Electronic Supplementary Information Anisotropic magnetic field observed at 300 K in citrate coated iron oxide nanoparticles: Effect of counterions Sushil K. Misra • Lin Li Department of Physics, Concordia University, Montreal, Quebec H3G 1M8, Canada Sudip Mukherjee • Goutam Ghosh () UGC-DAE Consortium for Scientific Research, Mumbai Centre, Mumbai 400 085, India E-mail: ghoshg@yahoo.com; ghoshg@csr.res.in 1 Phase characterization by X-ray Diffraction (XRD) technique Fig. S1 XRD pattern of the dried uncoated iron oxide nanoparticles. All peaks could be indexed as the Fe3O4 phase [JCPDS card no. 82-1533] 2 Surface coating analysis by Fourier-Transform Infra-Red (FTIR) spectroscopy Fig. S2 FTIR spectra of TXC (blue curves) and TXC coated SC-NCs (brown curves) with X is (a) L (Li), (b) S (Na), and (c) K (K). The broad band near 580 cm-1 corresponds to Fe-O vibration in all samples. These spectra confirmed the presence of citrate coating around the core. 3