NATIONAL QUALIFICATIONS CURRICULUM SUPPORT Chemistry Products from Plants [NATIONAL 4] This advice and guidance has been produced to support the profession with the delivery of courses which are either new or which have aspects of significant change within the new national qualifications (NQ) framework. The advice and guidance provides suggestions on approaches to learning and teaching. Staff are encouraged to draw on the materials for their own part of their continuing professional development in introducing new national qualifications in ways that match the needs of learners. Staff should also refer to the course and unit specifications and support notes which have been issued by the Scottish Qualifications Authority. http://www.sqa.org.uk/sqa/47423.html Acknowledgement © Crown copyright 2012. You may re-use this information (excluding logos) free of charge in any format or medium, under the terms of the Open Government Licence. To view this licence, visit http://www.nationalarchives.gov.uk/doc/open-government-licence/ or e-mail: psi@nationalarchives.gsi.gov.uk. Where we have identified any third party copyright information you will need to obtain permission from the copyright holders concerned. Any enquiries regarding this document/publication should be sent to us at enquiries@educationscotland.gov.uk. This document is also available from our website at www.educationscotland.gov.uk. 2 PRODUCTS FROM PLANTS (NATIONAL 4, CHEMISTRY) © Crown copyright 2012 Contents Planning for learning and teaching 4 Skills for learning, life and work 7 Ideas for learning and teaching 11 Practical investigations Dyes from plants Medicines from plants Vitamins and minerals from plants Essential oils from plants 14 14 17 19 22 References 25 PRODUCTS FROM PLANTS (NATIONAL 4, CHEMISTRY) © Crown copyright 2012 3 PLANNING FOR LEARNING AND TEACHING PLANTS TO PRODUCTS Planning for learning and teaching This advice and guidance is intended for use by staff. The learning and teaching suggestions are provided for exemplification only and should be adapted by individuals. It is anticipated that staff will be creative and innovative in planning approaches to meet the needs of learners . This advice and guidance suggests ideas for learning and teaching to prepare learners in the following mandatory course key area: Plants to Products in Nature’s Chemistry within Chemistry National 4 Progression from this topic may lead to further study of Energy within Fuels in National 4 or Agrochemicals at National 5. Advice and guidance has been produced by Education Scotland to support learning and teaching of Agrochemicals. Interdisciplinary learning is important to allow links to be made across subject areas and to develop learners’ higher-order thinking skills. Global citizenship can be developed to promote understanding of the interdependence between people, the environment and the impact of actions locally as well as globally. There are also opportunities for using plants as a context for learning in other curriculum areas, for example: Geography: The effects of intensive farming, crop rotation and other agricultural practices on land quality may be investigated in conjunction with geography. Business Studies: The marketing of a product from a plant source may be carried out in conjunction with business studies or as part of an enterprise activity. As outlined in the Professional Focus Paper for Chemistry at National 4, learning will be best when it applies a variety of creative and innovative approaches to the development of interest and enthusiasm for chemistry. Chemistry provides opportunities for active and collaborative learning in creative, relevant, inspiring and engaging contexts. Well -designed experiences in chemistry will develop learners’ curiosity and problem -solving and analytical thinking skills, skills for collaborative learning and independent thinking, and interest and enthusiasm for learning. Learners 4 PRODUCTS FROM PLANTS (NATIONAL 4, CHEMISTRY) © Crown copyright 2012 PLANNING FOR LEARNING AND TEACHING PLANTS TO PRODUCTS should be fully involved in their learning and be given opportunities for personal achievement in order to help build motivation, resilience and confidence. Concept development Chemistry National 4 is designed to articulate with learning and teaching within the Broad General Education. There are also clear links to Biology National 4/5 (Food security), Chemistry National 5 (Agrochemicals) and Science. Topical science can also be linked to this area of chemistry. Staff should also refer to the Concept development in the sciences paper, which provides more depth to each line of development. The Plants to Products topic may allow progr ession from the third level experience and outcome: I can participate in practical activities to extract useful substances from natural resources. (SCN 3-17b) PRODUCTS FROM PLANTS (NATIONAL 4, CHEMISTRY) © Crown copyright 2012 5 PLANNING FOR LEARNING AND TEACHING PLANTS TO PRODUCTS This advice and guidance should be adapted by staff to allow learners interests to be developed upon. The mind map below includes some ideas that may be of interest to learners. 6 PRODUCTS FROM PLANTS (NATIONAL 4, CHEMISTRY) © Crown copyright 2012 SKILLS FOR LEARNING, LIFE AND WORK Skills for learning, life and work Learners should experience a range of approaches that are designed to develop knowledge, understanding and the skills required for learning, life and work. These should be experiential and learner led. An investigatory approach is encouraged in chemistry and a holistic approach should be adopted to encourage simultaneous development of learners’ conceptual understanding and skills. The study of Plants to Products provides learners with opportunities to develop their competencies in practical skills, pro blem solving, critical thinking and working collaboratively. Additional information is provided in the Course and Unit Support Notes. Building the Curriculum 4 details the skills for learning, life and work, and it is envisioned that these should be embedded in Broad General Education and the senior phase. The agriculture and agrochemicals industries provide a wide spectrum of employment possibilities, from council gardeners to PhD chemists, and therefore the study of this topic can provide links to many occupations. Partnerships with local agrochemical companies and environmental agencies could be made to further support learning in this area. Land-based work offers many opportunities with a wide range of employers and employer organisations. LANTRA, the Sector Skills Council, states that production horticulture and agricultural crops provide over 7000 jobs in Scotland. A recent report from the Forestry Commission states that over 13,000 people work within Scottish woods, forests and wood products. The forests, woods and products contribute over £300 million to the Scottish economy. It has been calculated that approximately 17% of Scotland's land supports woods and forests, and 90% of all schools are within 1 km of woodland. Plant products are also used in the cosmetics industry (eg vitamin E), in the food industry (as flavourings and colours, such as beetroot extract) and in perfumes. Partnerships with local companies (eg cosmetic s or fine chemicals) and environmental agencies could be made to further support learning in this area. STEM ambassadors are a useful resource for this and other science topics. PRODUCTS FROM PLANTS (NATIONAL 4, CHEMISTRY) © Crown copyright 2012 7 SKILLS FOR LEARNING, LIFE AND WORK The importance of current research and development of products from plants cannot be ignored. New plant products may prove to be a key aspect of providing food and energy security in Scotland and beyond. Scientists in Scotland are researching many different ways of using plants as a source of new products. Plants are being used to develop new, renewable sources of feedstocks for the chemical industry, for example starting materials for polymer production and fuel production. Some of these new products will reduce our reliance on fossil fuel s and other non-renewable resources. Learners may already be aware of the use of biomass to develop alternative fuels. Biodiesel can be made from vegetable oils. Alcohol made from sugars and starches is used to make fuel for cars. The National STEM centre has developed a teaching resource about biodiesel. Learners could be encouraged to consider the implications of growing crops like corn for food or fuel on the biodiversity of our planet. In some countries, for example Indonesia, huge areas of forests have been cleared to grow one cash crop to produce palm oil, which is used in cosmetics, toiletries and food. Open-ended question Using your knowledge of plants and their uses, give examples of how plants are being used to help solve some of the world’s problems and explain some of