Gas Law Review Problems immHg L iTorr L ikPa L iatm R = 62.36 Lmol = 62.36 = 8.314 = 0.0821 iK mol iK mol iK mol iK 1. What is the volume occupied by 0.128 mol of He gas at a pressure of 0.97 atm and 325 K? 2. If the volume of a container of gas doubles in volume while the temperature stays constant what changes? (Be specific regarding magnitude) 3. A gas mixture contains each of the following gases at the indicated partial pressures: N2 = 315 torr; O2 = 124 torr; and He, 219 torr. What is the total pressure of the mixture and how many moles of oxygen would be present in a 2.15 L sample of this mixture at 25.0°C? 4. Determine the final pressure of 12.5 L container of CO2 initially at 1.35 atm that is compressed down to 10.3 L. 5. What is the pressure, in atm, within a 15.0 L cylinder filled with 0.448 mol of N2 gas at a temperature of 305 K? 6. If half the moles of gas are removed from an elastic balloon what happens to the balloon? 7. A gas mixture contains 1.25 mol of N2, 0.85 mol of O2 in a 1.55 L container at 18°C. Calculate the total pressure of the gas in atm. 8. A heliox deep-sea diving mixture contains 10.0 g of O2 (MM = 31.998 g/mol) to every 90.0 g of He (MM = 4.0026 g/mol) at 16°C. If the pressure within the mixture is 8.54 atm calculate the volume. 9. If the temperature within a rigid container is doubled, what changes? 10. Gas from a 3.5 L tank at STP must reach what temperature, in °C, in order to reach 2.5 atm within a 3.0 L tank? 11. How many moles of Ne gas will occupy a 250.0 mL chamber with a pressure of 125 kPa at 25°C? 12. Calculate the moles of H2 present in a 11.2 L chamber of gas at STP if the partial pressure of O2 within is 0.45 atm and while H2 gas makes up the remainder. 13. A 3.50 L tank of O2 at 1.25 atm is mixed with a 2.75 L tank of H2 at 1.50 atm. Determine the pressure of the entire 6.25 L tank once the gases are combined if all tanks are at 23°C. 14. Now see if you can solve number 13 using a derived gas law. (Challenge) 15. If you blow on your hand with your mouth wide the air feels ________________, but if you narrow your lips and blow on your hand the air feels_______________. Why? 16. A 1.0 L balloon of argon gas and a 2.2 L balloon of Cl2 gas both at STP are compressed into a 1.5 L container. Determine the final pressure in the container if the temperature remains constant. Gas Law Review Solutions 1. What is the volume occupied by 0.128 mol of He gas at a pressure of 0.97 atm and 325 K? (0.97) V = (0.128) (0.0821) (325) V = 3.5 L 2. If the volume of a container of gas doubles in volume while the temperature stays constant what changes? (Be specific regarding magnitude) The pressure inside will be half the original 3. A gas mixture contains each of the following gases at the indicated partial pressures: N2 = 315 torr; O2 = 124 torr; and He, 219 torr. What is the total pressure of the mixture and how many moles of oxygen would be present in a 2.15 L sample of this mixture at 25.0°C? 315 + 124 + 219 = 658 torr = PT (124) (2.15) = n (62.36) (298) nO2 = 0.0143 moles 4. Determine the final pressure of 12.5 L container of CO2 initially at 1.35 atm that is compressed down to 10.3 L. P1V1 = P2V2 (1.35) (12.5) = P2 (10.3) P2 = 1.64 atm 5. What is the pressure, in atm, within a 15.0 L cylinder filled with 0.448 mol of N2 gas at a temperature of 305 K? P (15.0) = (0.448) (0.0821) (305) P = 0.748 atm 6. If half the moles of gas are removed from an elastic balloon what happens to the balloon? It will shrink to half the size 7. A gas mixture contains 1.25 mol of N2, 0.85 mol of O2 in a 1.55 L container at 18°C. Calculate the total pressure of the gas in atm. 1.25 + 0.85 = 2.10 moles of gas total P (1.55) = 2.10 (0.0821) (291) PT = 32.4 atm 8. A heliox deep-sea diving mixture contains 10.0 g of O2 (MM = 31.998 g/mol) to every 90.0 g of He (MM = 4.0026 g/mol) at 16°C. If the pressure within the mixture is 8.54 atm calculate the volume. 10.0 / 31.990 = 0.313 mol O2 90.0 / 4.0026 = 22.5 mol He 0.313 + 22.5 = 23.4 total moles (8.45) V = (22.8) (0.0821) (289) V = 64.0 L 9. If the temperature within a rigid container is doubled, what changes? The pressure doubles 10. Gas from a 3.5 L tank at STP must reach what temperature, in °C, in order to reach 2.5 atm within a 3.0 L tank? P1V1 P2V2 (1.0)(3.5) (2.5)(3.0) 585 K 312°C = = T1 T2 (273) T2 11. How many moles of Ne gas will occupy a 250.0 mL chamber with a pressure of 125 kPa at 25°C? (125) (0.25000) = n (8.314) (298) n = 0.0126 moles of Ne 12. Calculate the moles of H2 present in a 11.2 L chamber of gas at STP if the partial pressure of O2 within is 0.45 atm and while H2 gas makes up the remainder. 1.0 – 0.45 = 0.55 atm = PH2 (0.55) (11.2) = n (0.0821) (273) nH2 = 0.27 moles 13. A 3.50 L tank of O2 at 1.25 atm is mixed with a 2.75 L tank of H2 at 1.50 atm. Determine the pressure of the entire 6.25 L tank once the gases are combined if all tanks are at 23°C. Tank O2 (1.25) (3.50) = n (0.0821) (296) nO2 = 0.180 mol O2 Tank H2 (1.50) (2.75) = n (0.0821) (296) nO2 = 0.170 mol H2 0.18 + 0.17 = 0.35 moles gas in the final tank P(6.25) = (0.35) (0.0821) (296) P = 1.36 atm 14. Now see if you can solve number 13 using a derived gas law. (Challenge) P1V1 = P2V2 (1.25) (3.5) = P (6.25) = PO2 = 0.70 atm (1.50) (2.75) = P(6.25) = PH2 = 0.66 atm 0.70 + 0.66 = 1.36 atm = PT 15. If you blow on your hand with your mouth wide the air feels ________________, but if you narrow your lips and blow on your hand the air feels_______________. Why? Will discuss 16. A 1.0 L balloon of argon gas and a 2.2 L balloon of Cl2 gas both at STP are compressed into a 1.5 L container. Determine the final pressure in the container if the temperature remains constant. Tank Ar (1.00) (1.0) = n (0.0821) (273) nAr = 0.045 mol Ar Tank Cl2 (1.00) (2.2) = n (0.0821) (273) nCl2 = 0.098 mol Cl2 0.045 + 0.067 = 0.143 moles gas in the final tank P(1.5) = (0.143) (0.0821) (273) P = 2.1 atm Or P1V1 = P2V2 (1.0)(1.0) = PAr (1.5) PAr = 0.67 atm (1.0) (2.2) = PCl2 (1.5) PCl2 = 1.5 atm 0.67 + 1.5 = 2.1 atm = PT