Brandon Waltman FUEL CELL VEHICLES: A VIABLE ALTERNATIVE TO COMBUSTION ENGINES Brandon Waltman (bsw21@pitt.edu) INTRODUCTION: “ZERO EMISSION” VEHICLES, WHY ARE THEY SO IMPORTANT? The issue of creating an economically viable and consumer-friendly zero-emission vehicle is of grave concern to me as a future engineer. It is a matter of whether or not I will be living on a planet that has the ability to sustain life as well as it does today. Education on this issue is necessary if engineers wish to continue to better our planet through innovation. Aside from innovation, there is a code of ethics for engineers that are unflinchingly rigid. They uphold and advance the honor, dignity, and integrity of our profession and allow us to respectfully and effectively service society [6]. It is imperative that the United States shifts its focus from gasoline-powered vehicles to an alternative fuel source in order to reduce harmful emissions as well as reduce our dependence on foreign oil. The U.S. relied on net imports for about 45% of the petroleum we consumed in 2011. Fortunately, dependence foreign oil has declined since peaking in 2005 [4]. Moving to an alternative fuel source is also becoming necessary as a means of preserving the earth for future generations. The International Energy Agency warns that we are headed toward irreversible climate change if fossil fuel infrastructure is not changed within the next five years, as we have nearly swallowed up our entire “carbon budget”[5]. Since carbon dioxide gas is one of the primary byproducts of combustion engines, changing the way we power our vehicles is necessary to prevent permanent, irreversible damage to our environment. Several challenges must be overcome in order to make Fuel Cell Vehicles (FCV’s) competitive with conventional gas-powered vehicles, but the potential benefits are substantial [1]. THE BASICS OF FCV’S: HOW DO THEY WORK? Fuel Cell Vehicles look nearly identical to today’s gas-powered cars on the outside, but instead of a combustion engine, fuel cell stacks power them. The fuel cell stack converts hydrogen stored on board with oxygen from the air to produce electricity that is used to propel the car. Since each individual fuel cell produces only about 1.16 Volts of electricity, they must be assembled in stacks in order to produce enough power to drive the vehicle [1]. Polymer Electrolyte Membrane (PEM) Fuel Cells PEM fuel cells are typically used to power vehicles, and use stored hydrogen and oxygen from the air to produce electricity. On a basic level, the fuel cell consists of a cathode and an anode separated by a polymer electrolyte membrane that only allows positively charged ions to pass though to the cathode. There are hydrogen flow plates on the side of the anode and oxygen flow plates on the side of the cathode. The process can be outlined in four steps: FIGURE 1, PEM FUEL CELL The diagram above outlines the four basic steps in which a standard PEM fuel cell generates electricity [1]. HYDROGEN FUEL CELLS VERSUS BATTERY-ELECTRIC MOTORS As far as the competition for alternatives to traditional combustion engines, hydrogen fuel cells currently trail behind battery-electric motors. The Obama admini stration abandoned Bush’s work on FCV’s, and instead launched an aggressive program to further develop a new generation of high-performance batteries, the factories that produce them, and the vehicles they would power. The three Brandon Waltman key points of this legislation were to get the country off oil, reduce CO2 emissions, and invigorate a new era of American manufacturing. However, electric cars are off to a slow start. They are not selling as fast as was originally predicted, and battery costs seem likely to remain high [2]. It seems as though the Obama administration would be best off to reconsider its initial hostility toward the zero emission hydrogen fuel cell program. There are initial cost advantages that come along with battery-powered vehicles. They will sell at a lower price than if car manufacturers were to roll out FCV’s right now, and the price of battery-powered vehicle is already quite a bit higher than a comparable gas-powered car [2]. However, the advantage of hydrogen fuel cell powered vehicles comes in refueling and range. A typical hydrogen tank can be refilled in 2-3 minutes while a battery will take about 8 hours to fully recharge. The most substantial difference comes in the range of the vehicle on a single tank or charge. A FCV can travel about 250-300 miles on one tank while an electrified car can only go 40-100 miles on a single charge, depending on the specific vehicle [2]. This is a huge setback to battery-powered vehicles. Challenges WEIGHING OUT THE CHALLENGES AND BENEFITS OF HYDROGEN FUEL CELLS Benefits Less greenhouse gasses- Zero emission means no greenhouse gases are emitted directly from the vehicle. Producing hydrogen to power FCV’s can produce greenhouse gasses, but it is much less than what is produced by conventional gas and diesel engines [1]. Less Air Pollutants- gasoline-powered vehicles contribute greatly to the high amount of air contaminants that cause smog. If hydrogen production requires fossil fuels it still release a significantly less amount of pollutants into the air. Reduced Dependency on Foreign Oil- the United States is overly reliant on foreign companies for crude oil. Hydrogen can be produced domestically greatly reducing the effect of oil supply shocks on our economy [1]. On Board Hydrogen Storage- There are FCV’s that