the problems associated with these uses. Learners should be made aware that many scientists are currently resear ching new ways of using plants and plant-based substances. Biomimicry is an emerging area of research and development that is described in this TED talk. This short video demonstrates 12 examples of materials that have been developed using the concept of biomimicry. Plants are being used to decontaminate soils, clean the air and clean water. They are being modified to produce the starting materials (feedstocks) for some industrial processes. Plant-based substances like cornstarch are being turned into biodegradable polymers for packaging, eg polylactic acid. Biodegradable plant-derived plastic 8 PRODUCTS FROM PLANTS (NATIONAL 4, CHEMISTRY) © Crown copyright 2012 SKILLS FOR LEARNING, LIFE AND WORK Plants produce a whole range of complex substances that can be used as alternatives to chemicals. Waxes, fats, proteins and sterols can be extracted and used in commercial products such as cosmetics. Some of the challenges we face in the near future, eg the reduction in fossil fuel supply, pollution and food production, may well be so lved by innovations in the way we use the natural resources of the plants that grow around us. Learners should be encouraged to find out about novel materials and what contribution they may make to these challenges. Corn – a crop for food or fuel? Food from plants – bread, bioethanol fuel pump The Course and Unit Support Notes for Chemistry National 4 suggest skills and techniques that are important in the development of young scientists in preparation for the world of work. The study of Plants to Products could provide opportunities for learners to practise: titrations safe methods of heating PRODUCTS FROM PLANTS (NATIONAL 4, CHEMISTRY) © Crown copyright 2012 9 SKILLS FOR LEARNING, LIFE AND WORK drawing diagrams of apparatus using tables to represent data representing experimental data using bar or line graphs and sketching lines or curves of best fit if appropriate suggesting improvements to investigations with reasoning. 10 PRODUCTS FROM PLANTS (NATIONAL 4, CHEMISTRY) © Crown copyright 2012 IDEAS FOR LEARNING AND TEACHING Ideas for learning and teaching The key area of Plants to Products provides an opportunity for a number of learning activities that could enhance practical and investigative skills while providing a context for scientific research and ICT activity . This advice and guidance uses medical, health and dye products as exemplification. As described earlier, this is not an exhaustive list of plant products and it must be noted that there are many other product types that could be investigated depending on the interests of learners. Alternatively, staff may prefer to consider this topic within another key area, eg acids and alkalis. Card sort exercises could be used as an introduction to the topic. Learners could be shown a variety of consumer products containing plant-based substances. There are numerous examples, including but not limited to: vegetable oils paper tea coffee cotton sugar flour shampoo (coconut, lemon) biodiesel rice aspirin vitamin C tablets evening primrose oil natural food colouring natural flavourings (eg vanilla) perfume body lotion (containing cocoa butter, shea butter, olive oil etc) vegetable-based soap rubber cellulose It may also be a worthwhile exercise to include products that are not derived from plant materials. Learners could categorise the products into self-determined categories and provide reasons for their choice of categories. As an alternative to this card sort exercise learners could be provided with pictures of the plants from which these products are derived and asked to match up the product with the plant. Using a plant product of choice, learners could research the stages of PRODUCTS FROM PLANTS (NATIONAL 4, CHEMISTRY) © Crown copyright 2012 11 IDEAS FOR LEARNING AND TEACHING plant to product. This work could be presented in a variety o f ways, with the learners choosing with negotiated success criteria. The card sort exercise will allow learners to conclude that plants have many uses, from cosmetics to fuels. Working collaboratively, learners could rank the uses in order of importance using a diamond nine exercise. Learners progressing from the Broad General Education should be familiar with the process of photosynthesis and the contribution that plants make to maintaining a CO 2 