Name: __________________________________________________ Period:_____ 2014 Chemistry I Level Final Exam Review 1. Review all your quizzes and “Story so far” sheets for every UNIT 1-12. 2. Complete the Review Study Guide. The more practice, the better you will feel on the day of your Chemistry final exam. Remember “Chem-is-try” Good luck! The Atom and the Periodic Table Locate and label the Alkali metals, Alkali-Earth metals, Transition elements, Metalloids, Halogens, and Nobel Gases using this Periodic Table: 1. Identify the following elements: (a) The most reactive nonmetal on the Periodic Table (b) The least reactive Halogen. (c) The least reactive member of the fifth period. 2. Explain why the atoms of the elements at the bottom of a given group (vertical column) are larger than the atoms of the elements at the top of the same group. 3. Arrange the following sets of elements in order of increasing atomic size: (a) Sn, Xe, Rb, Sr 4. Define ionization energy: 5. In the following set of elements, which element would be expected to have the highest ionization energy? (a) Cs, K, Li Elements Aa and Cc are in the same group, Bb and Dd are in the same group, Aa and Bb are in the same period, and Cc and Dd are in the same period. Which has the greatest ionization energy? 6. Which has the greatest ionization energy? a. Aa b. Bb c. Cc d. Dd 7. Which has the largest atomic radius? a. Aa b. Bb c. d. Cc Dd 8. Which has the most electrons? a. Aa b. Bb c. d. Cc Dd 9. Which will require the least amount of energy to remove an outer electron from? a. Aa c. Cc b. Bb d. Dd 10. How many valence electrons does each of the following atoms possess? a. Sodium c. Chlorine b. Magnesium d. Neon 11. How are the electron arrangements in a given group (vertical column) of the periodic table related? 12. Which of the following groups of atoms have the same outermost valence electron configurations but with electrons in different energy levels? a. N, O, F, Ne b. S, Cl, Ar, K c. O, S, Se, Te 13. The elements chlorine and iodine have similar chemical properties because they: a. are both metals b. are in the same chemical period c. have the same number of electrons in their outer energy levels d. have the same number of stable isotopes 14. Which three elements are likely to have similar chemical and physical properties? a. sodium, lithium, and potassium b. sodium, magnesium, and aluminum c. nitrogen, oxygen, and neon 15. Locate Magnesium (#12), Calcium (#20), and Strontium (# 38). What do these elements have in common? Directions: Fill in the following information for chlorine: 35 16. The scientist whose alpha-particle scattering experiment led him to conclude that the nucleus of an atom contains a dense center of positive charge is: a. J. J. Thomson b. Ernest Rutherford c. Lord Kelvin d. James Chadwick 17. The identity of an element is determined by its: a. mass number b. atomic number c. number of neutrons d. atomic mass 18. Which atomic particle determines the chemical properties of the atom? a. Proton c. Electron b. Neutron d. Quark 19. What subatomic particle is never found in the atomic nucleus? a. Proton b. Neutron c. Electron 20. How many protons, electrons, and neutrons does the following isotope of iodine contain? 12753 I 21. Give the isotopic notation for an atom containing 6 protons and 8 neutrons. 22. If an atom of an element has a mass number of 201 and has 121 neutrons, what is the isotopic notation of the element? 