Three Kits for CMDITR Outreach Overview The demo kits are meant to provide support for quick, engaging classroom or public presentations. The initial kits contain materials for demo presentations not necessarily enough for full-class, hands-on activities. The presenter guide provides a flexible “script” explaining how to do the demos, what points to make and how to relate it to the CMDITR focus. Presenters use these as starting points or accents to their own unique presentation that is geared to the audience and venue. The table below maps the topics approximately to grades. Higher level demos might be appropriate as the “gee whiz” demos for earlier grades without getting into the conceptual explanation. At the same time a solar car could be an appropriate conversation piece when talking about a higher level topic. KIT Optics and lasers Elementary Topics Color mixingLight goes in straight line Middle/Public Topics Lenses/optics Reflection, refraction, absorption, luminescence High School Topics Polarization Diffractionwavelength Photovoltaics Solar car Rechargeable batteries Angle/area/ distance dependence Circuits – series and parallel Types of cells Total efficiency Voltage/current curves Raspberry Cell Color Absorption Internal reflection Sugar water bending light Tyndal effectattenuation Control light with polarization Interference Index of refraction Fiber networking Telecommunications Light carries information Optical fiber Water stream demo These kits were designed by the Center for Materials and Devices for Information Technology Research (CMDITR) an STC Program of the National Science Foundation No. DMR 0120967. http://STC-MDITR.ORG Education Standards Science classroom time is packed full and teachers have many specific educational objectives that are dictated by their districts and states. One key to being welcomed to the classroom is to relate your presentation to specific content they have to cover anyway. Even if your specific science is not covered you can switch the activity format to address general process skills such as observation, hypothesizing, designing an experiment and interpreting results. Careers and the connection between science, technology and society are also hooks that tie into must curricula. Overview Page 1 of 2 To learn what is taught at various grade levels check the National Science Education Standards, AAAS Project 2061 and the links to state Science below. http://www.nap.edu/openbook.php?record_id=4962&page=104 National Science Education Standards - Grade level Content http://www.project2061.org/publications/bsl/online/index.php?chapter=4 AAAS 2061 Benchmarks - The Physical Setting http://www.education-world.com/standards/state/toc/index.shtml Education World State Standards Links http://www.mcrel.org/compendium/SubjectTopics.asp?SubjectID=2 McREL Content Knowledge http://dev.nsta.org/ssc/ National Science Teachers Association- Science Scope and Coordination More Hands On Demos and Activity Ideas http://depts.washington.edu/cmditr/media/Educ_demo_suppliers.docx List of suppliers for education kit materials http://www.hands-on-optics.org/resources/ HANDS ON OPTICS- (from OSA, SPIE and NOA0 http://projectsol.aps.com/inside/inside_pv.asp APS Project Sol- Animation explains silicon solar solar cells http://www.solideas.com/solrcell/cellkit.html Solar Cell Kit-How to build your own solar cell http://spie.org/etop/2007/etop07k12V.pdf Innovative Methods to Teach Optics in the Grade 5- (including jello optics) http://www.exploratorium.edu/snacks/index.html Exploratorium - Snacks are simple demo ideas - this is the premier organization for hands-on demos and learning http://ice.chem.wisc.edu/Catalog/SciKits.htm#Anchor-Optical-13405 Institute for Chemical Education- Source for kits http://mrsec.wisc.edu/Edetc/nanolab/index.html Video labs in Nanotechnology from Univ. Wisconsin MRSEC http://www.optics.rochester.edu/workgroups/berger/EDay/EDay_Writeups.html Rochester Optics demonstrations for Eday http://www.osa.org/educationresources/youtheducation/classroommaterials/default.aspx OSA classroom materials including the Optics Suitcase Overview Page 2 of 2 Basic Light and Optics The purpose of this kit is to introduce students to the basic properties of light such as color, straight beams, reflection, refraction and polarization. Each of these phenomena can be presented in a “discovery” mode in which students related their current knowledge by guessing what will happen. At a higher level some of the phenomena can be explained with formulas and confirmed with measurements. Following each demo description are ideas of how to tie the demo into the CMDITR science. Key Concepts and Demos 1) Diffraction Grating White light is composed of many colors. Pass around the diffraction grating. There is a loose grating as well as one in the color filter paddle set. Have them describe what they see. Are the colors the same for any light you look at? The diffraction grating is able to split white light into colors that make it up. (The diffraction grating works because of constructive and destructive interference, but this is higher level concept.) Students may be able to notice that the colors difference between an incandescent bulb, and LED and fluorescent bulb shown below. Connect this idea to other sources of rainbows colors such as a rainbow (reflection and dispersion within a drop of water), oil sheen on water (interference between nanolayers), or prisms (transmission and dispersion). You could also use the equilateral prism of from the prism set to create a rainbow by refraction. Research Connection: Sunlight is composed of many colors. To be efficient solar cells need to be able to capture all colors. Organic LED light sources can be designed to provide specific colors. Basic Optics Kit Page 1 of 12 2) Additive Color Mixing When red, green and blue are added together they produce white. Turn on a white flashlight. Ask student what colors they see? Say yes to all colors that student answer. Pass out the color flashlights. These produce red, green and blue light. What happens when two or more colors of light are combined? By focusing all three colors to one point a white light is created. Research Connection: An RGB monitor has tiny red, green and blue dots. All colors including white can be made by mixing these three colors. CMDITR research with organic light emitting diodes has led to OLED displays