balance. However, growing plants on an industrial scale often requires the use of fertilisers, special greenhouses and the use of chemicals, including pesticides, fungicides and herbicides. Synthetic fertilisers and pesticides are manufactured in processes that use energy and other resources. Organic farming uses only natural fertilisers and pest control. Learners could be encouraged to consider the issues of sustainability and renewable resources by the use of reflective questioning. If appropriate, this learning activity may allow learners to consider the environmental, social and economic significance of plants grown locally an d/or globally. Reflective questions Plants are renewable resources. What distinguishes a renewable resource from a finite resource? What is meant by the term ‘sustainability’? Many plant materials have been replaced by synthetic polymers, for example nylon rope can replace hemp rope, PVC can replace wood for window frames. However, most synthetic polymers are made from substances obtained from crude oil, which is a finite resource. Can you suggest reasons for the widespread use of oil -based products? Using your knowledge of chemistry describe some ways that the use of plant-derived products could help to minimise climate change . Learning within this key area will allow learners to become aware that plants contain a plethora of often complex chemicals essential to industry and to our daily lives. Learners could be asked to consider the reasons why these chemicals are produced by plants. Poisonous plants could be discussed and links to crime writers such as Agatha Christie could be used to stimulate interest in this topic. The use of digitalis 12 PRODUCTS FROM PLANTS (NATIONAL 4, CHEMISTRY) © Crown copyright 2012 IDEAS FOR LEARNING AND TEACHING as both a poison and a medicine could be a starter for the consideration of medical testing on animals. PRODUCTS FROM PLANTS (NATIONAL 4, CHEMISTRY) © Crown copyright 2012 13 PRACTICAL INVESTIGATION Practical investigations The following experiments have been adapted from the work of SSERC. They provide examples of how plants and their derivatives can be used. These experiments should be adapted to meet the needs of learners to allow progression of scientific skills and offer suitable challenge to all. Dyes from plants Learners may have extracted dyes from plants in the Broad General Education and this should be taken into consideration by staff to ensure progression of skills and knowledge in this topic. In ancient times, cloth was dyed using plant -based substances. The roots, bark, leaves, fruits and wood from certain plants give characteristic colours. Today, most fabric dyes are synthetic chemicals. Indigo is a natural dye extracted from the plant Indigofera tinctoria, commonly known as true indigo. Learners may examine samples of this pink flowered plant to ascertain which part of the plant produces the blue dye. It was the original dye used to colour denim its characteristic blue. The chemical structure of the dye is now known and it can be manufactured synthetically. Indigo plant 14 PRODUCTS FROM PLANTS (NATIONAL 4, CHEMISTRY) © Crown copyright 2012 Denim PRACTICAL INVESTIGATION Learners could find out about other traditional dyes , such as henna, and consider the significance and importance of these dyes in different cultures past and present. The dyeing procedure is a straightforward process. A piece of material is soaked in the dyeing liquid then washed and dried. A mordant is used along with the dye to make the product colour-fast. In the past, mordants were natural chemicals such as urine, vinegar and lemon juice. A procedure for preparing and using dyes is outlined. It is suggested that this experiment is used as a starting point for an investigatory approach . The procedure can be adapted in many ways, as suggested below. The plant dyes have been selected for their availability and safety. Others can be used. Learners should be encouraged to suggest, risk assess and experiment with plants of their choosing. Aim To prepare natural dyes from plants and test the various properties of dyes. To allow for the development of experimental skills, learners can be encouraged to plan and design this experiment. Equipment Squares of white fabric Stirring rod 250 cm 3 beakers Bunsen burner Tripod Heat-proof mat Plant material Turmeric powder Beetroot (boiled or pickled) Tea or coffee (strong solution) Blackberries (brambles) Onion skins Colour produced Yellow Pink Brown Purple Yellow Mordant (if used) 4 g alum (aluminium potassium sulphate) and 1 g cream of tartar dissolved in 100 ml warm water Alternative: 100 ml vinegar PRODUCTS FROM PLANTS (NATIONAL 4, CHEMISTRY) © Crown copyright 2012 15 PRACTICAL INVESTIGATION Safety As part of planning experiments and investigations learners should be encouraged to risk assess the planned procedures. This planning stage, in conjunction with earlier work on plant chemicals , may encourage learners to consider that ‘natural’ does not necessarily indicate a lack of potential risks . Goggles Gloves Procedure 1. 