23. An atom of an element has an atomic number of 24 and a mass number of 52. What is the isotopic notation, the name, and the number of protons, neutrons, and electrons in this atom? 24. Three isotopes of argon occur in nature: argon-36, argon-38, and argon-40. Calculate the average atomic mass of argon, given the following relative atomic masses and abundances of each of the isotopes: argon-36 (3.7%), argon-38 (6.3%), and argon-40 (90%). Electrons and Ions 25. Metals tend to ___________________ elections; Non-metals tend to ___________________ electrons. (LOSE or GAIN) 26. Which of the following is NOT a molecular compound? How do you know? a. P2O5 c. H2O b. NaF d. PCl3 27. How many protons, neutrons, and electrons are present in 42He? Protons: Neutrons: Electrons: 28. How many protons, neutrons, and electrons are present in 3717 Cl? Protons: Neutrons: Electrons: 29. How many protons, neutrons, and electrons are present in 4020 Ca? Protons: Neutrons: Electrons: 30. How many protons, neutrons, and electrons are present in the 2412 Mg+2 ion? Protons: Neutrons: Electrons: 31. How many protons, neutrons, and electrons are present in the 9140 Zr+4 ion? Protons: Neutrons: Electrons: 32. How many protons, neutrons, and electrons are present in the 7934 Se-2 ion? Protons: Neutrons: Electrons: Directions: Name and write chemical formulas for the following compounds. Circle all molecular compounds. Compound 33. NaOH 34. MgBr2 35. SiO2 36. FeCl2 37. Zn(OH)2 38. Be2SO4 Name of Compound Molar Mass of Compound 39. P4O10 40. N2O Compound 41. sodium phosphide 42. magnesium nitrate 43. lead (II) sulfite 44. calcium phosphate 45. bromine monofluoride 46. aluminum sulfide 47. disulfur dichloride 48. copper (I) arsenide Formula of Compound Molar Mass of Compound Counting Atoms: Calculate the total number of atoms of each of the following elements Na = 2 49. Na2CO3 C=1 52. Be(OH)2 O=3 50. Al2(SO4)3 51. 4 Pb(OH)4 53. 3 C2H3O2 54. 3 Ca3(PO4)2 Types of Chemical Reactions Identify each of the equations below as synthesis, decomposition, single displacement, combustion, or double displacement reactions. 55. KClO3 → KCl + O2 56. Zn + CuSO4 → ZnSO4 + Cu 57. Mg + O2 → MgO2 58. C10H8 + O2 → CO2 + H2O 59. Ca(OH)2 + HNO3 → Ca(NO3)2 + H2O Directions: Balance the following chemical reactions and indicate the type of chemical reaction. Include particle pictures of the reactants and products in each balanced chemical reaction. 60. ____ KClO3 → ____ KCl + ____ O2 Reactants 61. ____ Fe + ____ H2O → ____ Fe2O4 + ____ H2 Reactants 62. Products ____ H2SO4 + ____ NaCl ____ HCl + ____ Na2SO4 Reactants 63. Products Products ____ SO2 + ____O2 ____SO3 Reactants Products Solubility Rules 1. All compounds containing an element from Group 1A are soluble 2. All compounds containing ammonium (NH4+) are soluble 3. All compounds containing a nitrate ion (NO3-) are soluble Directions: Circle the precipitate (solid) that forms in each reaction. Use the solubility rules provided. 64. AgNO3 (aq) + BaCl2 (aq) AgCl + Ba(NO3)2 65. KOH (aq) + CuSO4 (aq) K2SO4 + Cu(OH)2 66. Na2S(aq) + AgNO3 (aq) NaNO3 + Ag2S 67. Convert from g moles or from moles g. Use proportion. a. 111.7 g Fe = b. 35.45 g of chlorine gas = mol of chlorine gas **** c. 0.15 moles NaNO3 = g NaNO3 d. 1.5 moles NO2 68. Empirical Formula CH NO2 mol of Fe = __________________g NO2 Actual Molar Mass of 78 g/mol Molecular Formula 92 g/mol 69. For each of the following solutions, calculate the Molarity (M). a. 0.50 mol KBr; 250 mL b. 0.50 mol KBr; 500 mL c. 0.50 mol KBr; 1000 mL 70. For each of the following solutions, calculate the Molarity (M). a. 26.89 g CuCl2; 250 mL b. 42 g NaHCO3; 500 mL c. 265 g Na2CO3; 1000 mL 71. In the Kool-Aid lab, the solute was considered the and the solvent was the . 72. Draw particle pictures for the following Kool-Aid (KA) solutions. Include the solute and solvent. Include a total of 10 particles in each picture. 6 M Kool-Aid 2 M Kool-Aid 73. You have 1 L of a 0.5 M aqueous solution of Kool-Aid. You want to dilute the solution to 0.25 M. What do you do? Draw a particle picture before and after the dilution. Compare the solute to solvent before and after the dilution. 0.5 M 0.25 M 74. Calculate the new concentration when 25 mL of a 5.0 M solution of CuSO4 is diuted to 125 mL. Draw a particle picture before and after the dilution. Compare the solute to solvent before and after the dilution. 