A112 Paper #2060 ELECTRIFIED NANOFILTERS: THE FUTURE OF CLEAN WATER Shafa Suddle (sns44@pitt.edu), Daniel Blemler (dcb35@pitt.edu) Abstract— Although one of the most precious necessities of life is access to clean drinking water, various countries throughout the world do not have ready amounts available. However, many of these locations have access to surface and groundwater, which, with modern technology, can be purified and consumed as drinking water. There are several different techniques that engineers have started to experiment with in order to obtain clean water—one of which happens to be the use of nanotechnology in water treatment. This paper will investigate and evaluate nanotechnology in water treatment, specifically, the new methods within nanofiltration. The engineering and technologies behind electrified nanofilters will be analyzed and discussed. The importance of innovation within nanofilters will be assessed, and the significance of current research and development in electrified nanofilters will be addressed. Additionally, the significance of ethical issues involved with nanofiltration will be considered. The invention of electrified nanofilters is especially important to civil and environmental engineers since creating accessible water is something that they strive to achieve. Clean water is a necessity of life and with technological advances like this, water will continue to become more accessible to people all over the world. Nonetheless, with these innovations, engineers must be held accountable for their nanofilter products. Abiding by a strict code of ethics is a must as they lay the frame work for proper procedures during manufacturing. Holding engineers to these standards will help to ensure the water produced for human consumption is pure and therefore safe for use. With the use of these methods, nanofiltration, and in particular electrified nanofilters can revolutionize nanotechnology in water filtration for the future. TYPES OF NANOTECHNOLOGY There are many different techniques that engineers have started to experiment with in order to obtain clean water— one of which happens to be the use of nanotechnology in water treatment. Nanotechnology, the engineering of matter at the nanoscale (1-100 nanometers), has been identified as a technology that could greatly reduce the problems associated with water purification and quality. This technology is used for the “treatment of surface water, groundwater, and wastewater contaminated by toxic metal ions, organic and inorganic solutes, and microorganisms” [1]. Within nanotechnology, nanoscopic materials such as carbon nanotubes and alumina fibers are used in the nanofiltration of water. A team of researchers from D.J. Sanghvi College of Engineering, in Mumbai, India, stated that “the main advantages of using nanofilters, as opposed to conventional systems, are that less pressure is required to pass water across the filter, they are more efficient, they have incredibly large surface areas and can be more easily cleaned by back-flushing compared with conventional methods” [2]. With these advantages, nanofiltration is worth the attention of engineers, as it seems to be a possible answer to the challenge of providing adequate amounts of inexpensive, clean water for the world’s increasing population. Key Words—Efficiency, Electricity, Electrified Nanofilters, Ethics, Nanowires, Water Filtration PRESENTING NANOFILTERS Due to its significance, clean water is something that every human should have access to. Unfortunately, there are many places throughout the world that do not have adequate amounts of clean water or means to purifying water. Creating new technology within water filtration is extremely important as it would provide access to quality water for those with inadequate amounts. Engineers must figure out a way to distribute clean water in a more cost and time efficient method and it seems as if the invention of nanofilters has done exactly that. Through further development of carbon nanotubes and alumina fiber filters, nanofiltration could be the leading method in water purification. If a procedure is developed to distribute these methods on a large scale, they could help solve the problem of providing enough clean water for the world’s population. Furthermore, electrified nanofilters purify water faster and do it in a more efficient and inexpensive method by using less electricity and inexpensive materials such as cloth and silver. Similar to carbon nanotubes and alumina fiber filters, if this method can be industrialized, it could be the leading way to efficiently provide purified water throughout the world. University of Pittsburgh Swanson School of Engineering TYPES OF NANOFILTRATION: CARBON NANOTUBES Carbon nanotube filters, consisting of “hollow cylinders with radially aligned carbon nanotube walls,” have been proven to remove bacterial pathogens from contaminated water [1]. These nanotubes are produced using thermal processes which strip carbon atoms from carbon-bearing materials and then form a hexagonal network of carbon atoms that are rolled up into a cylinder [3]. March 1, 2012 1 Shafa Suddle Daniel Blemler FIGURE 1 Computer simulation of carbon nanotubes [3] Additionally, these