Naming Binary, Bi-Valent Ionic Compounds- notes Honors Chemistry Name_____________________________ Period____ Ionic compounds are compounds composed of ions, charged particles that form when an atom (or group of atoms, in the case of polyatomic ions) gains or loses electrons. A cation is a positively charged ion Metal Ion Systematic name Common name An anion is a negatively charged ion. 2+ Chromium Cr chromium(II) ion chromous ion Ionic compounds are formed when a metal reacts with a nonmetal (or a Cr3+ chromium(III) ion chromic ion polyatomic ion. These notes will not Cobalt Co2+ cobalt(II) ion cobaltous ion deal with polyatomic ions.) 3+ Co cobalt(III) ion cobaltic ion Many Transition group metals can form Copper Cu+ copper(I) ion cuprous ion more than one cation. 2+ Many of these ions have common or Cu copper(II) ion cupric ion trivial names formed from the stem of Iron Fe2+ iron(II) ion ferrous ion the element name (the Latin name in 3+ Fe iron(III) ion ferric ion some cases) plus the ending -ic or -ous. Manganese Mn2+ manganese(II) ion manganous ion ic endings go with the higher possible charge Mn3+ manganese(III) ion manganic ion ous endings go with the lower possible Mercury Hg22+ mercury(I) ion mercurous ion charge Hg2+ mercury(II) ion mercuric ion The systematic names (also known as 2+ Nickel Ni nickel(II) ion nickelous ion the Stock system) for these ions are Ni3+ Nickel(III) ion nickelic ion derived by naming the metal first, 2+ followed in parentheses by the charge Tin Sn tin(II) ion stannous ion written in Roman numerals. Sn4+ tin(IV) ion stannic ion For the metals that typically form only 2+ Pb lead(II) ion plumbous ion one charge, it is not necessary to specify Lead Pb4+ lead(IV) ion plumbic ion the charge in the compound name. For example, iron can form two possible ions, 2+ and 3+. The Fe2+ ion is known as the ferrous ion (common) or the iron(II) ion (systematic); the Fe3+ ion is known as the ferric ion (common) or the iron(III) ion (systematic). The mercury(I) cation is a special case; it consists of two Hg+ ions joined together, and so is always found as Hg22+. (Hence, mercury(I) chloride is Hg2Cl2, not HgCl, while mercury (II) chloride is HgCl2.) ions Stock name Common name FeCl2 ________________________ Cu2O _________________________ ___________________________ _________________________ ___________________________ 1. SnS2 p ___________________________ Honors Chemistry Nomenclature Worksheet #1 Name_____________________________ Period_____ Write the formulas for the following ionic compounds: 1) titanium (IV) oxide __________________________ 2) calcium bromide ___________________________ 3) ferrous chloride ___________________________ 4) chromic oxide ___________________________ 5) manganese (VII) arsenide _____________________ 6) vanadium (V) nitride __________________________ 7) platinum (II) sulfide ___________________________ 8) iron (II) arsenide ___________________________ 9) beryllium chloride ___________________________ 10) silver oxide ___________________________ 11) potassium sulfide ___________________________ Name the following ionic compounds. When appropriate provide the stock and common name: 12) KI __________________________________________________________________________________ 13) SnBr4 _________________________________________________________________________________ 14) Mg3P2 ________________________________________________________________________________ 15) NaF __________________________________________________________________________________ 16) Al2Se3 ________________________________________________________________________________ 17) NaBr _________________________________________________________________________________ 18) Zn3P2 ________________________________________________________________________________ 19) Cu2O _________________________________________________________________________________ 20) SnS2 __________________________________________________________________________________ 21) FeCl2___________________________________________________________________________________________________________________________ 22) Cr2O3__________________________________________________________________________________________________________________________