which use thousands of red, green and blue lights to make all the points on the display. Basic Optics Kit Page 2 of 12 3) Color filters Light can be absorbed. Ask students what they know about color. a. Pass out colored filter samples and have students look at the room. Which color filter makes the light of a certain color go away? Colored filters absorb different colors and let other colors through. The deluxe filter paddle also has a polarizing filter and a diffraction grating. b. Ask which color paints are mixed together to make other colors. Is it possible to make white paint by mixing colored paints? (No this is because each color absorbs another part of the spectrum. If you added enough colors together eventually to would absorb all the light making black.) Have student pick three colors from the sample pack that when combined makes black or grey. If an organic solar cell appears red colored what does tell you about its absorption spectrum? The color of reflected light from a material represents the color of light that is not absorbed. c. Print out the “red reveal” hidden message sheets. Ask student to find a filter that reveals the hidden message. The red filter will mask all the colors that are similar to red in the picture. This leaves only the cyan layer that shows up as black because no light of this color can pass through the red filter. Research Connection: Solar panels are black because they absorb many colors. We are trying to design new materials that can capture solar energy and convert the energy to electricity. It would might pretty but it might not work as well as one that appears black. Why? Basic Optics Kit Page 3 of 12 Basic Optics Kit Page 4 of 12 4) Spectroscope The color of light can be described by wavelength. You may not notice it but every light has its own unique color. A spectroscope is an instrument that lets you measure all the colors present in a light source. a. Point the spectroscope at a fluorescent light and look through the hole on the end with the diffraction grating. Notice the green line that appears at the 5450 mark. Fluorescent bulbs are actually a little bit green. Some street lights are blue or even orange. This color depends on the chemistry of the materials used in the bulb. b. Now place a color filter #89 that only transmits color in the green part of the spectrum. Notice that the red line disappears from the fluorescent spectrum. Try using other filters to isolated different lines. What rule can you come up with about what color filters do to the full color spectrum of light? ( A color filter blocks all colors except for the color it appears to be. Similarly reflective colors absorb all light except for the color they can be observed to reflect) Research Connection: LEDs have distinct colors. Scientists and engineers are working to make LEDs that have light with the full spectrum of sunlight so colors look right. Other applications require LEDs with a very specific wavelength to match the material they must pass through such as plastic screens or fiber optics. Research Connection: We use instruments like the spectroscope to measure the light absorbed by chemicals we produce and to measure the light the color produce when they stimulated with lasers and electricity. Basic Optics Kit Page 5 of 12 5) UV sensitive beads Some portions of the electromagnetic spectrum are invisible. Point out the colors on the electromagnetic spectrum chart and show that some types of radiation are not visible. Pass out some UV beads. These are photochromic beads which change color in the presence of UV light but revert to white in the dark or in incandescent room light. Ask students if all light is visible. Have them place the beads in various places around the classroom under lights, in the dark and in the sun. Explain that UV light is invisible but very powerful and is the cause of sun burns. As an extension you could apply UV skin sunblock to a bead and see how effective it is in blocking UV rays. Research Connection: UV light is damaging to the body. It is also damaging to organic chemicals that we use in our solar cells. One of the challenges is to make design chemicals that do not break down in the presence of UV light. Basic Optics Kit Page 6 of 12 6) Glow Paper Some materials absorb light and then continue to emit it over time. Some colors of light do not have enough energy to excite these substances. a. Turn off the lights in the room. Expose the sheet to light for an instant. Point out that the sheet glows for an instant and then goes away. A phosphorescent material gives off light for a time after the light that excites it is turned off. b. Use the three colored flashlights, the white flashlight, daylight, colored filters, and the red laser to stimulate the glow-in-the dark paper. Red light should not be able to make it glow even though the laser pointer is very intense. Distinguish between the intensity of light which can be thought of photon flux or wave amplitude and the energy level of light which is dictated by the frequency or wavelength. This is because the chemical in the paper requires a minimum energy of light in order to excite its electrons to a higher energy level. Once the higher level is reached the energy slowly decays back to the ground state emitting light that is observed as glowing phosphorescence. Also notice that the phosphorescence is a slow phenomena. Research Connection: We attempt to design organic chemicals that are tuned to absorb in the range of light that is desired for a given purpose. Basic Optics Kit Page 7 of 12 7) Quantum Dots Solutions Materials can be made that designed that absorb and emit radiation at specific wavelengths. These vials contain extremely small 25nm particles of cadmium selenium that have been grown to specific sizes because of their light absorbing qualities. These particles exhibit fluorescence; they absorb light at one color and emit light at a different wavelength. In the visible spectrum they absorb and emit yellow and pale red. They absorb ultraviolet and fluoresce in green, red and orange. a. Examine the vials in regular light. Predict what color the vials will appear under UV light. b. Expose the vials to UV light Research Connection: It is possible to use quantum dots as a light antenna to absorb light and pass energy to another chemical. Some quantum dots for example could be used to trap infrared (IR ) light which would help solar cells work on cloudy days when IR passes through the clouds but visible light is mostly blocked. 