nanotubes are reusable and can be cleaned; two properties that are vital in cost-effectively providing clean water. Furthermore, carbon nanotubes have shown to have an equal or faster flow rate compared to filters with larger pores which adds to their effectiveness [2]. If these filters are able to be produced for commercial use, they could be part of the solution in providing adequate, quality water across the globe. FIGURE 2 Aluminum Oxide Hydroxide (AlOOH) Fiber [5] HOW CARBON NANOFILTERS ARE USED FOR TREATING WATER These nanofibers, which have been incorporated into cartridge filters, are capable of absorbing various contaminants and have extremely high surface areas which “allow for potential absorption of significant amounts of contaminants” [5]. Similar to carbon nanotubes, alumina fiber nanofilters also allow a high flow rate with a low pressure drop compared to reverse osmosis and ultrafiltration. With continued research and development, these filters could also be constructed for widespread use in water purification. Researchers believe that carbon nanotubes could provide a strong advantage over current technologies such as reverse osmosis and ultrafiltration because water molecules would be allowed to pass through the filters while contaminants would not. This filtration process, called size exclusion, would directly correlate to the increased flow rate and decreased energy requirement of carbon nanotubes compared to current water purification techniques. One manufacturer has a carbon nanotube that, while not at the full potential researchers believe this method can achieve, is undoubtedly a step forward in nanofiltration [3]. If this method is able to reach its predicted full potential, the previous, less-efficient methods would become obsolete while quality water would be more accessible to people around the world. THE BEST SOLUTION: ELECTRIFIED NANOFILTERS While the nanofilter technologies previously discussed are certainly helping to provide access to clean water, a new innovation seems to be the best solution. A team of researchers at Stanford University has invented an electrified nanofilter, which, instead of physically trapping bacteria like the carbon nanotubes and alumina fibers, pathogens are allowed to pass through where they are then destroyed by an electric field. This new method is not only 80,000 times faster than any other existing filter, but it is also inexpensive, as it uses very little power to operate [6]. The fact that it is even cheaper and faster than other filters makes it seem like the best solution and potentially the future method to purifying water. TYPES OF NANOFILTRATION: ALUMINA FIBERS In addition to carbon nanotubes, alumina fiber filters are a type of nanofiltration technique that “remove bacteria, viruses as well as organic and inorganic colloids, much faster than conventional filters would do” [4]. An Orlandobased company, Argonide Nanomaterial’s, makes a filter that is able to retain 99.9999+% of viruses at flow rates several hundred times greater than more porous membranes [4]. Through continued research and making these particular filters more obtainable, water purification could moreefficiently be achieved. THE CREATION OF ELECTRIFIED NANOFILTERS Discovered by researchers at Stanford University, electrified nanofilters are created by using a relatively simple method. To create electrified nanofilters, scientists first take a plain cotton fabric and dip it into a solution of carbon nanotubes. They let this fabric dry and then repeat this process, but instead of dipping it into carbon nanotubes, they dip it into a silver and nanowire solution. However, these researchers have also discovered that mixing the carbon nanotubes with the silver nanowires and then dipping the fabric into this mixture is just as effective [6]. After mixing the cloth with the nano-substances, the cotton is let to soak for twenty HOW ALUMINA FIBER NANOFILTERS ARE USED FOR TREATING WATER Alumina nanofibers are very small fibers made from aluminum metal or aluminum containing materials, ranging in size from 1-100 nanometers in diameter and several micrometers in length. 2 Shafa Suddle Daniel Blemler water exceeds 105 V/cm, the electricity is able to break down cell membranes in a process called electroporation [7]. Electroporation is when a cell membrane is subject to an increase of electrical conductivity by an external source. If enough electricity is used, the cell can be destroyed. Secondly, electrified nanofilters are made of silver nanotubes (Ag NW). Silver is known for killing bacteria; thus, if any bacteria are able to get past the electricity, the silver will destroy it. This second filter acts as a back-up to the first while increasing the effectiveness of the overall system. Finally, there is also the possibility that changes in pH have been able to purify the water. During the filtration process, the maximum intensity on the surface of the nanowires is increased to 100 kV/cm. Due to the large amounts of voltage, the pH on the surface of the wires can be significantly altered; so much in fact that the pH can drop to a level as low as 3 [7]. This dramatic change in the pH may also impact the percent of bacteria