IMRIE-GIELOW, INC.
2823 PAPIN ST.
ST. LOUIS, MISSOURI 63103
314-772-4200
SAFETY DATA SHEETS
1) Identification a) Product identifier used on label:
i)
I-G CAULK
b) Other means of identification;
i) REFRACTORY CERAMIC FIBER PRODUCT
c) Recommended use of the chemical and restrictions on use;
i) Refractory
d) Name, address and telephone number of manufacturer;
i) Imrie-Gielow, Inc.
ii) 2823 Papin St
iii) St. Louis, Missouri 63103, United States of America
iv) 314-772-4200
e) Emergency phone number;
i) 314-772-4200 -07:00-16:00 Central Time Zone
ii) 800-414-9300 Chemtrec
2) Hazard(s) Identification
a) Classification of the Chemical
i)
POSSIBLE CANCER HAZARD BY INHALATION
ii)
Chronic Effects – There has been no increased incidence of respiratory
disease in studies examining occupational exposed workers. In animal
studies, long term laboratory exposures hundreds of times higher than
normal exposures has produced fibrosis, lung cancer and mesothelioma in
rats and hamsters. The fibers in those studies were specially sized to
maximize rodent respirability
iii)
Target Organs – Respiratory Tract (nose and throat), Skin and Eyes
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IMRIE-GIELOW, INC.
2823 PAPIN ST.
ST. LOUIS, MISSOURI 63103
314-772-4200
SAFETY DATA SHEETS
b) Signal word, hazard statement(s) in accordance with paragraph (f) of 1910.1200.
i)
Signal Word - Warning
ii)
Hazard Statement – Although studies, involving occupationally exposed
workers have not identified any increased incidence of respiratory disease,
results from animal testing have been used for the basis for hazard
classification.
iii)
Hazard symbol - Carcinogen
iv)
Precautionary statements – Proper use of PPE’s especially breathing
protection
v)
Prevention – When handling use good housekeeping and industrial
hygiene procedures to minimize airborne dust. Avoid breathing dust: an
approved dust mask or respirator recommended where dust generation is
possible. Avoid contact with skin and eyes: wear suitable loose fitting
clothing, gloves and eye protection.
3) Composition/information on ingredients
a) For Mixtures
i)
The name and concentration (exact percentage) or concentration ranges of
all ingredients which are classified as health hazards in accordance with
paragraph (d) of 1910.1200 and are present above their cutoff
concentration limits; or present a health risk below cut-off/concentration
limits.
The International Agency for Research on Cancer (IARC) confirmed in
October 2001 that Group 2B (possible human carcinogen based on
sufficient evidence of carcinogenicity in animals but inadequate evidence
in humans) continues to be the classification for refractory ceramic fiber
ii)
The concentration (exact percentage) shall be specified unless a trade
secret claim is made in accordance with (i) of 1910.1200, when there is a
batch-to-batch variability in the production of a mixture.
CHEMICAL NAME
CAS #
Refractory Aluminosilicate Fibers
142844-00-6 Up to 11
N/A
Amorphous Silica
7631-86-9
Up to 36
N/A
Chromic Oxide
1308-38-39
<0.3
Water
7732-18-5
Up to 55
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%
GHD-US Classification
N/A
IMRIE-GIELOW, INC.
2823 PAPIN ST.
ST. LOUIS, MISSOURI 63103
314-772-4200
SAFETY DATA SHEETS
4) First-aid Measures
a) Description of necessary measures, subdivided according to the different routes of
exposure, i.e. inhalation, skin and eye contact and ingestion
i)
INHALATION – Respiratory Tract (nose & throat) Irritation – if
respiratory tract irritation develops, move the person to a dust free
location. See Section 8 for additional measures to reduce or eliminate
exposure.
ii)
SKIN – If skin becomes irritated, remove soiled clothing. Do not rub or
scratch exposed skin. Wash area of contact thoroughly with soap and
water. Using a skin cream or lotion after washing may be helpful.
iii)
EYES – If eyes become irritated, flush immediately with large amounts of
lukewarm water for at least 15 minutes. Eyelids should be held away from
eyeball to ensure thorough rinsing. Do not rub eyes.
iv)
INGESTION – If gastrointestinal tract irritation develops, move person to
a dust free environment.
v)
GENERAL – If the above symptoms persist, seek medical attention.
b) Most important symptoms/effects, acute and delayed
i)
GENERAL – Pre-existing medical conditions, including dermatitis,
asthma or chronic lung disease may be aggravated by exposure.