8) Electroluminescent Panel Electricity can be used to excite a material and make it emit light. Electroluminescent panels have a transparent conductor layer, a layer of phosphor and a metal back electrode. When the front and back electrode are energized with a high frequency current the phosphor in between is stimulated and emits light. Research Connection: Electroluminescent panels are similar to the structure of Organic Light Emitting Diodes (OLEDs). Instead of a layer of phosphor the OLED contains an organic chemical that emits light after being excited with electricity. The organic chemicals can be tuned to get specific colors. OLEDs are now used for flat displays and televisions. 9) Laser pointer Basic Optics Kit Page 8 of 12 Light goes in a straight line until it interacts with matter. All light sources produce beams of light. Lighting usually produces many beams going many directions. a. A laser produces a very bright, focused beam. Use the laser show the path of a light beam. Laser light is used to guide rockets, in surveying or carpentry to line things up, or even to guide farm machinery. Place the laser along a flat surface such as the floor or table and show that it is not affected by gravity. b. Fill the plastic tub with water and add some powdered milk powder to make the light beam visible. A tub of clear gelatin can also be used for this demonstration. 10) Mirrors and lasers Light can be reflected. First ask what kinds of objects reflect light. Test the theories about what will reflect by pointing the laser at the objects that are suggested. They should be able to describe the quality of shiny, glassy or metallic being needed for mirrors. a. Place a mirror on edge on the table with a protractor in front of it. Place the cylinder lens end tip on the laser so that it produces flat line instead of a dot. Orient the line so it is vertical (with the cylindrical lens horizontal). This will make it easier to see the light ray and its reflection on the table. Use the protractor to measure the angle of light coming in (angle of incidence) and the angle of reflection. What is the rule for this? (the angle of incidence equals the angle of reflection) b. Challenge: what arrangement of mirrors would be needed to reflect a laser beam into a complete circle? Optical fiber has smooth surfaces and narrow diameter. Light reflects inside the tube until it emerges from the end. This is called total internal reflection. Research Connection: We do many experiments with lasers that pass through many lenses, filters and sensors on a special optics table. We move the laser beam around the table using mirrors and large optical fibers. Some lasers are so powerful they can burn a hole in wood if the beam is absorbed. Mirrors can reflect this light without getting hot at all. 11) Refraction with grow cubes and prisms Light can be refracted. a. One day before the demonstration place several of the optic grow cubes into water in a plastic bag. Each cube will expand into a 3 cm, optically clear cube. Use the single edge razor to cut the cube into various shapes used in optics. Alternatively cast a sheet of clear gelatin using three times as much gelatin as is Basic Optics Kit Page 9 of 12 called for on the recipe. Use the laser pointer to show how lenses and prisms work. Try making a convex lens, a concave lens, an equilateral prism, a fiber optic tube, a periscope with right angle prisms. b. Use the acrylic prism set to demonstrate various optics phenomena. If possible use two lasers to show parallel beams. The equilateral prism produces a rainbow in sunlight. c. Research Connection: We use lenses to focus light to a point for experiments, or to make a wide parallel beam. Prisms are used to separate light into the color spectrum and then isolate particular color bands in instruments such as the monochromator. Basic Optics Kit Page 10 of 12 12) Polarizing Filters Light waves can be random or polarized in one direction. Polarized materials only allow light with a certain orientation to pass through. a. Have two students hold the nylon rope and generate a wave in the crossways direction. Place two straight back chairs back to back on either side of the rope so that it’s horizontal movement is limited. The waves will be dampened. Ask the students to generate a wave in the up and down direction. This will pass through between the chairs. This how a polarized light is blocked or passed through a polarizing filter. b. Use the polarizing filters to show that light from a laser or from an LCD monitor can be almost completely blocked as the filter is rotated. Two filters can be used to block non polarized light. c. Clear materials such as plastics can change the polarity of light when they are under stress because their molecules get aligned in a certain way by forces. If you place a clear plastic spoon between two polarizing filters or between an LCD monitor (a polarized light source) and a polarizing filter you can see rainbow colored patches where light is being blocked or refracted in response to stresses in the material. Research Connection: Liquid crystal displays have a polarized light source. The liquid crystal chemicals can be rearranged when electricity is applied to change the way they polarize light and thus let certain light pass through under the red, green and blue cells. This property can be used to control light in fiber networks and computers. Research Connection: CMDITR is creating new organic materials that can change their polarization in an electric field or when light of specific wavelength is provided. Basic Optics Kit Page 11 of 12 13) Lasers and diffraction grating Lasers light is coherent and a precise wavelength. Place a diffraction grating in front of the laser pointer. There will be three dots, one for straight transmission and two diffracted dots on either side. Compare this to the pattern that appears from looking at a fluorescent bulb with a diffraction grating. Research Connection: Researchers pick lasers that have precisely the wavelength they need for their experiments. For example most optical fiber communications operate at 850nm or 1300 nm wavelength. 