2. 3. 4. Prepare ca. 150 cm 3 of dye solution in a beaker. Onion skins, beetroot or blackberries can be chopped up and boiled in water for approximately 10 minutes then the solution strained. 6 g of turmeric should be added to 150 ml warm water. A strong solution of coffee should be made with 25 g of instant coffee in 150 cm3 water or strong tea made with boiling water, left to brew then strained. Prepare the mordant solution and add 50 cm3 to the dye solution. Alternatively, the fabric can be soaked in the mordant for 30 minutes and dried before adding it to the dye. Add the fabric to the warm dye solution. The longer the fabric is left, the more dye is taken up. It could be left overnight. Rinse the dyed fabric in cold water and leave it to dry. Treatment of results Learners should be given the opportunity to change the basic proce dure above. Photographs may be taken of the experimental procedure or samples as evidence of the process. The technique lends itself to a number of investigations: 1. 2. 3. 4. 5. 6. Compare the effect of using the mordant with no t using the mordant. Compare different dyeing times. Investigate the effect of washing on dye retention. Compare a natural dye with a synthetic dye. Do ‘colour’ washing powders affect dye retention when compared to other washing powders? Use the prepared dyes to indicate pH. 16 PRODUCTS FROM PLANTS (NATIONAL 4, CHEMISTRY) © Crown copyright 2012 PRACTICAL INVESTIGATION Reflective questions Discuss some advantages and disadvantages of using plant dyes instead of synthetic dyes. Consider some reasons that people may have wanted to use dyes. Why do you think more synthetic dyes are used than natural dyes in manufacturing today? Medicines from plants Many medicines in current use are derived from substances found in plants. Learners could find out about some common medicines that are derived from plant substances. Since ancient times, people have recognised that chewing bark or drinking a tea made from certain leaves can help to relieve symptoms like pain or fever. Scientists have been able to identify many of the active ingredients of such plants. Once identified, the chemical structure of the active ingredient can be worked out and the s ubstance can be manufactured in a laboratory. After extensive testing, the substance may be marketed and sold as a medicine. This is a costly process for the pharmaceuticals industry. Aspirin is a well-known example of a useful medicine derived from a pla nt. As understanding of aspirin's properties has grown, its therapeutic applications have widened. It first became established as a hou sehold painkiller and now is considered to be an important medicine in the management of cardiovascular disease. There is increasing evidence that it reduces the risk of some cancers and certain pregnancy complications. There are undesirable side effects of aspirin, including gastrointestinal ulcers and stomach bleeding. Aspirin medications for children under 16 were banned because of the risk of Reye's syndrome. The history of aspirin, from the chewing of willow bark to the isolation of salicylic acid, is summarised in a booklet from the Royal Society of Chemistry (RSC) that can be downloaded from their website http://www.rsc.org/learnchemistry/content/filerepository/CMP/00/000/045/Aspirin.pdf The story of aspirin may be used as a starting point for research around medicines and their efficacy and testing. Learners could source information and use it to create a timeline of the development of aspirin. This could be PRODUCTS FROM PLANTS (NATIONAL 4, CHEMISTRY) © Crown copyright 2012 17 PRACTICAL INVESTIGATION compared to other known drugs. An interesting example of drug use is thalidomide, which is currently being used for some conditions despite previous