are capable of storing enough hydrogen to give it the same range per fill up as an average gaspowered car: about 300 miles. However, this needs to be achieved across all makes and models [1]. It also requires the construction of all new fueling stations Cost- Cost needs to be reduced if FCV’s are to be competitive with gas-powered cars. The focus needs to be on reducing the cost of production, specially that of the fuel cell stacks[1]. They require platinum as a catalyst to spark the reaction, which is not cheap [2]. Also, the cost of building a sufficient amount of fueling stations must be accounted for. According to General Motors, a full fleet will require at least 11,000 fueling stations coast to coast, at a grand total of around $20-$25 billion. In California, the state has already allocated funding for hydrogen fueling stations; 26 are either already in place or funded. Durability- In certain environmental conditions, some fuel cells are not as reliable as traditional combustion engines. Currently hydrogen fuel cell engine durability is at about half of what it needs to be; 75,000 miles. By 2015, the target mileage per engine is 150,00 miles [1]. Public Acceptance- In order for the shift from gas to hydrogen-powered vehicles to be successful it requires that the general public embrace it. The introduction of the gas-electric hybrid can be used as a model. FCV’S ARE MORE THAN JUST A MODE OF TRANSPORTATION FIGURE 2, GRAMS OF CO2 PER MILE Bar graph charting the amount of GHG’s per mile produced [1]. Honda has turned their fuel cell sedan, the FCX Clarity, into more than just a car by equipping it with electrical outlets and a solar-powered hydrogen-fueling system. It features a box of power outlets in the rear that allow it to act as a 9kW generator. Also, Honda has installed a new hydrogen fueling station in Saitama, Japan that creates hydrogen using only the sun and water by Brandon Waltman utilizing a high-pressure water electrolysis system. In 24 hours it can produce about 1.5 kg of hydrogen, enough to power the FCX clarity for 90 miles. This is an exciting development. It indicates that hydrogen-fuel-cell-powered vehicles could become part of a smart grid system in which the cars can be used as emergency generators in times of high power demand [3]. A MATTER OF ETHICS The topic of morality is always an underlying issue. However, for engineers, the National Society of Professional Engineers code of ethics as well as a number of other codes of ethics for the respective fields of engineering serve as a guideline to allow us to better society while protecting the integrity of our profession [10]. The first fundamental canon of the NSPE code of ethics states that “Engineers, in the fulfillment of their professional duties, shall hold paramount the safety, health, and welfare of the public.” The two main concerns regarding the safety of FCV’s are the flammability of the fuel and possibility of electric shock. This is an obvious threat to the safety of the consumer, posing a potential conflict with the fist cannon of the NSPE code of ethics. It is disclosed the industry standard for the vehicles is a 42-volt system. Anything higher than 50 volts has the potential to stop a human heart [6]. Fueling the vehicles involves transfer of hydrogen and must be carefully controlled in order to ensure the safety of the operator. In March, SAE (Society of Automotive Engineers) Technical Information Report J2601, “Fueling Protocols for Light Duty Gaseous Hydrogen Surface Vehicles,” was released. This is in accordance with canon 3, sections A and B respectively stating “Engineers shall be objective and truthful in professional reports, statements, or testimony. They shall include all relevant and pertinent information in such reports, statements, or testimony, which should bear the date indicating when it was current” and “Engineers may express publicly technical opinions that are founded upon knowledge of the facts and competence in the subject matter” [9]. The document establishes safety limits and performance requirements for gaseous hydrogen fuel dispensers. The criteria include maximum fuel temperature at the dispenser nozzle, maximum fuel flow rate, maximum rate of pressure increase, and other performance criteria based on the cooling capability of the station’s dispenser. Fueling stations must employ algorithms and special fueling equipment in order to keep within these guidelines. Also, vehicles fueling at these stations must be designed appropriately for fueling [7]. Engineers are rightfully working within the guidelines within the code of ethics to protect the safety and wellbeing of the consumer. EDUCATION: PAVING THE WAY FOR FUTURE ENGINEERS The preamble of the NSPE code of ethics states, “Engineering is an important and learned profession. As members of this profession, engineers are expected to exhibit the highest standards of honesty and integrity. Engineering has a direct and vital impact on the quality of life for all people” [9]. There will come a point where a new generation of engineers must step up and take over the responsibilities of those above them, and in order to preserve this valued history of integrity, they must be trained in the practice of engineering and to perform under a standard of professional behavior that requires adherence to the highest principles of ethical conduct [9]. Institutes of higher learning that offer degrees in any field of engineering must value the quality of education they are delivering to their