14) Advanced Laser experiments See experiments 6, 7, 8 of the laser kit Sources http://www.i-fiberoptics.com/laser-kits-projects-detail.php?id=2240 $51 Laser pointer education kit class II red laser pointer http://www.arborsci.com/detail.aspx?ID=1428 grow lens cubes (100s) $8 (clear gel to play with lens shapes) http://scientificsonline.com/product.asp_Q_pn_E_3053471 Acrylic prisms set $34 http://scientificsonline.com/product.asp?pn=3082363 UV beads $7.95 http://www.arborsci.com/detail.aspx?ID=894 Filter paddle samples 2 x $12 http://www.officedepot.com/catalog/vendorRouter.do?configurableItemType=NORWOO D&id=976090 White LED flashlights 3 x $5 http://www.arborsci.com/detail.aspx?ID=380 Fog in a can $16.95 http://www.arborsci.com/detail.aspx?ID=395 slide mounted polarizing filters( 50) $33 http://www.arborsci.com/detail.aspx?ID=37 6 gel color filter pack $12 http://www.arborsci.com/detail.aspx?ID=928 Phosphor Glow Paper $3.95 http://www.arborsci.com/detail.aspx?ID=319 Adventures in fiber optics kit $44. http://www.glowhut.com/a6-size-electroluminescent-light-with-9v-invert69.html EL light with inverter $29 Basic Optics Kit Page 12 of 12 Photovoltaics Photovoltaics (PV) or solar cells are one of the most promising sources for renewable electrical energy. The first generation cells were made from silicon crystals like those used computer semiconductor chips. These are efficient but very expensive. Silicon PV were first widely used where the cost of wiring to the grid was impractical such as in satellites or to power remote sensors along pipelines or railway tracks. Materials research and improved manufacturing techniques have brought the price down to where they are beginning to become practical for home energy systems. Plastic solar cells that use organic chemicals instead of silicon may be the next breakthrough. These demos show some basic devices and engage students in quantifying their performance and considering how basic science relates to engineering design. Key Concepts and Demos 1) Solar Car - Solar battery charger – (motor - LED) Solar energy can be converted to electrical energy using a solar cell. Demonstrate the solar car, the motor and rotor, and solar battery charger. Place the solar car in the full sun. What happens when the car passes into the shade? Demonstrate that the small silicon cell doesn’t generate enough energy to power the single LED but the larger amorphous silicon panel can power the light, even in indirect sunlight. Compare the solar electricity to power from a battery. See if they know about batteries polarity. Predict what would happen to the motor if you switch the leads to the solar cell. Reverse the polarity and the disc on the motor will rotate in the opposite direction. Research Connection: CMDITR is building a new kind of solar cell that uses an organic chemicals to trap light and then transfer electrons to conductive layers. Photovoltaics Kit Page 1 of 19 2) Types of solar cells. There are several kinds of solar cells which differ power, cost, durability, and preferred applications. Demonstrate the various types of solar cells in the kit by connecting them to a motor, voltmeter or LED. For ease of desktop display we have prepared self supporting mini-displays on which 1-3 cells can be mounted. The dangling clip leads can be connected to devices and configured in series or parallel circuits. a. Single crystal and poly crystalline silicon cell. The smaller cells in the kit are rated .45 volts and 400ma. Crystalline silicon solar cells (c-Si) can have efficiencies from 10-12%. They are produced from ingots of solid silicon and are rigid. These are the cells that most often used in space station where power density and durability are most important. b. Amorphous silicon battery charger. The panel is rated 7.2 volt / 200ma and has diode built into the circuit to prevent battery discharge into the panel when it is dark. Amorphous silicon is made by depositing an extremely thin layer of silicon on a conductive polymer. As a result the panel is flexible. (a-Si) Amorphous silicon has a comparatively low 6% efficiency because the silicon is poorly organized creating barriers to charge movement but it makes up for this with a lower cost and ease of manufacturing. c. Copper indium selenide (CIS) CIS and Copper indium gallium selenide cells (CIGS) have 14-20% efficiency. These cells must be full encapsulated to prevent release of toxic selenium. These cells have an open circuit voltage of 5 volts and a short circuit current of 95ma. Max power output is 3.9 volts at 64mA. d. Organic photovoltaics (OPV)- currently maximum is 56.5 %. The Konarka Power Plastic is one of the few commercially available OPV panel. The advantage of organic or plastic solar cells is that they have the potential of extremely low material and manufacturing cost and they are flexible. A disadvantage is that organic materials have a limited lifetime especially in full sun and exposed to water and oxygen. e. Dye Sensitized Solar Cell (DSS)Demonstrate the dye sensitized solar cell. Follow the separate directions to activate a titanium dioxide coated ITO slide to Photovoltaics Kit Page 2 of 19 form a Graetzel cell. Beginning with a pre-coated TiO2 / ITO slide, add berry juice to sensitize the TiO2. Lightly coat the other slide with the carbon soot from a candle. Pinch the slides together (carbon against TiO2) with the binder clips so that the slides are offset exposing the conductive ITO layer. Apply iodide solution as an electrolyte and then attach the alligator clips to the exposed edges of the f. Desktop Display – It’s convenient to mount the various demonstration cells on a display board so that the leads hang free and can be connected in a variety of ways. The output can be connected to a small motor with a rotating disc which is safe and impressive to kids. For indoor demonstrations a 100 watt equivalent fluorescent bulb (1700 lumens) in a clip on holder works well because it stays cool and is safe around kids. Several of these can be used for more intensity or they can be placed very close to the cells. g. Brainstorm what characteristics would be desirable for a solar cell. Some possibilities power, costs, durability, flexibility, safety, ease of producing, environmental safe and plentiful materials. Research Connection: CMDITR Engineers and scientists are trying to develop the next generation of solar cells using organic chemicals. The research connects includes theoretical modeling of organic systems, synthesis, prototyping and testing. Photovoltaics Kit