Conference Session B6 Paper 6148 Disclaimer — This paper partially fulfills a writing requirement for first year (freshman) engineering students at the University of Pittsburgh Swanson School of Engineering. This paper is a student, not a professional, paper. This paper is based on publicly available information and may not be provide complete analyses of all relevant data. If this paper is used for any purpose other than these authors’ partial fulfillment of a writing requirement for first year (freshman) engineering students at the University of Pittsburgh Swanson School of Engineering, the user does so at his or her own risk. REVISED PROPOSAL Nicholas Evanoff, nle8@pitt.edu, Mahboobin, 4:00 Joseph Nicolosi, jdn27@pitt.edu, Mena, 4:00 USE OF MULTI-JUNCTION SOLAR CELLS WITH QUANTUM DOTS TO IMPROVE EFFICIENCY AND PRODUCTIVITY OF SOLAR PANELS The use of multijunction cells with quantum dots can increase the efficiency of solar panels and decrease production costs to make solar energy more profitable and provide a strong alternative to fossil fuels. Regular solar cells convert sunlight from a single region of the spectrum [1]. In multijunction cells, each junction absorbs sunlight from a specific region of the sunlight spectrum, meaning that multiple regions of light can be absorbed and harnessed, as opposed to just one [1]. Because these junctions or subcells can be stacked on top of each other, they have the potential to absorb much more sunlight [1]. Quantum dots can be used to adjust even further what range of the solar spectrum is absorbed by the multijunction solar cells so that these cells can be even more specific as to the range of light they are absorbing, increasing the efficiency of the solar cells [2]. The quantum dots make these solar cells more efficient by making it possible for solar cells to become even more specific in the type of light they absorb, so the cells do not let any light be wasted. What makes quantum dots have the ability to change what light is absorbed is due to their band gap. A band University of Pittsburgh 01-29-16 gap is an area of a solid where no electrons can exist. The only way for them to pass from one side of the solid to the other is if they have enough energy to “jump” the gap [3]. So the area of light absorbed will be determined by the energy of the electrons in each part of the spectrum. [3]. Using multijunction cells with quantum dots to improve solar panels is important to engineering because it makes solar energy much more attractive. As of 2015, solar energy made up only 0.4% of US energy consumption [4]. The main reason for its lack of use as a large source of energy is due to the sizeable numbers of panels needed to produce large amounts of energy [4]. By increasing the efficiency of the solar cells, fewer panels would be needed to produce large amounts of energy. Money would be saved by decreasing the amount of solar panels needed to produce energy, and companies would be able to install more solar panels to increase their energy production. Solar energy would become more attractive because it would become much cheaper and offer a clean energy solution to fossil fuels, which cause a great deal of pollution to meet energy needs. 1 Conference Session B6 Paper 6148 In our paper we will begin by explaining the technology behind solar cells and how multi-junction solar cells differ from single solar cells. After this we will explain the principles behind quantum dots and how they can be used to increase the efficiency of multi-junction solar cells. After this we will show that by increasing the efficiency of solar panels and solar energy, it will make it a more profitable fuel source. By showing it is more profitable now and that it is attractive due to it being a clean energy source, we will be able to make the case that solar energy could replace fossil fuel. We plan on using scholarly articles and sources from the library for our research. REFERENCES Ellingsons, Randy, Mathew Beard, Justin Johnson, Pingron Yu, Olga Micic, Arthur Nozik, and Andrew Shabaev. "Highly Efficient Multiple Exciton Generation in Colloidal PbSe and PbS Quantum Dots." Nano Letters. N.p., 30 Mar. 2006. Web. 13 Dec. 2016. Katz, Cheryl. "Will New Technologies Give Critical Boost to Solar Power?" By Cheryl Katz: Yale Environment 360. Yale University, 11 Dec. 2014. Web. 13 Jan. 2016. Nozik, A.J. "Quantum Dot Solar Cells." Quantum Dot Solar Cells. University of Pittsburgh, 2005. Web. 13 Jan. 2016. TOPIC AREA: INDUSTRIAL We believe that our paper should be included in the industrial engineering category at the conference. We think this because while solar panel technology is part of environmental or mechanical engineering, the technology’s application in this paper will be to improve the efficiency of solar technology to improve profits from it and make it able to expand as an alternate energy. By making solar energy more efficient it will open up a new market to make new consumers. This will optimize the profit for many many energy companies which is exactly what Industrial Engineers do. [1] Zyga, Lisa. "Multijunction Solar Cell Could Exceed 50% Efficiency Goal." Multijunction Solar Cell Could Exceed 50% Efficiency Goal. Phys.org, 20 Feb. 2013. Web. 13 Jan. 2016. [2] BORGHINO, DARIO. "Quantum Dot Breakthrough Could Lead to Cheap Sprayon Solar Cells." Quantum Dot Breakthrough Could Lead to Cheap Spray-on Solar Cells. Giz Mag, 24 June 2014. Web. 13 Jan. 2016. [3] Chandler, David L. "Explained: Bandgap." MIT News. Massachusetts Institute of Technology, 2010. Web. 13 Jan. 2016. [4] Institute for Energy Research. "Solar IER." IER. Institute