Notes Chapter 3: Matter and Energy Matter is anything that has mass and takes up space (volume) In other words it is ‘stuff’, ‘things’, whatever is NOT energy Chemistry-1 Notes Chapter 3 Page 1 of 22 Matter comes in three states (or phases): State Solid Definition has a fixed volume and a fixed shape Liquid has a fixed volume but takes the shape of its container Examples ice cubes, diamond, iron bar gasoline, alcohol, water, blood has no fixed volume Gas or shape; it takes the volume & shape oxygen, helium, air of its container Chemistry-1 Notes Chapter 3 Page 2 of 22 Molecular Arrangement in the Three States Solid (Ice) Liquid (Water) Gas (Steam) Molecules are held close together by strong forces; molecules are in a crystalline pattern Molecules are loosely held together by weaker forces; molecules can flow around each other Molecules are NOT held together at all; molecules are independent of each other Chemistry-1 Notes Chapter 3 Page 3 of 22 Physical Properties and Physical Changes Physical properties of a substance include: color, odor, mass, volume, density, aanndd state (solid, liquid, gas) (In other words it is a characteristic of a substance that can change without the substance becoming a different substance) Physical changes include: cutting, breaking, expanding, contracting, aanndd Chemistry-1 changes in state (melting, solidifying, evaporating, and condensing) Notes Chapter 3 Page 4 of 22 (In other words it is a change in a substance without the substance becoming a different substance) The Molecules Remain Intact (unchanged). Chemistry-1 Notes Chapter 3 Page 5 of 22 Distilling Saltwater is a Physical Change. Distillation (physical method) + Salt Saltwater solution Pure water (homogeneous mixture) Steam is condensed in a tube cooled by water. Cooling water in Saltwater Cooling water out Pure Bunsen burner water Chemistry-1 Notes Chapter 3 Page 6 of 22 Salt Pure Water a.k.a. Distilled Water Chemistry-1 Notes Chapter 3 Page 7 of 22 Filtration also is a Physical Change Mixture of Solid and Liquid Filter paper traps solids Stirring Rod Funnel Filtrate - liquid component of the mixture Chemistry-1 Notes Chapter 3 Page 8 of 22 Chemical Properties aanndd Chemical Changes Chemical properties of a substance include: ability to react with oxygen, ability to react with water, decomposing, aanndd burning. In other words it is the ability to form new substances. Chemical changes include: wood burning, iron rusting, food digesting, grass growing Chemistry-1 Notes Chapter 3 Page 9 of 22 In other words a substance changes into a different substance (or substances) The Molecules Change Into Different Molecules. Chemistry-1 Notes Chapter 3 Page 10 of 22 Elements, Compounds, aanndd Mixtures Elements: they are made up of only one kind of atom are the simplest form of matter are the purest form of matter are represented by a chemical symbol cannot be broken down into other substance by any means. Examples: Gold (Au), Silver (Ag), Oxygen (O22) Compounds: compounds are pure substances are made up of two or more kinds of atoms chemically bonded into molecules. the molecules of a compound are always the same. the kinds of atoms that make up the compound are always in definite proportions Chemistry-1 Notes Chapter 3 Page 11 of 22 can be represented by a chemical formula and they have a chemical name can be broken down into other substances by chemical changes only. Examples: Carbon Dioxide (CO22), Water (H22O), Salt (NaCl), Sugar (C66H1122O66) Mixtures: are made up of two or more substance NNOOTT chemically combined. the substances in the mixture are combined in any proportion do not have a chemical formula and do not have a chemical name Heterogeneous mixtures: Chemistry-1 Notes Chapter 3 Page 12 of 22 contain regions that have a different proportion of substances (and so have different properties) from other regions of the mixture. Examples: blood, cereal & milk, cement Homogeneous mixtures: are the same throughout. Every part of the mixture contains