Unit B –Chapter 2 – Review #1 B-1 1. Polar Covalent (electron sharing) bonds form. The Oxygen “hogs” the electron pairs, while Hydrogen misses out. 2. A Hydrogen bond – It is a very weak bond but it creates many of the unique properties of H2O. 3. The Covalent bond is much stronger than the Hydrogen bond. 4. The Oxygen atom in a water molecule takes on a partly negative field due to the fact that it hogs the two electron pairs (it is more electronegative) it is supposed to evenly share. 5. A polar molecule is any molecule that has a region that has a bit of a positive charge and a region that has a bit of a negative charge. 6. A Hydrogen bond forms between a Hydrogen on a molecule that is a bit positive and some other part of a molecule that has a bit more negativity to it. 7. Ionic bonds form between a metal and a nonmetal, the metal donates valence electrons while the non-metal accepts those electrons. So the metal becomes a positive ion and the non-metal becomes a negative ion, then the two are drawn together. Covalent bonds form between a non-metal and another non-metal, this bond requires the two atoms to share a pair/pairs of electrons to meet the Octet rule. The electron pairs spend time orbiting both atoms. B-2 1. 2. "Universal Solvent". Other polar molecules and Ionic compounds are easily dissolved in Water. 3. The watery portion of blood is important for a number of reasons: - dissolving key solutes (nutrients and wastes) for transport. – Water’s high Specific Heat Capacity, helps the body with Thermoregulation. 4. Water is less dense in its solid form, so ice floats. Also water is transparent to let light through the vertical column for aquatic producers to photosynthesize. 5. Water has a high S.H.C., because of the cohesive property of water. When you add heat (kinetic energy) to water, the molecules resist picking up their kinetic energy because they try to stick together because of H-bonding between the water molecules. 6. A high SHC, allows water to resist temperature change. Bodies of water (organisms as well as ponds, lakes oceans etc) resist drastic temperature change. Organisms perspiring cools the body by running a phase change. Liquid to gas – requires lots of energy to be absorbed. 7. During metabolic reactions heat is always given off. This heat is moderately absorbed into tissue fluids and blood and the heat is carried out to the skin. 8. Water is unique in that when it solidifies the molecules spread out during crystallization. This makes the substance less dense as a solid. So ice forms at the top of liquid water. 9. Ice forms at the top of a body of water. If ice was more dense than liquid, it would form at the bottom of bodies of water and over many years all bodies of water would eventually freeze up solid. 10. Cohesive means that the molecules want to stick to each other. They are drawn to each other because of H-Bonding between the different waters. This cohesive property of water helps with transportation, as energy is put into moving some water it will efficiently pull on the rest of the water. B-3 1. When acids dissolve in H2O, H+ ions are released. It is these reactive hydrogen ions that give acids their corrosive properties. 2. When bases dissolve in water, OH- ions are released. It is these reactive hydroxide ions that give a base its corrosive power. 3. A BUFFER. 4. Acids range from 0 – 6.9 or so on the pH scale. Examples: stomach acid diluted pH =2.5, Lemon Juice pH = 2.0, Coca Cola/Vinegar pH = 3. 5. A pH of 7.0 is NEUTRAL. Distilled water and tears. This means that there are 10-7 moles of H+ ions and an equal 10-7 moles of OH- ions. A perfect balance. 6. It is a 10 X increase or decrease. For example pH = 5 10-5 = .00001 moles of H+ while a pH of 4 10-4 =.0001 moles of H+ ions. 7. (10). A pH of 6 has 1000 X more H+ ions than a substance with a pH of 9. 9 8 7 6 X10 X10 X10 = 1000 8. Bicarbonate ions (HCO3-) can pick up H+ ions when the pH drops and then form Carbonic acid H2CO3, This carbonic acid can go to the lungs and be broken down into H2O and CO2. Which are then exhaled. But in this case we want to keep the Carbonic acid in the blood and let it dissociate into Bicarbonate ions (HCO3-) and H+ ions. These free H+ ions will combine with all those extra Hydroxide (OH-) ions to form H2O. Multiple Choice 1. D 2. A 3. A 4. B 5. C 6. C 7. D