inactivated. With the use of these three filters, electrified nanofilters can purify the water effectively and efficiently. minutes until it has dried. Multiple layers of this fabric are needed to make the filter powerful enough to successfully purify water, but once the fabrics have become approximately 2.5 inches thick, they are shaped into a cylindrical filter and placed into a glass funnel [6]. Water is then poured into this filter at a rate of 1liter per hour while a voltage of -+ 20 volts is applied to it. This process must then be repeated three times in order to produce a filter which destroys 98% of bacteria [7]. FIGURE 3 This image demonstrates how live cells are pumped into the filter and are electrified or killed by the Ag NW’s--by the time the bacteria comes out, it is dead [8]. Nanomaterials are a big advantage in the creation of nanofilters due to their incredibly small size. Nanomaterials, such as nanowires, range from 40 to 100 billionths of a meter which make them easy to stick into cotton [7]. These materials, due to their strong bonding with the fabric, create smooth surfaces on the cotton fibers and in turn create a more conductible surface for the electricity. The longer nanowires have their own responsibility in these filters—one of the ends is attached to the nanotubes while the other end branches off into the space between the cotton fibers [6]. This branching is useful because it allows the electricity to go through the fabric which makes the process much more efficient. Dr. Yi Cui, Professor of Materials Science and Engineering at Stanford University and one of the Stanford researchers who helped create this invention, stated that, “with a continuous structure along the length, you can move the electrons very efficiently and really make the filter very conducting” [6]. The more efficient and conductive this invention is, the more effective it becomes as a water purification technique. FIGURE 4 A scanning electron microscope image of silver nanowires and cotton during the process of constructing the filter. The large fibers are the cotton [6]. EFFECTIVE AND EFFICIENT With all new technology, efficiency is an important factor— if new technology lacks efficiency, than its use in the world drastically decreases. With this in mind, researchers at Stanford University have strived to make electrified nanofilters efficient and they have been successful in several ways. Traditionally, nanofilters have several problems that have prevented them from being as efficient as possible. One of these problems is that in order for nanofilters to purify water, the pores used to filter the bacteria must be extremely small. This was not originally considered to be a problem because the smaller the pores, the more effective the filter becomes at preventing bacteria from entering the filter. However, the problem with this method is that having such small pores severely restricts the filter’s flow rate [6]. It also THE THREE STEP FILTER PROCESS There are three different filters that electrified nanofilters are made with. Firstly, since the electricity applied to the 3 Shafa Suddle Daniel Blemler becomes much easier to clog and the filters must therefore be frequently replaced. With the discovery of electrified nanofilters, these problems have been overcome. Firstly, electrified nanofilters’ method of purification is by flowing water through the filter and then electrifying it after it has passed through [6]. Electrified nanofilters are much more efficient than traditional nanofilters because they do not purify the water by keeping the bacteria from entering the filter altogether. Instead, these filters kill the bacteria by “zapping” it with electricity once inside. The pore size does not need to be as small or restrictive with this process, allowing electrified nanofilters to have large pores and a drastically increased flow rate. Dr. Yi Cui stated that, “our filter is about 80,000 times faster than filters that trap bacteria” [6]. By increasing the flow rate, these filters improve the efficiency of the purification process. THE ADVANTAGES OF SILVER IN NANOFILTERS The efficiency of these filters is also demonstrated by how silver is used in the filtration process. Silver is known for its antibacterial properties and the inclusion of it in the filter forms a second filtration method. If, by chance, any of the bacteria is able to pass through without being electrified, the silver nanowires will kill it. This “double filtration” avoids biofouling, “in which bacteria forms a film on a filter. Biofouling is a common problem in filters that use small pores to filter out bacteria” [6]. The use of silver helps decrease the chance of biofouling and in turn reduces the number of times these filters need to be either replaced or repaired. The silver nanowires (Ag NW) combined with the carbon nanotubes also increase the percent of bacteria filtered out, therefore making these filters more effective. Figure 5 represents the performance of the electrified nanofilter running at a flow rate of 1L/h (or 80000L/(h m2) compared to the same rate for a nanofibrous membrane operating at 130psi [7]. The efficiency of these devices was tested by placing a treated solution of