the same proportion of ingredients. Homogeneous mixtures are called solutions Examples: saltwater, tea, air, alloys Chemistry-1 Notes Chapter 3 Page 13 of 22 Heat Energy Energy: the capacity to do work (using a force to move an object). when the temperature of an object is raised, the molecules have more energy and therefore move more. The amount of energy (heat) needed to raise the temperature of one gram of water by one degree Celcius is a . . . calorie. the unit of energy used in the metric system is the joule. You can convert between joules and calories using the following equation (conversion factor) Chemistry-1 Notes Chapter 3 Page 14 of 22 1 cal = 4.184 Joules In other words, it takes 4.184 J of energy to raise the temperature of 1.0 g of water 1°C. Specific Heat Capacity What is it?: You know it takes 4.184 J of energy to heat up one gram of W WA AT TE ER R by 1°C. How much energy does it take to heat up one gram of A AL LU UM MIIN NU UM M by 1°C? How about one gram of C CA AR RB BO ON N? Chemistry-1 Notes Chapter 3 Page 15 of 22 The amount of energy it takes to heat up one gram of a substance by 1°C is that substance’s S SP PE EC CIIF FIIC CH HE EA AT T. A high specific heat means it takes a large amount of energy to raise the temperature of that substance; whereas a low specific heat means it takes a small amount of energy to raise the temperature of that substance. Chemists describe this difference by saying that substances have different H HE EA AT TC CA AP PA AC CIIT TIIE ES S. The Specific Heat Capacity of Water is 4.184 J/g-°C Finding the Specific Heat of a Substance Energy (heat) required (Q) Chemistry-1 = Specific Heat Capacity (s) Mass (m) in grams of sample x Notes Chapter 3 Change in x temperature (T) in °C Page 16 of 22 Q Q = s xx m x T ss == Q Q m m xx TT There are two symbols for specific heat: s and Cp. We will use them interchangeably so you can learn both of them. Chemistry-1 Notes Chapter 3 Page 17 of 22 Let’s try a sample problem A 35.2 g sample of a metal requires 1,251 J of energy to heat the sample by 25.0°C. Calculate the specific heat of the metal. ss == Q Q m m xx TT ss == ss == ss == Chemistry-1 11,,225511 JJ 3355..22 gg xx 2255..00ooCC 11,,225511 // 3355..22 // 2255..00 11..4422 JJ gg -- °°CC JJ gg -- °°CC Notes Chapter 3 Page 18 of 22 Let’s try a little harder problem A 25.0 g sample of pure iron at 85°C is dropped into 75.0 g of water at 25°C. What is the final temperature of the water – iron mixture? We know the specific heat of water is: 4.184 J/g-°C From Table 3.2 on page 73 we know the specific heat of iron is: 0.45 J/g-°C Remember, T is the change in temperature T = higher temp. - lower temp. Iron is cooling, so it’s initial temp. is higher For Iron: T = (Tii – Tff) Water is heating, so it’s final temp. is higher For Water: T = (Tff – Tii) Chemistry-1 Notes Chapter 3 Page 19 of 22 First let’s find the amount of heat lost by the iron. Q Q = s xx m xx TT Q Q = 0.45 J/g-°C xx 25.0 g x (85° - Tff) Q Q = 11.25 x (85 - Tff) J Chemistry-1 Notes Chapter 3 Page 20 of 22 Next, let’s find the amount of heat gained by the water. Q Q = s xx m xx TT Q Q = 4.184 J/g-°C xx 75.0 g x (Tff - 25°) Q Q = 313.8 x (Tff - 25°) J Since the amount of heat lost by the iron is equal to the amount of heat gained by the water, we can set these two ‘heats’ (Q’s) equal to each other. 11.25 x (85 - Tff) = 313.8 x (Tff - 25) First, distribute the 11.25 and the 313.8 by multiplying them with what’s in the parenthesis. You will end up with this: 956.25 - 11.25Tff = 313.8Tff - 7,845 Next, solve for Tf. There are a number of ways to do this. One way would be to add 7,845 to both sides of the equation, then add 11.25Tf to both sides of the equation. You’ll end up with the following: 8,801 27°C Chemistry-1 = 325Tff = Tff Notes Chapter 3 Page 21 of 22 Oh, I see! This is just basic algebra. As long as I have my calculator I can do these! Oh, sure. . . You better do a few more practice problems kiddo. Chemistry-1 Notes Chapter 3 Page 22 of 22