Individuals who have a history of allergies may experience greater
amounts of skin and respiratory irritation.
ii)
INHALATION – If inhaled in sufficient quantity, may cause temporary,
mild mechanical irritation to respiratory tract. Symptoms may include
scratchiness of the nose or throat, cough or chest discomfort.
iii)
SKIN – May cause temporary, mild mechanical irritation. Exposure may
also result in inflammation, rash or itching.
iv)
EYES – May cause temporary, mild mechanical irritation. Fibers may be
abrasive: prolonged contact may cause damage to the outer surface of the
eye.
v)
INGESTION – Unlikely route of exposure
c) Indication of immediate medical attention and special treatment needed, if necessary.
i)
If exposed and concerned, get medical advice and attention – NOTE TO
PHYSICIANS: Skin and respiratory effects are the result of temporary,
mild irritation; fiber exposure does not result in allergic manifestations.
5) Fire-fighting measures
a) Suitable (and unsuitable) extinguishing media
i)
As appropriate for surrounding fire
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IMRIE-GIELOW, INC.
2823 PAPIN ST.
ST. LOUIS, MISSOURI 63103
314-772-4200
SAFETY DATA SHEETS
b) Specific hazards arising from the chemical (e.g. nature of any hazardous combustion
products)
i)
This product is not combustible or explosive.
c) Special protective equipment and precautions for fire-fighters.
i)
As appropriate for surrounding fire
6) Accidental release measures
a) Personal precautious, protective equipment and emergency procedures.
i)
Do not breath dust. Avoid generating dust.
ii)
All personnel engaged in cleanup operations should adhere to the
instructions in Section 8 for personal protection.
iii)
Evacuate unnecessary personnel.
b) Methods and materials for containment and cleanup.
i)
Ventilate area
ii)
Sweep or shovel into appropriate waste containers
iii)
If dusts are generated during the spill, these should be collected. Dampen
prior to sweeping to minimize dust production. Do not empty material
into drains, sewers or water courses as fines harden in contact with water.
Disposal of wastes from cleanup operation should be carried out in
accordance to guidelines outlined in Section 13
7) Handling and Storage
i)
STORAGE - Store in original container in a dry and temperature
controlled area. AVOID FREEZING. Keep container tightly
closed,
when not in use to prevent dry-out and settling.
ii)
HANDLING – Gloves and protective clothing are recommended. Provide
proper ventilation. Clean up application tools and work area with water to
minimize stickiness and prevent drying and potential dust emission.
8) Exposure controls/personal protection
a) Engineering Controls – Use feasible engineering controls, such as, local exhaust
ventilation, point of generation dust collection, emission controlling tools, and handling
equipment designed to minimize airborne fiber emissions.
b) Personal Protection Equipment
i) Respiratory Protection – The moist product when handled properly in a well
ventilated environment is well within the 0.5 f/cc REG and therefore does not
require respiratory protection. Worker requested protection at this level is
satisfied with NIOSH certified respirator, such as a disposable particulate
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IMRIE-GIELOW, INC.
2823 PAPIN ST.
ST. LOUIS, MISSOURI 63103
314-772-4200
SAFETY DATA SHEETS
respirator or respirators with filter cartridges rated N95 or better. The evaluation
of workplace hazards and the identification of appropriate respiratory protection is
best performed, on a case by case basis, by a qualified Industrial Hygienist.
ii) Skin Protection – Chemical gloves are recommended when handling the moist
caulk. Cotton gloves are suitable when working with dry and dusty material.
High levels of dust may require additional protection such as head coverings and
full body clothing to prevent skin irritation. Precautions should be taken with
soiled clothing so as to avoid transporting dust from the work place.
iii) Eye Protection – Wear safety glasses with side shields or other forms of eye
protection in compliance with appropriate OSHA standards to prevent eye
irritation. The use of contact lenses is not recommended, unless used in
conjunction with appropriate eye protection. Do not touch eyes with soiled body
parts or materials. If possible, have eye washing facilities readily available
where eye irritation can occur.
9) Physical and chemical properties
a) Odor and Appearance – Moist fibrous compound
b) Chemical Family – Vitreous Aluminosilicate Fibers
c) Water Solubility (%) – Not soluble in water
d) Density – 90 pcf wet, 50 pcf dry
10) Stability and reactivity
i.
Chemical Stability – Stable under conditions of normal use
ii.
Conditions to avoid – Strong acids and alkalies during installation
iii.
Hazardous Decomposition Products – None
iv.
Hazardous Polymerization – N/A
11) Toxicological information
a) Health Data Summary – Epidemiological studies that include most people who have
ever worked in domestic RFC production have indicated no increased incidence of
respiratory disease or other significant health effects in occupationally exposed workers.