water into an agar plate, “a substrate which includes nutrients and attachment sites for the bacteria” [7]. These plates were then incubated at 37oC for a night. Agar plates are very efficient for this type of test due to how easily they can be read and interpreted. In these plates, each healthy cell in the solution multiplies and generates a colony of bacteria after the incubation period. These colonies can be clearly seen, allowing the healthy bacteria in the initial solution to be counted and compared to the amount of healthy bacteria in the solution after the incubation. The bacteria tested in this example was Escherichia coli. It was mixed into a 100 milliliter solution and contained a density of 107g/mL [7]. It was then put through the electrified nanofilter five times at five different voltages. The results show that at 0V, neither the AgNW/carbon nanotube cotton nor the carbon nanotube cotton alone filtered the bacteria effectively. However, at -20V the AgNW/carbon nanotube cotton inactivated 89% of the bacteria while at +20V it only inactivated 77%. This is a definite improvement compared to the results of the carbon nanotube cotton. At -20V it was approximately inactivating 30% of the bacteria and at +20V it decreased even more until it was barely stopping 10% of the bacteria [7]. These results show how the use of AgNW increases the efficiency of these filters and in doing so, helps make them more affordable. FIGURE 5 This graph represents how the alterations in voltage and the percent bacteria inactivated varies between the AgNW/CNT mixture and CNT mixture [7]. Since traditional nanofilters use small pores, water must be pumped through it at a substantially higher rate than necessary with electrified nanofilters, therefore using more electricity. The electrical current used in electrified nanofilters is 60 mW, which is “barely enough to cause a tingling sensation in a person…The electrical current can be generated by a stationary bicycle or by a hand-cranked device” [8]. In comparison, the power needed by an ultrafiltration membrane is around 250mW [8]. Due to the large pores, water does not need to be pumped into the filters but can instead be pushed through them from the force of gravity. By using this type of process, the “electricity needed to run current through the filter was only a fifth of what a filtration pump would have needed to filter a comparable amount of water” [6]. By requiring less electricity, these filters are able to purify water more efficiently and use less electricity compared to former purification techniques. 4 Shafa Suddle Daniel Blemler is a large cost and difficult challenge” [9]. Through utilizing these filters, water can be made more accessible to the world at a much lower cost. THE FUTURE OF CLEAN WATER Currently, this technology has not been tested enough to be widely distributed for public use. It has been, however, tested on E. Coli and shown to destroy 98% of this bacteria. This filter will need to be tested with various types of bacteria and produce similar, positive results before it can truly begin making an impact on the world. In continuing development, researchers are conducting experiments with electrified nanofilters by replacing the cotton with carbon cloth [7]. Carbon cloth is more conductive and still relatively cheap; while the dimensions of the cotton used are 2.5mm by 4mm in length, a 20cm by 20cm carbon cloth can be bought at a comparable price [8]. Hopefully, with ongoing tests, these filters will be improved further and therefore make water more accessible throughout the world. FIGURE 6 (B) Agar plate with bacteria solution incubated overnight; the light color is from a high density of cell colonies, the grey areas are agar without colonies. (C) Agar plate incubated overnight with paper treated with AgNWs; no colonies are visible [7]. INEXPENSIVE MATERIALS FOR INEXPENSIVE TECHNOLOGY One of the biggest issues with new water purification technology is whether or not the invention is affordable. Engineers have learned how to create clean water but distributing it to impoverished areas in a cost-effective way still seems to be an immense problem. With this in mind, the researchers behind electrified nanofilters looked towards cheap materials that were, “widely available and chemically and mechanically robust,” such as plain woven cotton [6]. This material is extremely accessible (according to Dr. Yi Cui’s report, they bought the fabric at Wal-Mart), and it can be used to conduct electricity [6]. Additionally, the amount of silver needed to create the filter was “so small the cost was negligible” [6]. These costs are miniscule compared to other filters that can range up into thousands of dollars for material costs. One of the highest expenses of nanofilters is the cost of the energy required to pump the water through the filters. The energy needed in traditional filters is around 190mW more than in electrified nanofilters [8]. This change in energy drastically decreased the cost if one considers that powering a 65mW filter costs much less than powering a 250mW filter. Even though the voltage is less than traditional filters, electrified nanofilters have been proven to be 80,000 times faster than