bans. White willow bark Aspirin tablet A useful exercise in which learners can practice their skills of scientific literacy might be to research a plant-based medicine and consider the accuracy of the sources of information. Some of the following questions could be used to form such a research exercise for learners. Other information could be included by learners. What medical conditions is this plant-based medicine used for? Have the uses changed? When was the active ingredient of the plant discovered? What is the name of the active ingredient and what is its structure? Is the active ingredient still extracted from the plant or is it manufactured? What steps are taken by pharmacologists to make sure a medicine is safe to use before it is sold to the public? Are there any side effects of this medicine? Can you name any other plant that is used to produce a medicine today? How reliable is the information that you have sourced? Is it recent research? Learners should present their findings in a suitable format. One method of presentation could be to use small cards. Working collaboratively learners could be asked to rank the medicines in order of usefulness. 18 PRODUCTS FROM PLANTS (NATIONAL 4, CHEMISTRY) © Crown copyright 2012 PRACTICAL INVESTIGATION Vitamins and minerals from plants Lemons – a source of vitamin C Vitamin E capsules Learners will be aware that vitamins and minerals are used as food supplements and may also be aware that both vitamins and minerals can also be used in topical treatments to help some skin conditions. Some vitamins are plant derived, for example vitamins A, B, C and E. Vitamin E is an antioxidant extensively used in skin creams. Shea butter, avocados and evening primrose oil are rich in vitamin E. Vitamin A is used in skin creams to help treat skin conditions like acne. It is present in fruit and vegetables that are yellow or orange in colour. Selenium is found in Brazil nuts and recent research suggests that selenium intake is correlated with a reduced risk of breast cancer. Lack of vitamin B has been linked to increased levels of depression. Reflective questions 1. 2. 3. 4. Find out what plants contain vitamins A, B and E. Some antioxidant vitamins are said to have an anti-aging effect. What is an oxidation reaction? What evidence is there to suggest that these vitamins have anti-ageing properties? Select a vitamin or mineral and find out what specific conditions it can be used to treat. Consider the effect of too much or too little of the vitamin or mineral. Brazil nuts in UK outlets are mainly imported from Bolivia. Consider the implications of the harvesting of these nuts. Do the health benefits outweigh the disadvantages of the food miles that are used ? Vitamin C is needed in the diet for healing and fighting infection. Vitamin C is also an antioxidant and has been included in some skin products. Fruit and vegetables are important sources of vitamin C. We can determine the vitamin PRODUCTS FROM PLANTS (NATIONAL 4, CHEMISTRY) © Crown copyright 2012 19 PRACTICAL INVESTIGATION C content of various food samples by using iodine in a redox reaction. This experiment can be adapted in a number of ways as an investigation. The following procedure uses droppers or syringes . Burettes may also be used. Aim To compare the vitamin C content of different fruit juices using iodine solution. Equipment Test-tubes 100 cm 3 beaker 10 cm 3 measuring cylinder 5 cm 3 syringes Iodine solution, 0.05 mol l –1 (1.27g iodine and 1.5 g potassium iodide made up to 100 cm 3 with distilled water) 0.1% starch solution Selection of fruit juices – these can be extracted from fruit, filtered and volume measured, or bought as fresh juice, from concentrate etc (dark juices like cranberry will require colour extraction first) Vitamin C tablet – 1000 mg dissolved in distilled water and made up to 1000 cm 3 Procedure 1. 2. 3. 4. 5. 6. 7. Arrange the test-tubes in a rack, one for each juice sample to be tested. Add 4 cm3 iodine solution to each test-tube Add 1 cm3 starch solution to each test-tube. Mix. The solution will be blue/black. Add the fruit juice to the iodine solution using a dropper or syringe. Mix. Record the volume of fruit juice required to remove the blue/black colour from the test-tube. Repeat for each sample of juice (and the vitamin C tablet) and record the results. Present your results in a suitable format . Note Some dilution of juices and solutions may be required to obtain suitable results, eg the vitamin C tablet in solution will contain much more vitamin C than the fresh juices. 