrium then complete the prelab questions. Teacher will check these before students begin the lab. 2. Explore- Students will apply various stresses to reactions at equilibrium and record their observations of what happens. 3. Explain- Students will explain what happened chemically in each reaction that led to the observations they recorded. 4. Elaborate- Students will work on the review for the test (due Day 5) for continued practice. Summary: When a stress is applied to a system in equilibrium, the system acts to reverse this stress and return to equilibrium. Most reactions are reversible meaning they can proceed forward in which reactants combine to form products or in reverse during which the products break up and reform the reactants. Any change in temperature, pressure, or chemical concentrations can affect equilibrium and cause the reaction to proceed more often in the forward direction (to the right) or more often in the reverse reaction (to the left) until it achieves equilibrium again. Day 5: Review for Reaction Dynamics Test Objectives (SWBAT): Physical Science 31-Describe chemical changes and reactions using diagrams and descriptions of the reactants, products, and energy changes Inquiry 5- Use graphing skills to solve problems Physical Science 37- Predict the direction of a shift in equilibrium in a system as a result of stress by using LeChatalier's principle Evaluated by: Review for Reaction Dynamics Test Class structure: Do Now: What types of stresses can be applied to a system at equilibrium and what happens when they are applied? 1. 2. 3. 4. Engage- Class will review the lab from Day 4. Explore- Teacher will work through the answers to the Reaction Dynamics review. Explain- Teacher will show all work and address any questions throughout the process. Elaborate- Teacher will review the vocabulary and equations that could appear on the test. Summary: For a reaction to happen, there must be a high enough concentration of reactants that they hit each other and these collisions must have enough energy (more than the activation energy) to force a change. Once a reaction happens, reactants begin to run out and the reverse reaction then picks up speed until the rate of the forward reaction is equal to the rate of the reverse reaction (dynamic equilibrium). This equilibrium can be changed by changes in concentration or environment (volume, pressure, temperature) but the system will always act (shift toward one reaction or the other) to correct the change (Le Chatelier’s Principle). Day 6: Reaction Dynamics Test Objectives (SWBAT): Demonstrate at least 67 % proficiency on the standards of this unit. Evaluated by: Test- Reaction Dynamics Class structure: Do Now: Take out a calculator and something to write with, open your binder to the table of contents and place it on the back bench, move your bags to the A/C, and clear your calculator RAM TEST Summary: There is only one more nine weeks to go now. Remember that all of this material, from January to May, can appear on the final exam. Please be reviewing as you go. Testing Preparation GLE Objective Day(s) Addressed Inquiry 5 Use graphing skills to evaluate reactions 2, 3, 5 Physical Science 31 Describe chemical changes and reactions using diagrams and descriptions of the reactants, products, and energy changes (Reaction Progress Diagrams) 1, 2, 5 Physical Science 37 Predict the direction of a shift in equilibrium in a system as a result of stress by using LeChatalier's principle 3, 4, 5 Vocabulary Activation Energy Activated Complex Catalyst Inhibitor Assessment Design Basic: 6 Questions Collision Theory Forward vs Reverse Reaction Dynamic Equilibrium Le Chatelier’s Principle Standard: 12 Questions Expanded: 6 Questions Essential Skills and Learning Objectives Type of Question (MC, CR, P) Basic (Remember & Understand) Standard (Apply & Analyze) Expanded (Evaluate & Create) Use graphing skills to evaluate reactions MC/CR 1 CR MC/CR/P 2 MC 1 MC 1 CR 4 CR Describe chemical changes and reactions using diagrams and descriptions of the reactants, products, and energy changes (Reaction Progress Diagrams) Predict the direction of a shift in equilibrium in a system as a result of stress by using LeChatelier's principle MC/CR 1 MC 3 CR 1 MC 2 CR Describe the rate of a given reaction in terms of collision theory MC/CR 3 MC 2 CR 1 CR 2 CR