In animal studies, long term, high dose inhalation exposure resulted in the development
of respiratory disease in rats and hamsters.
b) Epidemiology – The University of Cincinnati is conducting an ongoing epidemiologic
investigation. The evidence obtained from employees in U.S. RCF manufacturing
facilities show: no evidence of any fibrotic lung disease and no evidence of an elevate
incidence of lung disease.
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IMRIE-GIELOW, INC.
2823 PAPIN ST.
ST. LOUIS, MISSOURI 63103
314-772-4200
SAFETY DATA SHEETS
c) Toxicology – A number of toxicological studies designed to identify any potential
health effects from RCF exposure have been completed. The results have been
conflicting as the level of exposure was above maximum tolerated does. Additional
studies in the same protocol showed no statistically significant increase in lung cancer.
d) Amorphous silica: Toxic effects described in animals from single inhalation exposures
of amorphous silica included upper respiratory irritation, lung congestion, bronchitis and
emphysema. Repeated inhalation exposures at concentrations of 50 or 150 mg/m cubed
produced increased lung weights and lung changes. No progressive pulmonary fibrosis
was seen and the observed lung changes were reversible. No adverse effects were
observed in this study at 10 mg/m cubed. No animal test reports are available to define
the carcinogenic, mutagenic or reproductive effects.
12) Ecological information – No ecological concerns have been identified
13) Disposal considerations
a)Waste Management – To prevent waste materials from becoming airborne during waste
storage, transportation and disposal, a covered container or plastic bagging is
recommended.
b) Disposal – RCF, as manufactured, is not classified as a hazardous waste according to
Federal regulations (40 CFR 261). As manufactured, RCF was tested using EPA’s
Toxicity Characteristic Leaching Procedure (TCLP). Results showed there were no
detectable contaminants or detected leachable contaminants that exceeded the regulatory
levels. Any processing, use, alteration or chemical additions to the product, as purchased,
may alter the disposal requirements. Under Federal regulations, it is the waste
generator’s responsibility to properly characterize a waste material, to determine if it is a
“hazardous” waste. Check local, regional or state regulations to identify all applicable
disposal requirements.
14) Transportation information
a) UN number: N/A
b) UN proper shipping name: Product name
c) Transport hazard class: Not regulated
d) Packing group, if applicable: N/A
15) Regulatory information
i)
EPA – SARA Title III – This product does not contain any substances
reportable under Sections 302, 304, 313, (40 CFR 372). Sections 311 and
312 (40 CRF 370) apply – delayed hazard. TSCA – RCF has been
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IMRIE-GIELOW, INC.
2823 PAPIN ST.
ST. LOUIS, MISSOURI 63103
314-772-4200
ii)
iii)
iv)
SAFETY DATA SHEETS
assigned a CAS number; however it is not required to be listed on the
TSCA Inventory. CERCLA and the CAA – RCF contains fibers with an
average diameter greater than one micron and thus is not considered a
hazardous air pollutant.
OSHA – Comply with the HCS 29 CFR 1910.1200 and @9 CFR1296.59
and the Respiratory 29 CFR1910.134 and CFR 1926.103
California – Ceramic fibers (airborne particles of respirable size) is listed
in PROPOSITION 65, THE SAFE DRINKING WATER AND TOXIC
ENFORCEMENT ACT OF 1986 as a known to the State of California to
cause cancer.
Other States – RCF products are not known to be regulated by states
other than California; however, state and local OSHA and EPA
regulations may apply to these products. If in doubt, contact your local
regulatory agency.
16) Other information, including date of preparation or last revision
a) SDS – I-G Caulk
b) Issue Date – August 27, 2015
c) Revision Date – N/A
d) Revision # - N/A
Disclaimer: The information presented in this Safety Data Sheet is based on data
believed to be accurate as of the date this Safety Data Sheet was prepared. The
information above is provide on the condition that parties receiving the product make
their own determination as to the suitability of the product for their particular purpose
and assume the risk of use of the product. NO WARRANTY OF
MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE, OR ANY
OTHER WARRANTY IS EXPRESSED OR IS TO BE IMPLIED REGARDING THE
ACCURACY OR COMPLETENESS OF THE INFORMATION PROVIDED AVOVE,
THE RESULTS TO BE OBTAINED FROM THE USE OF THIS INFORMATION OR
THE PRODUCT, THE SAFETY OF THIS PRODUCT OR THE HAZARDS
RELATED TO ITS USE.
Imrie-Gielow, Inc. has no responsibility or liability for any damage or injury resulting
from abnormal use or from failure to adhere to recommended procedures.
<<<<END OF SDS>>>>
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