20 PRODUCTS FROM PLANTS (NATIONAL 4, CHEMISTRY) © Crown copyright 2012 PRACTICAL INVESTIGATION Learners may discuss the results and the relative vitamin C content of the samples. There are a number of possible investigations: 1. 2. 3. 4. Compare Compare Compare Compare fresh with ‘from concentrate’ juice. vitamin C content over time. the vitamin C content of fresh and cooked samples. previously cut and stored fruit with freshly prepared fruit . Suggested questions Do you think that taking vitamin C tablets would be better than getting vitamin C from fresh fruit or vegetables? Explain your answer. There is a lot of research into vitamin destruction in foods. Do your findings agree with published research? How would you improve the experiment to get more reliable results? There is an opportunity to evaluate the reliability of the sampling of the juices. Do you measure the mass of the fruit or just the volume of the juice extracted? Published tables of vitamin C content are expressed in m illigrams of vitamin C per 100 g of food. Findings can be recorded as an experimental report, including the discussion guided by these questions. Learners could use their research and experimental results to prepare a public information presentation on vitamins and minerals. PRODUCTS FROM PLANTS (NATIONAL 4, CHEMISTRY) © Crown copyright 2012 21 PRACTICAL INVESTIGATION Essential oils from plants Evening primrose Evening primrose oil capsules Some plant-derived substances are used in cosmetics, toiletries and foods. Essential oils are pure oils extracted from plant sources. Lavender, rose, sweet almond and clove oils are commonly available. There are well-established methods of extraction of essential oils in the laboratory using distillation equipment. A simple steam distillation is possible using Quickfit apparatus or test-tubes and a delivery tube. Extraction of oil from orange or lemon peel or cloves is carried out using water in a simple distillation. Minimal starting material is required (unlike the case of rose petals or mint leaves) and the product is highly scented. The experiment could be followed by a further procedure using the extracted oil to make a consumer product such as a candle or a lip balm, although this may require more oil than is produced. An opportunity for interdisciplinary learning exists here, producing, packaging and marketing a product using a plant-derived material. Alternatively, research into the manufacture of cosmetics or toiletries using plant products could be conducted. 22 PRODUCTS FROM PLANTS (NATIONAL 4, CHEMISTRY) © Crown copyright 2012 PRACTICAL INVESTIGATION Aim To extract essential oils from orange or lemon peel . Equipment Quickfit apparatus can be used for this experiment. Alternatively, a boiling tube, delivery tube and test tube could be used. Bunsen burner Tripod Ice 250 cm 3 beaker Anti-bumping granules Stand and clamp Orange or lemon peel (fresh or dried) Paper towel Distillation equipment Procedure 1. 2. 3. 4. Chop up and mash about 15 g of orange peel (try to avoid any white pith) with 20 ml water. Put the peel and water in a boiling tube or round-bottomed flask with some anti-bumping granules. Set up the distillation apparatus as shown in the diagram. (Use a paper towel soaked in cold water wrapped around the delivery tube as a condenser if not using Quickfit apparatus.) Use a low Bunsen flame or electric heating mantle to gently boil the water. PRODUCTS FROM PLANTS (NATIONAL 4, CHEMISTRY) © Crown copyright 2012 23 PRACTICAL INVESTIGATION 5. 6. Collect about 15–20 ml of condensate (the liquid in the test-tube). The steam should condense in a test-tube or beaker set in ice. The condensed liquid should contain essential oil from the peel. The oil should be seen as a thin layer above the water and have a strong smell of citrus. This is a simplified version of steam distillation. Normally the peel would be separated from the steam by a plug of glass wool so that the steam passes over the mashed up peel. If the oil is not to be collected for further use, eg to make lip balm, this method, without the glass wool, works well. Carrying out a distillation and drawing the apparatus are both skills required at National 4. The following RSC resource has a method for steam distillation and a number of suggestions for the use of the