for Energy Research, 2015. Web. 28 Jan. 2016. ANNOTATED BIBLIOGRAPHY Beard, Mathew. "Multiple Exciton Generation in Colloidal Silicon Nanocrystals." Nano Letters. ASC Publications, 24 July 2007. Web. 13 Jan. 2016. SOURCES CONSULTED Beard, Mathew. "Multiple Exciton Generation in Colloidal Silicon Nanocrystals." Nano Letters. ASC Publications, 24 July 2007. Web. 13 Jan. 2016. University of Pittsburgh 01-29-16 This article, from The American Chemical Society database, describes how multiple exciton generation in colloidal silicon 2 Conference Session B6 Paper 6148 nanocrystals make solar energy more efficient. This article talks about the process of the absorption of a single photon in a nanocrytal. This allows the energy from the photon to be passed through the crystal structure to the electric current. We will use this to explain the process of solar power absorption. importance of bandgaps to solar energy and how they can further improve the absorption of it. Ellingsons, Randy, Mathew Beard, Justin Johnson, Pingron Yu, Olga Micic, Arthur Nozik, and Andrew Shabaev. "Highly Efficient Multiple Exciton Generation in Colloidal PbSe and PbS Quantum Dots." Nano Letters. N.p., 30 Mar. 2006. Web. 13 Dec. 2016. http://pubs.acs.org/doi/abs/10.1021/nl05026 72 BORGHINO, DARIO. "Quantum Dot Breakthrough Could Lead to Cheap Sprayon Solar Cells." Quantum Dot Breakthrough Could Lead to Cheap Spray-on Solar Cells. Giz Mag, 24 June 2014. Web. 13 Jan. 2016. http://www.gizmag.com/quantum-dot-solarcells/32478/ This article is from a journal that focuses on nanotechnology. The article is about findings that quantum dots can be used to increase the efficiency of solar panels through their quantum dots’ bandgap. This is because in normal semiconductors, impact ionization is inefficient due to energy restrains. Quantum dots alleviate this because they have a larger threshold. This article can explain how quantum dots can make solar panels more effective. This article, from a scientific based magazine, explains an experiment done by the University of Toronto analyzing colloidal quantum dots as they interact with oxygen. The article talks about how using different semiconductor within a quantum dot can increase efficiency. It also mentions the applications of an adjustable band gap to optimize the energy intake. It also talks about a spray on application of using quantum dots. Institute for Energy Research. "Solar IER." IER. Institute for Energy Research, 2015. Web. 28 Jan. 2016. This article is from the Institute for Energy Research and explains the technology behind photovoltaic cells and semiconductors. It then explains how solar energy is used in the United States along with how much of it is used compared to other energy sources. Information from this article will help us to show that the solar industry has the ability to grow tremendously using the improvements argued for in our paper. Chandler, David L. "Explained: Bandgap." MIT News. Massachusetts Institute of Technology, 2010. Web. 13 Jan. 2016. http://news.mit.edu/2010/explainedbandgap-0723 This article, from a M.I.T research database, explains the science behind a bandgap and why they are important to solar energy. Bandgaps, found in semi conductors, are areas where electrons cannot be found. Band gaps are what make it possible for semiconductors to harness solar energy. This article will be used to explain the University of Pittsburgh 01-29-16 Kamat, Prashant. "Boosting the Efficiency of Quantum Dot Sensitized Solar Cells through Modulation of Interfacial Charge 3 Conference Session B6 Paper 6148 Transfer." - Accounts of Chemical Research (ACS Publications). American Chemical Society, 11 Apr. 2012. Web. 28 Jan. 2016. http://phys.org/news/2013-02-multijunctionsolar-cell-efficiency-goal.html This article, from a research and technology based website, describes how modern inventions breakthroughs in multi-junction cells are making solar energy more efficient. Throughout the article it talks about the benefits of using a large band gap, increasing the lattice energy difference within the cell, and the effects of using an anti-reflecting coating. The article goes on back up its finding listing experiments from various reputable universities. This article from the American Chemical Society talks about the increasing the Efficiency of Quantum Dot Sensitized Solar Cells through Modulation of Interfacial Charge Transfer. This article goes on to talk about how semiconductor nanocrystals and metal chalcogenides are helpful in maximizing energy intake. The article talks about how the change in band gap corresponds directly to the semiconductor in use. Katz, Cheryl. "Will New Technologies Give Critical Boost to Solar Power?" By Cheryl Katz: Yale Environment 360. Yale University, 11 Dec. 2014. Web. 13 Jan. 2016. Nozik, A.J. "Quantum Dot Solar Cells." Quantum Dot Solar Cells. University of Pittsburgh, 2005. Web. 13 Jan. 2016. http://e360.yale.edu/feature/will_new_techn ologies_give_critical_boost_to_solar_power /2832/ This article, from a Yale University website, explains the benefits of using a mulitjunction that are split into layers. The article describes the cell is composed of different semiconductors such as perovskite and gallium-arsenide that maximize energy consumption by using a series of quantum dots. Is also talks about tunable semiconductors that allow the solar cell to absorb energy from all of the light spectrum. Zyga, Lisa. "Multijunction Solar Cell Could Exceed 50% Efficiency Goal." Multijunction Solar Cell Could Exceed 50% Efficiency Goal. Phys.org, 20 Feb. 2013. Web. 13 Jan. 2016. University of Pittsburgh 01-29-16 4