25 mL of 5.0M CuSO4 75. Which of the following statements is true when diluting a solution? a. The number of moles of solute particles remains constant b. The number of moles of solute particles decreases upon dilution. c. The number of moles of solvent particles decreases upon dilution. 125 mL of ? CuSO4 76. How many moles of water can be prepared from 2.5 moles of oxygen? Equation: _____ H2 + _____ O2 _____ H2O Before Change After (a) How many moles of hydrogen (H2) reacted? (b) How many moles of water (H2O) were produced? 77. How many grams of calcium hydroxide (Ca(OH)2) will be produced from 4.5 moles of calcium hydride (CaH2) with excess water? Equation: ___ CaH2 + ____ H2O ____ Ca(OH)2 + _____H2 Before Change After (a) How many moles of calcium hydroxide (Ca(OH)2) are produced? (b) How many grams of calcium hydroxide (Ca(OH)2) are produced? (SHOW WORK) (c) How many moles of water were consumed? (d) How many grams of water were consumed? (SHOW WORK) Directions: Use the following recipe to answer questions #86 and 87. A cake recipe calls for: 2 cups water 4 cups flour 8 oz butter 4 eggs 4 cups sugar 8 squares chocolate The following ingredients are in your kitchen cabinet: Lots of water 4 eggs 5 cups flour 8 cups sugar 4 oz butter 12 squares of chocolate 78. Which ingredient is the limiting reactant? 79. Which ingredients on hand were in excess of the quantities required for the recipe? a) Water, chocolate, sugar, and butter b) Water, flour, chocolate, and sugar c) Water, flour, sugar, and butter d) Water, flour, sugar, and butter 80. Sodium reacts with chlorine gas to produce sodium chloride. Balance the equation. ______ a. Na + _____ Cl2 _____ NaCl Sketch 10 atoms of sodium and 6 molecules of chlorine gas in the container on the left. In the right container, sketch all the contents after the reaction is complete. Please note: Refer to the chemical equation above to complete the particle pictures. Before After After b. What is the limiting reactant? c. How many atoms of the excess reactant remain? 81. If 2.0 moles of ZnS are combined with 4.5 moles of O2, how many grams of ZnO can be produced? If the limiting reactant is ________ Equation: ____ ZnS _____ O2 + ___ ZnO ____ SO2 + Before Change After If the limiting reactant is ________ Equation: ____ ZnS + _____ O2 Before Change After (a) Which reactant is in excess? (b) Which of the reactants is the limiting reactant? (c) How many moles of the limiting reactant remain? (d) How many moles of ZnO were produced? (e) How many grams of ZnO were produced? (SHOW WORK) ___ ZnO + ____ SO2 82. What ion is present in the highest concentration in an acid? 83. What ion is present in the highest concentration in a base? 84. Draw a particle picture that compares an acid with a pH of 4 to an acid with a pH of 1. Explain the meaning of your picture. pH = 4 pH = 1 Directions: Match the following vocab words with their definitions. _____ 85. Acid A. Produces H+ ions in solution _____ 86. Base B. An acid that barely splits up in water like acetic acid _____ 87. Weak acid C An acid that completely splits up in water, such as HCl _____ 88. Strong acid D. Produces OH- ions in solution Directions: Choose the one alternative that best completes the statement or answers the question. 89. Which one of the following is an acid? A) NaOH C) Ca(OH)2 B) HCl D) phenolphthalein 90. Which one of the following is a base? A) NaOH B) H3PO4 91. 92. C) HC2H3O2 D) universal indicator Of the following pH values, which one is the most acidic? A) 10 B) 3 C) 1 D) 8 E) 5 Of the following pH values, which one is the most basic? A) 8 B) 5 C) 3. D) 10 E) 1 93. Which of these solutions has the lowest pH? a. 10-2 M H+ concentration b. 10-1 M OH - concentration -3 + c. 10 M H concentration d. 10-12 M H+ concentration Directions: Complete the pH table below. [H+] 94. [OH-] pH pOH Acid or Base 1 x 10-3 M 1 x 10-5 M 95. Directions: Complete the data table. Make sure you draw the electron pairs clearly Total # of Valence Electrons 96. PI3 97. H2O 98. COH2 99. CO2 100. CF2Cl2 101. NO3 -1 Lewis Dot Structure Molecular Shape Name Polar or Nonpolar