prepared essential oils, including making lip balm. It includes help with cost analysis, packaging and marketing. This may offer a good opportunity for an interdisciplinary learning project. http://www.rsc.org/learn-chemistry/resource/res00000790/wash-bagchemistry Extraction of the essential oil limonene from oranges. The poster presentation can be used by learners as a template for a poster. www.reading.ac.uk/web/FILES/chemistry/Limonene.pdf Article about using essential oils in aromatherapy. http://www.cancer.gov/cancertopics/pdq/cam/aromatherapy/healthprofessiona l/page3 Lip balm containing essential oils 24 PRODUCTS FROM PLANTS (NATIONAL 4, CHEMISTRY) © Crown copyright 2012 Skin cream REFERENCES References Resource discussing how plants are used to produce useful products. http://www.rsc.org/learn-chemistry/resource/res00000875/challenging-plantsproducts-from-plants Article about extracting waxes from plants and using them to make polymers. From waxes to riches, J. Clark and F. Deswarte, Education in Chemistry Vol. 45, Number 3, p 76, 2008. www.rsc.org/Education/EiC/issues/2008May/Index.asp Article about food vs fuel debate. http://www.google.co.uk/url?sa=t&rct=j&q=guardian.co%2Fuk%2Fcommenti sfree%2F2012%2Faug03%2Famerica&source=web&cd=1&sqi=2&ved=0CFAQFjAA&url=http%3A%2F%2Fwww. guardian.co.uk%2Fcommentisfree%2F2012%2Faug%2F03%2Famer icancorn-feed-people-notcars&ei=saEfULrCAdLa0QWX34HQCg&usg=AFQjCNHNedXDf_Rk_FqOU RvwBgE47GtgPA Article discussing fears that using corn as fuel will raise food prices. http://www.google.co.uk/url?sa=t&rct=j&q=http%3A%2F%2Fnytimes.com% 2F2011%2F04%2F07%2Fscience%2Fearth&source=web&cd=1&sqi=2&ved= 0CFIQFjAA&url=http%3A%2F%2Fwww.nytimes.com%2F2011%2F04%2F0 7%2Fscience%2Fearth%2F07cassava.html&ei=zaAfUKWoGYel0AWy94HIC Q&usg=AFQjCNF39JsC7DhIAfNILCsKFLpx1Brpmg Natural balance – threats to the rainforest. Short video (4.33 minutes) discussing the problem of sustainability in Brazilian rainforests. http://www.bbc.co.uk/learningzone/clips/natural-balance-threats-to-therainforest/4712.html Article on making plastic from plants http://www.rsc.org/chemistryworld/News/2010/November/2511 1003.asp PRODUCTS FROM PLANTS (NATIONAL 4, CHEMISTRY) © Crown copyright 2012 25 REFERENCES Article from Scientific American about the process of producing fuel from crops such as soya bean. http://www.google.co.uk/url?sa=t&rct=j&q=using%20plants%20to%20make %20fuel&source=web&cd=1&sqi=2&ved=0CFcQFjAA&url=http%3A%2F%2 Fwww.scientificamerican.com%2Farticle.cfm%3Fid%3Dusing -plants-insteadof-petroleum-to-make-jetfuel&ei=TaIfUK6MBcjV0QWk6YHwCg&usg=AFQjCNHkkbr -hBhjJ0_kyr9f5lSx57qfg Article about using plants to clean water. http://search.mywebsearch.com/mywebsearch/redirect.jhtml?searchfor=using +plants+to+clean+polluted+water&cb=YW&n= 77C09F4F&qid=069c8564007a4acf85c1048b6c2d154a&ptb=53D4EF8FCD57-4AD0-823A92A918782421&id=YWxdm002YYgb&pg=GGmain&ptnrS=YWxdm002YYg b&action=pick&ss=sub&pn=1&st=hp&pr=GG&tpr=hpsb&redirect=mPWsrdz 9heamc8iHEhldEScnQP%2Byj1AwJX6DKOFr8FbQAHz7FZOu6%2BCv0pM SS8p3rLkQqkWeCokhY2MOFXmxgE%2BThF3bpeeUjgxti p%2FwEHnhIWS nV8ZNmw%2BWsqRjo4I3%2Bklj7Lfr3DI8cvi1dwL88Q%3D%3D&ord=5&ct =AR& Factsheet from Rainforest Action Network http://ran.org/problem-palm-oil-factsheet More experiments for dyes. http://www.open.edu/openlearn/science-mathstechnology/science/chemistry/diy-experiments-natural-dyes You choose the news allows learners to create their own news stories from a bank of clips. The news stories are judged to be balanced or unbalanced and learners can consider bias in the media http://www.hutton.ac.uk/learning/games-resources/you-choose-news A short article giving the recent history of aspirin. http://www.telegraph.co.uk/health/healthnews/8184625/History -ofaspirin.html Workbook on aspirin that may be useful for background information. http://www.rsc.org/learnchemistry/content/filerepository/CMP/00/000/045/Aspirin. pdf 26 PRODUCTS FROM PLANTS (NATIONAL 4, CHEMISTRY) © Crown copyright 2012 REFERENCES Book containing the method for the vitamin C/iodine experiment. Contemporary Chemistry for Schools and Colleges , Vanessa Kind, RSC, 2004 Information about the vitamin content of foods. http://www.naturalhub.com/natural_food_guide_fruit_vitamin_c.htm Information about fat-soluble and water-soluble vitamins. http://www.bbc.co.uk/health/treatments/healthy_living/nutrition/dietary_vitfa t.shtml PRODUCTS FROM PLANTS (NATIONAL 4, CHEMISTRY) © Crown copyright 2012 27