CP Biology Name UNIT 2A: Basic Chemistry Chapter 2: The Chemistry of Life 2.1 – The Nature of Matter _KEY__ ____________ The Structure of an Atom Living things share a major fundamental similarity with nonliving matter. All matter is made up of atoms. *Atom: the basic unit of all matter Atoms are incredibly small in size, yet they themselves are made of even smaller subatomic particles called protons, neutrons and electrons. Protons and Neutrons have about the same mass but not the same electrical charge. Protons and neutrons are bound by strong forces which form the nucleus or center of the atom. The electron is a charged particle with 1/1840th the mass of a proton. The energy of their constant motion keeps them outside the nucleus, despite their attraction to the nucleus. Because atoms have equal numbers of electrons and protons, their positive and negative charges balance out and atoms themselves are electrically neutral. Complete the Chart Below: Subatomic Particle proton Electrical Charge +1 positive neutron 0 neutral electron -1 negative Location within atom nucleus nucleus Moving rapidly in energy levels (electron cloud) surrounding the nucleus Your personal notes, summary of the lesson, and/or questions that you may have: 1 A chemical Element is a pure substance that consists entirely of one type of atom. Element Name and Symbol 1) ___C____ is the symbol for Carbon 2) Na is the symbol for ___Sodium_______ More than 100 elements are known, but only about two dozen are commonly found in living organisms. Mass Number ________________________________________________ You may see a decimal number for the mass on the periodic The Periodic Table of Elements table because this is the average mass for the atoms of this (see picture of periodic table on the last page) element. Some atoms differ slightly in mass due to different number of neutrons. These are called isotopes and will be The Periodic Table of Elements is a reference tool we use to studied next year in Chemistry. For Biology class we will round gain information about different elements. Elements are this number to the nearest whole number. arranged in order by their atomic number. By using the periodic table we can determine 3 things: 1) Element Name and Symbol – a symbol is usually 1 or 2 letter abbreviation for the element’s name. 3) The mass of Oxygen is ___16 amu________ 4) The mass of Chlorine is ____35 amu________ Atomic Number 2) Mass Number – this is the sum of the protons and the neutrons in the nucleus. The electrons don’t count in the mass since their mass is next to nothing. 3) Atomic Number – the number of protons in the nucleus of an element. Important Biological Elements The five most abundant elements in living things are: 1. Hydrogen – 10% 2. Oxygen – 65% 3. Nitrogen – 4% 4. Carbon – 19% 5. Phosphorus – 1% 5) The atomic number of Hydrogen is ___1_______ 6) The atomic number of Sodium is ____11______ Protons and Electrons 7) Carbon has __6___ protons and __6___ electrons. 8) Lithium has __3___ protons and __3___ electrons. Label the Important Biological Elements Your personal notes, summary of the lesson, and/or questions that you may have: 2 1 Chemical Compounds In nature, it is common to find elements combined with other elements in compounds. *Compounds: a substance formed by the chemical combination of two or more elements in definite proportions. *Coefficient: tells how many molecules of that substance (the large number BEFORE the formula) *Subscript: goes with the element symbol preceding the number; tells how many atoms of that element within one molecule of the substance (small number WITHIN the formula. The physical and chemical properties of a compound are usually very different from those of the original elements from which it is formed. We show the composition of chemical compounds by a kind of shorthand known as a chemical formula. Example 1: What is the chemical formula for water which contains two hydrogen atoms and one oxygen atom? __H2O___ Example 2: 6CO2 What is the coefficient? __6_____ What is carbon’s subscript? __1______ What is oxygen’s subscript? ___2_____ How many molecules of this compound are represented by this formula? __6_______ e) How many atoms TOTAL are present in this molecule? ___18______ a) b) c) d) Use the following information on chemical names and chemical formulas to fill in the chart below: Example : NaCl (Table Salt) NaCl is formed from one atom of sodium a highly reactive, soft, silver-colored metal AND one atom of chlorine a poisonous yellow-green gas. Chemical formulas tell us: a) They types of elements (atoms) that are present in the compound. b) The number of atoms of each element present in the compound. Carbon – 1 Hydrogen - 4 Hydrogen – 2 Oxygen - 1 Carbon - 1 Oxygen - 2 Nitrogen - 1 Hydrogen - 3 Your personal notes, summary of the lesson, and/or questions that you may have: 3 1 Chemical Bonds The atoms in compounds are held together