Page 3 of 19 3) Series vs Parallel circuits Several cells can be connected in series or parallel to get desired power characteristics. a. Explain the difference between voltage and current. Show that the large panel produces a higher voltage (because it has several cell areas wired in series). Measure the voltage and current produced from each cell using the digital meter. The digital multimeter has a dial setting for measuring voltage and amperage also note that the red lead must be moved and the selector switch set to mA to get the ammeter mode. Each cell has a characteristic voltage. Silicon cells produce between .5 -.6 V oc *(volts open circuit), OPVs are usually around .4 Voc. b. Explain the difference between series and parallel circuits. Use the clip leads and the three small panels to demonstrate that in a series circuit the voltage is added. In a parallel circuit the voltage does not change but the current (amperage) is increased. + PV cell - + PV cell + PV cell - + voltmeter - Series + PV cell Parallel + PV cell + PV cell + voltmeter - c. Research Connection: The voltage of photovoltaic cells are determined by the bandgap of energy for the combination of chemicals or materials used. Even low voltage devices can be combined in series or parallel circuits to get the correct power for desired applications. Photovoltaics Kit Page 4 of 19 4) Measuring Power The power from a solar cell depends on the current and voltage. To measure the power record the voltage and amperage of a solar cell across a load. The ammeter has builtin precision resistors in its circuit. If you only had a voltmeter you could place a known resistor in the circuit and calculate current in amps as voltage divided by ohms. The peak power depends on specific load which affects the current and voltage. ( see voltage current graph below) For this activity you measure the voltage and current in a simple circuit without a load. Solar Cell A V P= V x I Power (watts) = Volts x Amps Sample calculation: Volts = .4 V Amp = 50ma= .05 amp Power = .02 Watts a. Compare the power for a 3 x 4 cm area for the crystalline solar cell compared to the same area of amorphous silicon cell. b. The amorphous panel provided is 7.2 V and 200 ma. How many of these panels would be needed to in what configuration to generate 100 Watts? c. Experiment with different sources of light, sunlight, or diffuse vs. direct light d. Experiment with the effect of temperature on cell power. Research Connection: CMDITR Engineers and scientists test their OPV cells in a similar manner by measuring voltage and current under different loads and light conditions to calculate the maximum efficiency. With a reliable way of comparing cells then it is possible to fine-tune the systems and methods to improve efficiency and longevity. Photovoltaics Kit Page 5 of 19 5) Power : area relationship The larger the cross sectional area of the light beam that is trapped, the greater the power generated. a. Cover portions of the panel to show decreasing current and voltage. Solar cells measured with the meter are under no load so you get the open circuit voltage (Voc). You should notice that the current responds quickly with decreasing light while the voltage stays somewhat stable, finally the voltage drops too. To measure the power from the panel you have to measure both voltage and amperage produced. b. Plot the power versus area for the amorphous silicon panel. Complete the table and graph from BLM 1- Power vs Area Experiment c. Repeat the measurement with a different pattern of shading (block the left, right top or bottom) You may get different results because of the wiring of cells within the array. Once a parallel section of panel is partially shaded it tends to knock out the whole section. Panels can also be equipped with bypass diodes which reroute current around underperforming cells. http://www.electroiq.com/index/display/article -display.articles.Photovoltaics-World.boscomponents.inverters.2009.03.shadehappens__installation.QP129867.dcmp=rss. page=1.html Research Connection: OPVs could be less expensive to manufacture so even if they are less efficient a larger area could be deployed. Photovoltaics Kit Page 6 of 19 BLM 1 Power versus Area Experiment Purpose Data Table Area Voltage Current Power Power Watts Data Analysis Exposed Area (cm2) Conclusions: Photovoltaics Kit Page 7 of 19 6) Power : distance relationship Energy from a radiant light source drops off with distance. As you move away from a diffuse light source the same amount of light is spread over a large area so the solar panel only intercepts part of the energy. This called the inverse square law. It relates I intensity with r the distance. If you use a focused light source up close this relationship will not hold. At the distance we are from the sun it does not make any measurable difference how close (for example sea level versus on mountain top) we place solar cells to the sun. There is some variation in power available from the sun as we as the Earth’s orbit reaches perihelion. Currently this occurs in January when the Earth is 5million km (3 million miles) closer to the sun. This results in about 7% more solar energy striking the earth at perihelion. Use the electric meter to measure the current produced by the sample silicon cell as you move away from a light source. Collect data and graph the experiment using BLM 2 – Power vs Distance Experiment Research Connection: When testing solar cells identical conditions need to be used. Typically a special “artificial sun” lamp with precise color balance and uniform power is used to simulate natural sunlight. Distance from the source must also be kept constant. Photovoltaics Kit Page 8 of 19 BLM 2 Power versus Distance Experiment Purpose Data Table Distance from Light Source Voltage Current Power Watts Data Analysis Exposed Area (cm2) Conclusions: Photovoltaics Kit Page 9 of 19 Power 7) Power : Incidence Angle relationship The angle with respect to the sun influences the energy output. Changing the angle has the effect of decreasing the cross section of light that is intercepted. You can see this by measuring the shadow of the panel as it is tilted. In addition low angle sun on the Earth must pass through more atmosphere so some energy is absorbed. This is described with the cosine law which relates I the insolation to S the incident solar energy (Watts/m2) and Z the Zenith angle