traditional filters [6]. The less time it takes to filter the water, the less amount of money is required to purify the water. Such energy efficient ways as found in electrified nanofilters helps to immensely reduce the cost of water purification. Also, replacing filters can but just as expensive, if not more, than operating them. However, since electrified nanofilters have pores between fibers that range from tens to hundreds of micrometers, a size that is significantly larger than that of bacteria, these filters rarely get clogged [7]. According to the American Chemical Society, “such technology could dramatically lower the cost of a wide array of filtration technologies for water as well as food, air, and pharmaceuticals where the need to frequently replace filters ETHICS IN NANOFILTRATION Though the nanofiltration methods previously analyzed are certainly important to providing cheap, quality, adequate amounts of water to the world’s population, it is perhaps more important that engineers keep ethical standards in mind while further developing these innovations. It is not enough for engineers to simply say that their innovations are producing clean, pure water. The public sector relies on this as being true, and if any corners are cut during the manufacturing process of these nanofilters, the health of the population would be directly, negatively affected. While engineers work to restore and improve water purification techniques, it is imperative that they abide by a strict code of engineering ethics such as those laid out by the National Society of Professional Engineers. More specifically, when working with a new technological advancement such as nanofiltration, it is important that the civil engineers involved in these projects strictly follow ethics laid out by an institution like the American Society of Civil Engineers. Through close consideration of these ethics, engineers participating in this particular improvement of water purification will be sure they are performing their jobs to the highest standards. ETHICAL CODES Knowledge of the codes of engineering ethics aids engineers in making ethical and professional decisions concerning the process of providing clean water. Implementing nanofiltration to improve and restore the world’s water supply is a “service provided by engineers [that] requires honesty, impartiality, fairness, and equity, and must be dedicated to the protection of the public health, safety, and welfare” [10]. A professional engineer working in this field 5 Shafa Suddle Daniel Blemler “purified” water and noting what effects this bacteria could have on humans. Any sign of potential concerns should tell the engineer, operating under strict ethical codes, their product cannot be released for practical use. must be attentive to engineering ethics throughout the project at hand. They must be honest from the beginning— considering the various options and weighing out what would be in the customer’s best interest; not their own based on possible financial gains from using inadequate, less expensive materials or failing to relentlessly test their products. Additionally, an engineer who works with water purification should be devoted to improving public health and safety by preventing water being accessed by the public which is not completely safe for consumption. Nanofiltration also follows the ethical code that “engineers shall undertake to perform engineering assignments only when qualified by education or experience in the technical field of engineering involved” [11]. This code is particularly important since nanofiltration is a new innovation to improving water quality. If someone experienced in former methods such as reverse osmosis or ultrafiltration were to undertake a project utilizing electrified nanofilters, their previous experience may not be enough to overcome the differences found while working with these materials. This could lead to faulty manufacturing of the filters and, consequently, harmful effects on consumers. A third canon valuable to an ethical engineer is that “engineers shall build their professional reputation on the merit of their services and shall not compete unfairly with others” [11]. Since a nanofiltration project is one that would often be awarded based upon a bid, it is important that those competing engineers honestly submit their bids with regards to previous experience. It would be unethical for an engineering firm without experience in nanofiltration to place a “low” bid in an attempt to receive the job without regard to the merit of their services. A LONG-LASTING IMPROVEMENT Improving and utilizing nanofiltration will be essential to providing clean water to developing countries and places with inadequate amounts of clean water in the future. As scientists continue working with these electrified nanofilters, they will surely find ways to increase their efficiency and decrease their overall costs. Additionally, further development should lead to ways of commercially producing these filters for large-scale use. With this, many places could have access to an inexpensive method of purifying their surface and groundwater. While working under a code of ethics, engineers will be held accountable for