- apcseet2013

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Please sent your abstract(s) in MS Word as an attached file together with e-mail text to
apcseet2013@gmail.com by March 15, 2013, if any room in the session)
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Example of the ordinary paper only for regular participants/regular students
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Name of presenter with title (or Mr. or Ms.): Prof. Toshinori KOJIMA: Dept. Materials and Life
Science, Seikei Univ., Japan; kojima@st.seikei.ac.jp, kojimaseikei@gmail.com; +81-422-37-3871 (fax)
Prior paper: oral; Journal of Chemical Engineering Japan
Influence of pH and Dissolved Fe Ion Concentration on Decomposition of
Trichloroethylene with Fenton’s Reaction Using Iron Powder
Yasuhiko TAKUMA(1), Toshinori KOJIMA(2*), Shigeru KATO(2), Shigeo SATOKAWA(2), Akihiro
YAMASAKI(2)
(1) Development Div., Tokyo Metropolitan Ind. Technol. Res. Inst,, Japan, takuma.yasuhiko@iri-tokyo.jp
(2*) Dept. Materials and Life Sci., Seikei Univ., Japan, kojima@st.seikei.ac.jp
Abstract: The decomposition rate of trichloroethylene (TCE) by Fenton’s reaction using iron
powder was investigated especially on the influence of pH and dissolved Fe ion concentration in
the presence and absence of buffer solution to maintain pH value. The decomposition rate
depended on hydrogen peroxide concentration, and the maximum rate was observed. This finding
was explained by the consumption of hydroxyl radicals by a competing reaction with hydrogen
peroxide against TCE decomposition by the hydroxyl radicals produced from hydrogen peroxide.
The most rapid dissolution rate of iron, i.e., the maximum increasing rate of Fe ion concentration,
----max 150 words
Keywords: Polluted soil; Trichloroethylene; Fenton’s reaction; Reaction kinetics
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