of the surface with respect to the sun. I= S Cos Z a. Set up the solar panel on its inclined support with protractor. Change the angle of the solar panel and measure the current. Plot the current versus the angle. Complete the data and graph on BLM 3 Power vs Angle Experiment b. Use this information to create a bar chart showing the total power generated by a cell during the course of day if the cell were fixed on a roof with an angle of 30 degrees. The peak angle of the sun on the spring or autumn equinox is 90- your latitude. At mid summer it is 90 – latitude -23.45 degrees. At mid winter it is 90 – latitude + 23.45 degrees Research Connection: Engineers have designed tracking systems that keep PV panels facing perpendicular to sun all day long. Others have explored using concentrators or light guides to reflect light to a smaller area where the cell is. Photovoltaics Kit Page 10 of 19 BLM 3 Power versus Angle Experiment Purpose Data Table Angle Voltage Current Power Power Watts Data Analysis Angle with respect to light source- deg Conclusions: Photovoltaics Kit Page 11 of 19 8) Power vs Wavelength- Absorption Photovoltaics absorb light at specific wavelengths. The sunlight that reaches the Earth is spread over a larger spectrum. Some is visible and some stretches out into the infrared and is invisible. The irradiance at the Earth’s surface shows distinct dips at certain wavelengths due to absorption by atmospheric gases. Each kind of solar cell absorbs efficiently distinct wavelengths. Characterizing the absorption spectra is important. a. Use the red, green and blue filters to show that certain colors when filtered out reduce the power more than other colors. Refer to the transmission spectra accompanying each filter to find its wavelength in nm. b. Plot the current versus wavelength when different colors are placed in front of the solar cell. You can use the large filter sheets or the filter sample booklets. Be sure to pick filters with approximately the same optical density. Use the attached transmission spectra tabs to pick colors that represent an even array across the spectrum. Complete BLM 4 Power vs Wavelength Experiment c. Compare the amorphous silicon, the polycrystalline silicon cell, and the dye densitized solar cell. Research Connection: When we design chemicals to use in organic photovoltaics we measure the absorption spectra of the chromophores. Ideally we want dyes that absorb across the entire visible spectrum. Photovoltaics Kit Page 12 of 19 BLM 4 Power versus Wavelength Experiment Purpose Data Table Wavelength Voltage Current Power Watts Data Analysis Wavelength nm Conclusions: Photovoltaics Kit Page 13 of 19 Power 9) Measuring Efficiency Efficiency is a measure of how much of the available energy is captured by a cell. It is the amount of electricity produced divided by the amount shining on the solar cell. To measure efficiency we have to know how much light energy is hitting the cell and how much electricity it is producing. It’s difficult to measure the incident light. Direct sunlight is between 250 and 1,000 W/m2. . a. In full sunlight measure the power of your solar cell and calculate the efficiency. In this example the cell has an area of 2.4 x 10-3 m2 , measuring .6 Volts and .5 amps in full sun Pi = A * Ps = 2.4 x 10-3 * 1000 = 2.4 watts Po = V x I = 0.6 x 0.5 = 0.3 W e = Po/Pi = 0.3/2.4 = 0.12 = 12% b. Repeat this measurement for various cells. What difficulties do you notice in comparing the efficiencies of various cells? 10) PV Cost estimation Solar cells are still somewhat expensive. Several factors have to be considered in sizing a solar system. Calculate how much area is needed to power a house, how much would it cost? a. Solar cells currently run about $5-$9 per peak watt. b. A house might require 2kW peak power c. If the silicon cells are 15% efficient and the d. Incoming energy is 1000 W/m2 assume 5 hours (5 kWh/m2) per day of useful sunlight or use the “Photovoltaics Solar Resource” map from NREL to identify the available solar resource for your area. e. If you aren’t connected to the grid you will need batteries which cost $1 amp hour Research Connection: Materials and manufacturing process determines the cost. Organic photovoltaics have a potential of being low cost because they can be manufactured with roll printing methods. Further research is needed to get higher efficiency, better durability (through encapusulation and decreased photobleaching) New organic solar cells may be much cheaper in the future. Photovoltaics Kit Page 14 of 19 11) PV characterization Solar cells are characterized using a voltage- current curve. Researchers build test cells using different materials and techniques and then test them in a controlled way. A common test is to create a voltage current plot. The curve goes between the open circuit voltage (Voc) and the short circuit current Isc. If you measure the voltage of solar cell with no load that is the open circuit. The maximum voltage occurs when there is no resistance and no current. If you have an infinite resistance on the circuit there is no voltage but a maximum current. Somewhere between these extremes is the peak power , a combination of current times voltage which can be seen as the elbow on the voltage current curve. In this experiment a variable resistor is used obtain a series of voltage and current pairs. a. Place the test PV cell in the wood test holder. Place an ammeter and a volt meter at the two pegs labeled A and V. Gradually change the series load in the circuit by sliding the variable resistor. Adjust the load to get an even series of voltage readings such as every .1 volts and record the amps for each voltage. Plot the data. The goal is to get a curve that is closer to a right angle (with a minimum fill factor). There is a certain combination of voltage and current that delivers peak power. b. Complete BLM 5 Current vs voltage experiment Research Connection: CMDITR researchers do this same measurement with much finer control. Photovoltaics Kit Page 15 of 19 BLM 5 Current voltage J/V graph Experiment Purpose Data Table Voltage (V) Current(A) Power (A x V) Power mW Current mA Data Analysis Voltage V Conclusions: Jsc =______Voc= ______ Photovoltaics Kit Page 16 of 19 12) PV Characterization with Probeware Researchers usually use computers to collect and analyze PV performance data. The Pasco voltage/current probe connected to the USB link provides an easily visible display of solar cell performance. To set up the experiment follow these directions: 1) Set up a solar cell at a set distance from a light source or in full sun. Be sure to keep illumination constant through the measurements. 