students. They have to prepare their students to the best of their ability to assume the immense responsibility that comes with being a professional engineer. The structures, systems, and processes we design have a sever impact the everyday lives of anyone who uses them, so there is no margin for error. It is our responsibility to ensure that those rising to the professional level are experts in their respective field, and strictly follow the code of ethics. Specifically, if one is to deal with the design of hydrogen-powered vehicles, they have to be properly educated in doing so. It must be understood that they are dealing with many people’s lives. So how can such a high standard of proficiency be achieved? It all starts here: the freshman-engineering program. A study done by the Journal of Engineering Education concluded the quantity and quality of students’ formal curricular experiences and their co-curricular experiences bared heavy relation to ethics. They suggest that institutions integrate ethics instruction throughout the formal curriculum, support use of varied approaches that foster high-quality experiences, and leverage both influences of cocurricular experiences and students’ desires to engage in positive ethical behaviors [8]. Assignments such as this introduce us future engineers to the strict and rigorous process that must be followed when creating or improving on a product. It introduces us to the code of ethics that upholds the values of our future profession. Although it is such a small part of our overall education, it is an important stepping-stone in leading us to our overall goal. WHY GO WITH HYDROGEN FUEL CELL POWERED VEHICLES? The over use of fossil fuel as a way to power our vehicles puts the United States in danger of over dependency on foreign oil producers, making our economy dangerously susceptible to large fluctuations in the price of crude oil as a Brandon Waltman result of supply shock [4]. It would allow us to domestically produce hydrogen, creating jobs in the process [1]. On an even grander scale, the world is in danger of suffering irreversible climate change, and highway vehicles are one of the main causes of the greenhouse gases that are depleting the ozone [5]. This must not be overlooked. The technology is there, it is just a matter of whether or not we choose to utilize what we have, and continue to further develop it. In order to do this, it is necessary that we focus our attention on the next generation of engineers. They are the ones we will pass the torch to. We engineers want to ensure that they continue to exhibit the highest standards of integrity and honesty that is expected of our profession. It is imperative they are educated in the practice as well as the ethics of engineering. With the efforts of current and future engineers, the support general public and government alike, Changing the way we power our transportation is something that is very achievable. [1] (Oct. 5, 2012). “Fuel Cell Vehicles”. U.S. Department of Energy. (Website). http://www.fueleconomy.gov/feg/fuelcell.shtml. [2] S. Levine. (May 17, 2012). “Giving Hydrogen Fuel-Cell Cars Another Chance”. Future Tense: A collaboration of Slate, the New America Foundation, and Arizona State University. (Online Article). http://www.slate.com/articles/technology/future_tense/2012/ 05/hydrogen_fuel_cell_vehicles_and_the_obama_administra tion_.single.html. [3] K. Barry. (Apr. 9, 2012). “Honda Turns Their Fuel Cell Sedan Into A Portable Generator”. Wired.com. (Online Article). http://www.wired.com/autopia/2012/04/hondaturns-their-fuel-cell-sedan-into-a-solar-powered-generator/. [4] (July 13, 2012). “How Dependent Are We On Foreign Oil?”. U.S. Department of Energy. (Website). http://www.eia.gov/energy_in_brief/foreign_oil_dependence .cfm. [5] F.Harvey. (Nov. 9, 2011). “World Headed For Irreversible Climate Change In 5 Years, IEA Warns.” The Guardian. (Online Article). http://www.guardian.co.uk/environment/2011/nov/09/fossilfuel-infrastructure-climate-change. [6] J. Runge. (March 12, 2003). “Safety issues regarding fuel cell vehicles and hydrogen fueled vehicles”. The International Consortium for Fire Safety, Health, and the Environment. (online article). https://dps.mn.gov/divisions/sfm/programsservices/Documents/Responder%20Safety/Alternative%20F uels/FuelCellHydrogenFuelVehicleSafety.pdf [7] (March 16, 2010) “Fueling Protocols for Light Duty Gaseous Hydrogen Surface Vehicles” SAE International. (online document). http://standards.sae.org/j2601_201003/ [8] (July 2012) “An Assessment of Engineering Students’ Curricular and Co-Curricular Experiences and Their Ethical Development” Journal of Engineering Education. http://www.jee.org/2012/July/04 [9] (July 2007) “NSPE Code of Ethics for Engineers”. National Society of Professional Engineers. (website). http://www.nspe.org/Ethics/CodeofEthics/index.html [10] “Code of Ethics for Engineers.” American Society of Mechanical Engineers. (website). http://www.asme.org/groups/educationalresources/engineers-solve-problems/code-of-ethics-ofengineers ACKNOWLEDGEMENTS My gratitude goes out to Dominic Stokes, my resident advisor, for providing me with the advice and summoning the willpower that allowed me to complete this assignment to the best of my ability. His infinite knowledge of campus buildings allowed me to find areas in which I could access the depths of my knowledge reserves. My colleague, Victor Abram, deserves special recognition as my lone partner as we began on this endeavor into the abyss.