their work which will ensure safe products that purify water to appropriate levels. Keeping ethical standards in mind and striving to deliver an inexpensive, efficient way of purifying water to improve people’s quality of life, engineers are helping to provide a crucial part of daily life for years to come. REFERENCES [1] M. Botes, T. Cloete, M. Kwaadsteniet and J. Lopez-Romero. (2010). “Nanotechnology in Water Treatment Applications.” [Online] Available: http://books.google.com/books?hl=en&lr=&id=_UGytCMXyp8C&oi=fnd& pg=PA103&dq=nanofiltration+overview&ots=uIrH2clqha&sig=PQLOJb7c 1ZKW78xZy4OjkGEzQ5Q#v=onepage&q=nanofiltration%20overview&f= false [2] F. Valli, K. Tijoriwala and A. Mahapatra. (2010, July 28). “Nanotechnology for Water Purification.” Nuclear Desalination. [Online]. Available: http://www.eurekalert.org/pub_releases/2010-07/ipnfw072810.php [3] “Carbon Nanotubes in Drinking Water Treatment.” U.S. Army Public Health Command.[Online]. Available: http://phc.amedd.army.mil/PHC%20Resource%20Library/Carbonnanotubes Apr10.pdf [4] Biliuti, Smaranda. (2010, July 28). “Nanofilters For Pure Water.” Softpedia. [Online]. Available: http://news.softpedia.com/news/NanofiltersFor-Pure-Water-149548.shtml [5] “Alumina Nanofiber Filters in Drinking Water Treatment.” U.S. Army Public Health Command.[Online]. Available: http://phc.amedd.army.mil/PHC%20Resource%20Library/Alumina%20Nan ofiber%20filters%20FS%20Feb%202011.pdf [6] L. Bergeron. (2010, August 31). “High-speed filter uses electrified nanostructures to purify water at low cost.” Stanford University. [Online]. Available: http://news.stanford.edu/news/2010/august/nano-pure-water083110.html [7](August 20). “High Speed Water Sterilization Using One-Dimensional Nanostructures.” Nanoletters. [Online]. Available: http://pubs.acs.org/doi/full/10.1021/nl101944e [8] (2010, November). “Nano Focus: Electrified nanostructures enable lowcost water sterilization.” Materials Research Society. [Online]. Available:http://journals.cambridge.org/action/displayAbstract?fromPage=o nline&aid=7966540 [9] (2010, October 13). “Electrified nano filter promises to cut costs for clean drinking water.” American Chemical Society. [Online]. Available: http://portal.acs.org/portal/acs/corg/content?_nfpb=true&_pageLabel=PP_A RTICLEMAIN&node_id=223&content_id=CNBP_025888&use_sec=true &sec_url_var=region1&__uuid=3741b6e1-2575-429b-b0f4-527647428808 ETHICS AND THE EFFECT ON CONSUMERS Although the main goal behind nanofiltration techniques is to provide clean water to consumers, engineers involved must constantly be attentive to how much bacteria is actually blocked by their products. The properties that make nanofilters fitting for these applications, such as those of carbon nanotubes, alumina fibers, and electrified filters, may also have potential health risk concerns. Since these products are relatively new, limited results are available concerning the effects they have on consumers. However, there are “concerns that carbon nanotubes may interfere or damage DNA [and] could cause harmful effects to organs if introduced into the body” [3]. Additionally, alumina nanofibers could be shed from a filter and be ingested or enter the environment in some other way. In some alumina fibers, there are “concerns that they may increase the risk of cardiovascular disease and adversely affect certain types of brain cells” [5]. With these concerns in mind, it is vital that engineers test their products to ensure that human health is not affected. During the manufacturing process, tests should continually be run, checking the percentage of bacteria released into the 6 Shafa Suddle Daniel Blemler [10] (2011) “NSPE Code of Ethics for Engineers.” National Society for Professional Engineers. [Online: Web site]. Available: http://www.nspe.org/Ethics/CodeofEthics/index.html [11] (2011) “Code of Ethics.” American Society of Civil Engineers. [Online: Web site]. Available: http://www.asce.org/Leadership-andManagement/Ethics/Code-of-Ethics/ ADDITIONAL RESOURCES D. Schoen, A. Schoen, L. Hu, H. Kim, S. Heilshorn and Y. Cui. (2010, August 20). “High Speed Water Sterilization Using One-Dimensional Nanostructures.” Nanoletters. [Online]. Available: http://pubs.acs.org/doi/full/10.1021/nl101944e D. Wareham and P. Elefsiniotis. (1996). “Environmental Ethics in Engineering Education: A Missing Fundamental.” Elsevier Science Ltd. [Online]. Available: http://www.iwaponline.com/wst/03412/0197/034120197.pdf F. Macedonio, E. Drioli, A. Gusev, A. Bardow, R. Semiat and M. Kurihara. (2012, January 11). “Efficient technologies for worldwide clean water supply.” Chemical Engineering and Processing: Process Intensification. [Online]. Available: http://www.sciencedirect.com/science/article/pii/S0255270111002066 V. Bruggen, M. Manttan and M. Nystrom. (2008, October 22). “Drawbacks of applying nanofiltration and how to avoid them: A review.” SciVerse. [Online]. Available: http://www.sciencedirect.com/science/article/pii/S1383586608002104 ACKNOWLEDGMENTS We would like to thank the writing instructors and librarians for their advice during class time and our professors for allowing them to come in. Additionally, we appreciate the help our co-chair and writing instructor have given us. 7