2) Connect the voltage probe to output of the solar cell using the black lead to the negative. 3) Connect the current probe to the output of the solar cell in series with a variable resistor. The resistor will be used to decrease the current from Jsc where there is maximum current but no voltage (since it is essentially a short circuit), to a maximum resistance Voc at which time there is no current flowing through the resistor but maximum voltage. Variable resistors will have to be carefully chosen 0-100, 0-500, 0-1000 are possibilities. 4) Open the DataStudio activity called JVcurve.ds. It will display a graph with amps on the y axis and volts on the x, and a dial display for current and voltage meters. The sampling option is set to “Manual Sampling” and “Keep data values only when commanded. On both meters and graph the appropriate range is 0-.1 amps for current and 0-.5 volts. Photovoltaics Kit Page 17 of 19 5) Click “Start” to begin viewing the current and voltage. The “Start” button turns to “Keep” with a red stop square to the right. Each time you click “Keep” a data point is added to the graph at the instantaneous current and voltage levels. This data set is known as a “run” and is noted in the data summary area on the left with a matching icon on the graph. (An alternative method is to set the sampling method to timed and then repeatedly change the potentiometer to fill in the curve. Since this is continually collecting x,y points it can result in a large number of redundant pairs but is more impressive as a dynamic display). 6) Adjust the variable resistor from 0 ohms to full resistance in series of steps. You’ll notice that as the resistance increase the voltage increases and the current decreases. Carefully adjust the variable resistor so that you get readings every .05 volts. 7) Click the red square to stop data collection. Click “start” to begin a new data set. 8) Repeat this measurement with different cell types, with different levels of illumination, and using different color filters. Links http://www.nrel.gov/learning/re_photovoltaics.html http://www.ccmr.cornell.edu/education/modules/documents/PhotovoltaicCells.pdf http://www.infinitepower.org/pdf/No19%2096-828B.pdf http://www.nrel.gov/midc/unlv/ live insolation data for Las Vegas http://en.wikipedia.org/wiki/Solar_cell http://www.powernaturally.org/Programs/SchoolPowerNaturally/InTheClassroom/kitlessons.asp ?i=9#Lesson14 Sources for kit materials http://shop.pitsco.com/store/detail.aspx?CategoryID=115&by=9&ID=2647&c=1&t=0&l=0 $8. 95 sunzoom lite car http://store.sundancesolar.com/subusobachki6.html 4 aa batter charger $39.95 http://store.sundancesolar.com/misorokitsus.html mini solar car $9.95 http://www.frys.com/product/5342528?site=sr:SEARCH:MAIN_RSLT_PG Electric Meter $26.95 http://scientificsonline.com/product.asp?pn=3039810 $5.95 each (3) http://scientificsonline.com/product.asp_Q_pn_E_3085037 $2.95 each CIS solar cell http://store.pasco.com/pascostore/showdetl.cfm?did=9&partnumber=PS-2100A&detail=1 Pasco PASPort USB link $59 http://store.pasco.com/pascostore/showdetl.cfm?&DID=9&PartNumber=PS2115&groupID=192&Detail=1 voltage/current probe $99 http://k8.vernier.com/products/interfaces/ Vernier Go!Link USB interface (alternative to Pasco version) Protractor Light Source for indoor use- quartz desk lamp Photovoltaics Kit Page 18 of 19 Color Filter pack for testing cells Rechargeable Batteries Cost $55- 250 Photovoltaics Kit Page 19 of 19 Telecommunications and Lasers Overview One of the major research thrusts of CMDITR is organic electronics that can be used in information technology and telecommunications. At the heart of this is the modulation of light using new organic electro-optical materials. Students need to understand how the system currently uses light and optics to carry information. Electro-optic materials can change their index of refraction in the presence of an electric field. This property combined with wave interference makes high speed switching possible. Finally, electro-optical and all optical switches can be miniaturized to the nano-scale to take advantage of other unique properties in device design. Key Concepts and Demos 1) Analog vs Digital Signals Information can be carried by modulating electrical signals either analog (continuously changing) or digital (discrete values- coded in timed pulses either on or off). Show or draw pictures of waveforms of analog and digital signals. 2) Light as a signal carrier Information can be carried by light. Bounce a laser off of mirror attached to a balloon stretched on a can. Tap the rubber membrane or speak into it. Brainstorm the advantages of using light as carrier for information? Research Connection: CMDITR is working on ways to modulate light by controlling the optical properties of the materials it passes through. This may lead to improved efficiency of switching light in communication systems. It also may lead to all-optical switching (AOS) in which light from one channel controls light in another channel. 3) Fiber optics explanation Optic fiber transmits light due to total internal reflection. Demonstrate light reflecting inside of plastic hose filled with water. Fill the plastic chamber with water and add a pinch of dry milk powder to reveal the light rays. Demonstrate the critical angle where there is total internal reflection. Place a wood plug in the hole in the plastic bottle and fill the bottle with water, place it on top of the plastic case. Position the laser in the support so that it points directly at the end of the plug. Place the larger plastic tub below the stream path. Turn on the laser and pull the plug. Use a white card to interrupt the stream and demonstrate that light is internally reflected in the stream. Telecommunications and Lasers Kit Page 1 of 6 The light fountain was first demonstrated by Daniel Colladon in 1842 Optical fibers have a variety of useful properties. Use the various materials in the Adventures in Fiber Optics kit to demonstrate cladded and uncladded cables, floures 4) Index of refraction demo Light is refracted and reflected when it encounters a material with a different index of refraction. Place a straw in the plastic tub with water (add a little milk to visualize laser) and observe that it appears to bend when placed at an angle. Repeat the demonstration this time with a laser pointed down from above. Index of refraction is the ratio of the speed of light in a vacuum over to that in the material. Air and water have very different indexes of refraction. 