by various types of chemical bonds. Bond formation involves the electrons that surround each atomic nucleus. *Valence Electrons: the electrons in an atom that are available to form bonds (these are unpaired electrons which are found in the outermost energy level of the atom’s electron cloud). *Octet Rule: the outermost energy level of most atoms will be complete when containing 8 electrons. Atoms will tend to gain, lose, or share electrons to achieve stability by having a full outer energy level (stable octet). ~ Do you think Carbon, Oxygen, Nitrogen and Hydrogen are reactive (unstable) atoms? Explain. Yes, in each case, there is a vacancy in the outer energy level. H has one vacancy in the 1st energy level. O has 2 vacancies in the 2nd energy level. Nitrogen has 3 vacancies and Carbon has 4. ~ What can reactive /unstable atoms do to become nonreactive /stable? (Recall that a stable atom has a fully filled outer energy level.) Exception: for hydrogen, the Duet rule applies (only 2 electrons are needed in the valence level) They can interact with other atoms by gaining, losing or sharing electrons to complete the atom’s valence energy level. The main type of bond that we will study in the unit is the covalent bond. Only reactive atoms are able to form bonds. The reactivity of an atom depends upon the arrangement of electrons in its outmost (or valence) energy level. Your personal notes, summary of the lesson, and/or questions that you may have: 4 1 *Covalent Bonds Formed when nonmetal atoms bond with each other A bond in which moving electrons actually travel about the nuclei of two atoms (at the same time) Electrons are shared between two atoms Example 1: Water (H2O) Example 2: Methane (CH4) Single Covalent Bond: atoms share 2 electrons (1 pair) Double Covalent Bond: atoms share 4 electrons (2 pairs) Triple Covalent Bond: atoms share 6 electrons (3 pairs) *Molecule: the structure that results when atoms are joined together by covalent bonds. The smallest unit of most compounds. NOTE: Bonds between the biologically important atoms H, O, N, C, & P (all non-metals) will be covalent. Hydrogen will only form Covalent Bonds!! H O N C 1 2 3 4 Molecules can also be represented by Structural Formulas: a drawing that shows the arrangement of atoms in a molecule Structural Formulas tell you: a) the types of elements in the molecule b) the number of atoms of each element AND c) the arrangement of atoms and location of covalent bonds. Shows the two dimensional shape of the molecule. Your personal notes, summary of the lesson, and/or questions that you may have: 5 1 NOTE: Structural formulas usually represent covalent bonding so they are used for molecules like H2O, but not for formula units like NaCl. In a structural formula, each line between atoms represent a position in which electrons are shared. Therefore, a line represents a single covalent bond. 2) Ammonia or NH3 __1___ atoms of Nitrogen in the molecule __3___ atoms of Hydrogen in the molecule 1) Hydrochloric Acid (Hydrogen Chloride) or HCl H ___1__ atoms of Hydrogen in the molecule ___1__ atoms of Chlorine in the molecule N–H H H - Cl 3) Oxygen gas or O2 4) Carbon Dioxide or CO2 ___2__ atoms of Oxygen in the molecule __1___ atoms of Carbon in the molecule __2___ atoms of Oxygen in the molecule O = O O = C = O Your personal notes, summary of the lesson, and/or questions that you may have: 6 1 2.4 Chemical Reactions Note: We will not be discussing Enzymes in this unit. The numbers and types of atoms in the __reactants___ = The numbers and types of atoms in the __products___ *Chemical Reactions: process that changes or transforms one set of chemicals into another set of chemicals. Involves changes to the chemical bonds that join atoms in compounds. Bonds of the reactants are broken and new bonds form in the products. *Reactants: elements or compounds that enter into a chemical reaction *Products: elements or compounds produced by a chemical reaction HINT: Reactants react to produce products! Use the chemical formulas below to determine how many atoms of each element make up each compound. A coefficient indicates the number of molecules present. (coefficient X subscript = the number of atoms) *Chemical Equations: a mathematical representation of a chemical reaction. It shows the numbers and types of compounds involved. *The Law of Conservation of Matter: matter (atoms and elements) in a chemical reaction cannot be created nor destroyed. Only the arrangement of the atoms is changed, NOT the number or types. Your personal notes, summary of the lesson, and/or questions that you may have: 7 1 Consider the following chemical equation for cellular respiration: In the diagram below, fill in the terms “products” or “reactants” in the proper blanks. 6O2 + C6H12O6 Reactants C – 6, H – 12, O – 18 6CO2 + 6H2O Products C – 6, H – 12, O – 18 Your personal notes, summary of the lesson, and/or questions that you may have: 8 1