AP Biology Book Notes The Chemistry of Life o ELEMENTS Everything is made up of matter, and matter is made of elements, which are substances that cannot be broken any further by chemical means. o THE ESSENTIAL ELEMENTS OF LIFE 96% of human mass is made of OXYGEN, CARBON, HYDROGEN, and NITROGEN Trace elements – are elements that are only required by an organism in very small quantities o SUBATOMIC PARTICLES If you break down an element you get an atome, the smallest unit of an element that retains its characteristic properties. The building blocks of the physical world. Are electrically neutral usually by having the same number of protons and electrons. The atom nucleus is made of protons and neutrons, and around the nucleus are electrons that spin around nucleus. Also if you change the number of neutrons in an element, the element is the same but it creates an isotope. Parts of An Atom – Protons, neutrons and electrons Proton – Positively charged particles Neutron – Uncharged particles Electron – Negatively charged particles that spin around the nucleus. They are considered massless. Nucleus – Core of an atom where protons and neutrons are packed together. Isotope – Atoms that have the same number of protons, but differ in the number of neutrons in the nucleus. o Compounds When 2 or more different types of atoms are combined into a fixed ratio, you have a compound. Also you can have a chemical reaction when multiple elements are combined. Another thing to remember is that the atoms in a compound are held by chemical bonds, which have 3 subgroups the ionic bonds, the covalent bonds, and hydrogen bonds. Chemical Bonds – A bond formed between the atoms of a compound. Ionic Bonds – When one atom of the compound gives 1 or more electrons to the other atom(s). Covalent Bonds – When atoms of a compound share electrons. Nonpolar Covalent Bonds – Equal sharing of electrons. Polar Covalent Bonds – Unequal sharing of electrons. o Water: The Versatile Molecule Water – One of the most important substances in nature is water. More than 60% of our body weight consists of water. Considered a unique and important molecule because it plays an important role in chemical reactions. Properties – 2 Hydrogen atoms and 1 Oxygen atom. The hydrogen atoms have a partial positive charge, and the oxygen atom has a partial negative charge. The positively-charged ends of the water molecules strongly attract the negatively-charged ends of the polar compound, and vice versa where negativelycharged ends attract positively-charged ends. This attraction creates water beads or rain drops. Also water molecules tend to stick together which is called cohesion or they tend to stick to other substances which is called adhesion. Lastly water has a high heat capacity, which means the energy needed to change the degree of a substance by 1 degree. Polar Water Molecules – Molecules that have a partial positive and a partial negative charge. Hydrogen Bonds – Weak chemical bonds that form when a hydrogen atom that is covalently bonded to one electronegative atom that is also attracted to another electronegative atom. Collectively they are strong, individually they are weak. Cohesion – The strong tendency to for 2 molecules to stick together. Adhesion –When molecules are attracted and stick to other substances. Surface Tension – a contractive tendency of the surface of a liquid that allows it to resist an external force. Capillary Action – the ability of a liquid to flow in narrow spaces without the assistance of, and in opposition to external forces like gravity. REVIEW OF PROPERTIES – Polar and can dissolve other polar substances, cohesive and adhesive properties, high heat capacity, and high surface tension. o The Acid Test Acids – Contains a lot of hydrogen ions. Bases – Do not release hydrogen ions. Alkaline – The release of a lot of hydroxide ions. pH scale – The measure of alkalinity or acidity. o Organic Molecules Organic Compounds – Contains carbon atoms Inorganic Compounds – Doesn’t contain carbon atoms Carbohydrates Organic compounds that contain carbon, hydrogen, and oxygen. Ratio 1:2:1. Saccharide – fancy word for sugar Monosaccharides – The simplest sugars, they serve as an energy source for cells. Glucose is the most popular sugar around, found in plants, and is a hexagonal ringed shape. Fructose common sugar in fruits, and is a pentagonal ringed shape. Disaccharides – When 2 monosaccharides are chemically linked. In order to create a disssacharide you must go through Dehydration Synthesis or Condensation. Also in order to break up a dissacharide you must go through Hydrolysis. o Dehydration Synthesis/Condensation – The loss of a water molecule. o Hydrolysis – The addition of a water molecule Polysaccharides – When multiple units of minisaccharides are liked (more than 3). They are a type of a polymer, pr a molecule with repeating units. The most common types are starch, cellulose, and glycogen. Also they are often storage forms of sugar or structural components. When starch (alpha glucose) is stored, it is stored in plastids. Cellulose (beta glucose) serves as a structural molecule in walls of things such as fungus and arthropods. o Proteins Made of amino acids. Amino acids are organic molecules that serve as the building blocks of proteins. There are 4 parts of an amino acid, the Amino Group, the Carboxyl Group, the Hydrogen Group, and the R Group. R Group is also called the side chain. Functional Groups Distinctive groups of atoms that play a large role in determining the chemical behavior of the compound they are a part of. Carboxyl Group – To spot an amino acid keep your eye out for an Amino Group (NH2), then look out for the Carboxyl Group (COOH). Polypeptides When 2 amino acids form a dipeptide. The carboxyl group of one amino acid combines with the amino group of another amino acid. Peptide Bond – The bond between 2 amino acids. Polypeptide – A group of amino acids are joined together. When these twist and folds on itself, it forms a 3-D structure called a protein. o Lipids Consist of Carbon, Hydrogen, and Oxygen atoms, but not in the 1:2:1. The most common examples of lipids are fats, oils, phospholipids, and steroids. A typical fat consists of 3 fatty acids and 1 glycerol. Triglyceride is a fancy name for “fat.” Making a Triglyceride – Each carboxyl must react with 1 of the 3 hydroxyl groups of the glycerol molecule. The creation of fat involves the removal of 3 water molecules, Dehydration Synthesis in action once again. Ester Linkage – The linkage formed between the glycerol molecule and the fatty acids. Saturated Acid – Single covalent bond between each pair of carbon atoms. Unsaturated Acid – Adjacent carbons are joined by double covalent bonds instead of single covalent bonds. Polyunsaturated Acid – When a fatty acid has many double covalent bonds within the fatty acid. Phospholipids – 2 fatty acid tails and a phosphate head attached to a glycerol chain. The head is hydrophobic (Positive head opposes the positive end of a water molecule). The tail is hydrophilic (Negative tail attracts positive end of water). A amphipathic molecule has both a hydrophobic and hydrophilic region (Ex: Phospholipid). Steroids – Basic 4 carbon ring structure, with cholesterol, vitamin D, and hormones. o Nucleic Acids Contains Carbon, Hydrogen, Oxygen, and Nitrogen, but also contains phosphorus. Made of simple units called nucleotides. 2 types of Nucleic Acids – Deoxyribonucleic Acid (DNA) and Ribonucleic Acid (RNA) DNA – Contains genes, the hereditary blueprints of life. RNA – Is essential for protein synthesis. o Heterotroph Hypothesis The hypothesis that the earliest precursors of life arose from nonliving matter. Believed that gases collided, producing chemical reactions and creating the organic molecules of today. Then simple cells create complex cells. Heterotroph – A consumer or something that rely on something else to make food. Autotroph – A self-producer, making its own food.