ANW People travel much more than they used to. As a result much more fuel is being used. Fuels are valuable because they provide us with energy. By burning these fuels gasses are produced which are bad to our health. Carbon dioxide, produced when burning greenhouse gasses the global climate to change. People worry about the damage the climate change can cause. The air quality becomes less. Air pollution can cause serious damage to people with heart- and lung diseases. Fuels for transport As fuel burns, chemical reactions give out energy. Sometimes this energy is directly used to make a car engine run of a jet engine. It can also be used to make electricity. The electricity is used for trains, trams or electric cars. Electricity is a secondary energy source. Fuel fuels such as oil, coal and natural gas, are only available for a limited time. Eventually they will run out. Burning those fuels has done more than anything to increase the concentration of greenhouse gasses in the air. The products of burned fuels do not simply disappear. CO2 is the main greenhouse gas. Transport is the main reason why there are so many greenhouse gasses in the atmosphere. Alternatives to fossil fuels (biofuels) Biofuels come from plants. Bioethanol comes mainly from sugars and starches. Biodiesel mainly comes from rapeseed and palmoil. These biofuels are mixed with normal fuels. In theory these fuels are carbon-dioxide neutral. The CO2 that is released from burning these energies has previous been taking in by the plants to grow. In practice this doesn’t turn out to be this way. During the stages of growing, harvesting and processing these plants also causes CO2 emission due to the use of farmingvehicles. It is said that producing biofuels is not the most effective way of using biomass. A British report said that the most effective way is burning biomass and using the heat for generating electricity. The biofuels which offer the most energy are crops from tropical countries. In Brazil ethanol is made by fermenting sugars from sugar cane. The refineries use the waste from the sugar cane for heating and generating energy. There is one huge disadvantage is that huge forests have been cut down to make room for these refineries. The idea of energy energy does not have a simple definition. Energy also has two meanings. One of the meaning is the amount of change that an object can cause to happen. Energy can be transferred from one object to another by force, by heating, by radiation or by electricity. The amount of energy used can be calculated in many different ways. Energy is always conserved in a progress. ‘Energy is always conserved in a progress’. Energy conservation has a different meaning in everyday life. It refers to the fact that energy sources like fossil fuels are in a limited supply and are valuable. ‘World energy consumption has risen steadily over the past decade. We need to takes steps to conserve energy’. Why does burning fuels cause pollution? Carbon dioxide produced with the burning of fossil fuels does affect the global climate, but doesn’t affect the air quality. Engines pollute the air with gasses that are harmful for different reasons: 1. Sometimes the fuel is not burnt completely which causes the production of CO (instead of CO2). 2. The fuel contains other chemicals as well as hydrocarbons (CₓHₓ) 3. Fuel is burned under high pressure which causes oxygen and nitrogen to react and form NOₓ. Carbon monoxide (CO) Oxides of nitrogen, NO and NO₂. Also NOₓ Sulfur dioxide (SO₂) Ozone (O₃) Particulates (fijnstof) Volatile organic compounds (VOC’s) which are normally gasses or liquids but evaporate so easily that their vapours stay in the air. (vluchtige organische stof) Procudes when fuel is not completely burned, so when theres not enough oxygen Mainly from engines. Due to the pressure and high temperature oxygen and nitrogen react Burning fuels used in motor engines contrain sulfur. Main source is coal from which burning fuel is made. Formed when sunlight shines on polluted air which contains NOₓ The particles include dust from roads and industries. Fines particles are from in diesel engines. SO2 and NO2 react and from particles Include a wide variety of CₓHₓ from evaporated fuels. Another source is leakage from pipelines. Ozone and its effects The ozone layer in the upper atmosphere is a good thing. It protects us from UV-radiation. Ozone in the lower atmosphere is harmful. Ozone is a very reactive gas which irritates the eyes and causes breathing difficulties. Ozone is toxic and can affect the growth of crops and other plants. Most of the pollutants are primary pollutants. Ozone is a secondary pollutant. It is formed from NO2. Sunlight splits up the NO2 into NO and O. The free oxygen molecule reacts with O2 and forms O3.In sunny weather the Ozone level rises and mixes with VOC’s. This forms a yellow haze (smog) and a soup of irritating chemicals. Monitoring air quality the aims of monitoring the air quality are to - understand the scale of air pollution so that the authorities can devise cost effective ways of dealing with the problems. - See if the standers are met. - Inform the public about air quality who may be at risk. Different errors can be made. There are random errors, which cause repeat measurements to vary and scatter around a mean value. These errors can be avoided by calculating an average value of these measurements. Another type of error is systematic error: an error which affects all the measurements. Systematic errors can occur when, for example, the instruments used do not work as they should be. Sampling and analysis Taking a sample is an important first step of monitoring air quality. It is important to make sure that the sample taken is representative for the air in the place where pollution is measured. For example, a sample taken in the centrum of London is not representative for a suburb of London. There are different ways of sampling. One method is to pump air through an analyzer. A systematic error than can occur is that the material of the analyzer can absorb some of the chemicals. Another method is to grab a sample of air in a bag. There will always be uncertainty the results. How do air pollutants affect human health? People working outside all day are more exposed to pollutants than people who work on an office. The evidence about the effects of air pollutants on health is complex. Research has shown that the main damage to people is done by fine particles which carry chemicals which include unburned hydrocarbons. How can technology improve air quality? Changing the way people traffic is practically impossible, since many people are dependent on the traffic. To change the air quality we have to use the technology. Catalytic converters are placed in cars and convert chemicals produced with the burning of fossil fuels in the engine into non-harmful gasses (NOₓ, CₓHₓ and CO into CO2, N and H2O). They do not reduce CO2 emission. In fact, they make it slight worse since. Eletric vehicles have a great advantage that they don’t have emit air pollutants. Disadvantages are that they have to be regularly charged. An alternative to batteries is to use fuel cells. A fuel cell is like a battery, but instead of containing a fixed amount of chemicals, it is supplied with a flow hydrogen gas and air. The hydrogen reacts with the air, forming electricity and water vapor. Also using public transport reduces the emission of air pollutants. How can regulations improve air quality? Since 1970 there have been different rules and regulations to reduce the emission of greenhouse gasses and air pollutants.