5) Comparing index of refraction of substances Various solids and liquids can have different indexes of refraction. Carefully pour a layer of 80% sugar solution or corn syrup into the bottom of the plastic container. Tell students that sugar water has index of refraction of 1.49 and pure water is 1.33. Repeat the refraction demo. The light should bend a second time when it reaches the sugar water layer. Another variation is to carefully mix a series of sugar solutions and layer them so the solution is progressively more dense. This will result in a smoothly bending straw or light beam. Research Connection: This property is used in optic fiber in which the core and cladding have different IOR. Some fibers use the graded index fiber with special glass or polymers with progressively higher IOR. This decreases the dispersion of light that is caused by light at different angles passing through the fiber at different speeds (modal dispersion). 6) Optic Fiber Network Demo Fiber optics are used to transmit signals over long distances for phone and computer networks, or short distances between computer servers where high speed connections are needed. This usually involves transferring from electrical to optical and back to electrical signals. The optical fiber communications demonstration kit includes a transmitter and a receiver. Apply the 5V power supply to the demonstration device. This demo shows one way communication. (for two way communication the system would have a receiver and transmitter at both ends). The transmitter has a simple oscillator that controls an LED at the point where the optical fiber enters the device. Light passes along Telecommunications and Lasers Kit Page 2 of 6 the fiber to the receiver where a photo detector senses the light and the circuitry coverts the light back into electricity at the Data output lines. Connect EN and EXT on the transmitter to the +5V positive terminal. An LED will flash on the Data lines on the receiver, proving that the signal has made it all the way back to electricity again. Disconnect the optical fiber from the receiver end and show that that the fiber end is flashing, the LED on the data will stop flashing when it stops getting its optical signal. As you bring the fiber back into the receiver the LED will begin flashing again. The circuit is controlled with the following logic on the transmitter side. 0 means the line is connected to the ground, 1 means it is connected to the +5V line. Mode EN 1 0 2 0 3 1 4 1 EXT 1 0 1 0 LED State ON OFF OSCILLATING OFF Research Connection:CMDITR researchers are concerned with various aspects of the optical network. An electro-optical switch can built using polymers. A key problem is switching speed. New organic molecules may be able to operate at higher speeds than current materials. Telecommunications and Lasers Kit Page 3 of 6 7) Polarizing Filter with Laser Telecommunications depend on the ability to turn light on and off quickly (modulation). Show how the polarizing filter can pass or block light from the laser pointer. 8) Michelson Interferometer Coherent light can be modulated by using interference of light waves. The MachZehnder (MZ) interferometer is a device used to modulate light. In the MZ device a light beam is divided into two paths and one path goes through some electro-optic material. Changing the electric field on the EO material changes its index of refraction. When the two paths converge again destructive interference cancel the output light creating a signal. A Mach-Zehnder device The Michelson Interferometer demonstrates this kind of interference with a more complicated path. One path of the split beam goes through the beam splitter, reflects off a mirror, then reflects off the back side of the image splitter and finally reflect off a second mirror before exiting the beam splitter along the original path. The two beams then pass through a diverging lens to spread the beam out into a wider area to reveal a series of bands or circles where there has been interference. This device is extremely sensitive to distance (for visible light it is 1/100th the thickness of human hair. This makes it sensitive to minute vibrations and minute changes in the index of refraction of material placed in the path. The Michelson Interferometer Light Path Follow the manufacturer’s instructions for arranging the pieces for the interferometer demo. Once you get a somewhat stable interference pattern then experiment with placing glass in the path. By turning the glass slightly you will alter its effective index of Telecommunications and Lasers Kit Page 4 of 6 refraction and cause a shift in the interference pattern. Similarly, when an electro-optical material is placed in the beam path it will alter the interference pattern. A variation on this setup can be used to measure the electro-optic coefficient of materials. Research Connection: CMDITR research is building materials that can be used in telecom and all optical switching. 9) New materials can be fashioned into extremely small nano-scale devices integrated right on to the chip. Show photos, discuss micro-electronic trends, fabrication and scale. Sources for Materials http://www.i-fiberoptics.com/laser-kits-projects-detail.php?id=2110 Michelson interferometer with pointer $109 http://www.i-fiberoptics.com/educational-detail.php?id=14200 Educational Communication Kit $18 includes fiber, LED photodetector http://i-fiberoptics.com/educational-detail.php?id=13700&cat=kits-projects Adventures in Fiber Optics Kit $42 Laser pointer $14 plastic tray, pop bottle, milk. Nanophotonics pictures Plastic tube with clear plastic ends Radioshack dpdt submini switch- 275-0407 $3 5V DC power supply- Cost $141- $300 Telecommunications and Lasers Kit Page 5 of 6 Links http://en.wikipedia.org/wiki/Interferometer http://depts.washington.edu/cmditr/mediawiki/index.php?title=Dispersion_and_Attenuation_Phe nomena http://depts.washington.edu/cmditr/mediawiki/index.php?title=Optical_Networks Telecommunications and Lasers Kit Page 6 of 6