FIELD TEST OF COMPOST AMENDMENT TO REDUCE NUTRIENT RUNOFF FINAL REPORT prepared by: Robert B. Harrison Mark A. Grey Charles L. Henry Dongsen Xue UNIVERSITY OF WASHINGTON COLLEGE OF FOREST RESOURCES Ecosystem Science and Conservation Division Box 352100 Seattle WA 98195 206 685 7463 voice 206 685 3091 FAX May 30, 1997 prepared for: Phil Cohen Effect of Compost on P Runoff Final Report City of Redmond Public Works Redmond, WA 98052 page 2 Effect of Compost on P Runoff Final Report page 3 TABLE OF CONTENTS TABLE OF CONTENTS ............................................................................................................... 3 EXECUTIVE SUMMARY ............................................................................................................ 4 INTRODUCTION AND PROJECT OVERVIEW...................................................................... 5 SITE, METHODS AND MATERIALS ........................................................................................ 6 Site Description and Construction ....................................................................................... 6 Soil and Compost Analysis .................................................................................................... 6 Plot Establishment and Fertilization .................................................................................... 7 Storm Simulation ................................................................................................................... 8 Runoff Characterization and Collection .............................................................................. 8 Runoff Analysis ...................................................................................................................... 8 RESULTS AND DISCUSSION ..................................................................................................... 9 Soil and Compost Analysis .................................................................................................... 9 Storm Hydrology .................................................................................................................. 10 Water Chemistry .................................................................................................................. 10 Hydrology and Water Chemistry Assimilation ................................................................. 13 SUMMARY AND CONCLUSIONS ........................................................................................... 16 Summary of Results ............................................................................................................. 16 Implications of Results ........................................................................................................ 17 Future Directions ................................................................................................................. 18 Effect of Compost on P Runoff Final Report page 4 EXECUTIVE SUMMARY This project looked at the use of compost as an amendment to Alderwood series soil to increase water-holding capacity, reduce peak flow runoff, and decrease phosphorus in runoff. Seven 8 ft. x 32 ft. beds were constructed out of plywood lined with plastic and filled with Alderwood subsoil or mixtures of soil and compost. These beds were located at the College of Forest Resources Center for Urban Horticulture at the University of Washington. Samples were taken over the period from March 7 to June 9, 1995. Compost amendment had the following effects on physical water properties: * Water-holding capacity was about doubled with a 2:1 compost:soil amendment. * Water runoff properties were improved with the compost amendment, with the compostamended soil showing greater lag time to peak flow at the initiation of a rainfall event and greater base flow in the interval following a rainfall event. Water chemistry (total P, soluble-reactive P and nitrate-N) was measured for a series of artificial and natural rainfall events. For the overall study, which included fertilizer treatments, the following results were observed: Runoff from the compost-amended soil had 24% lower average total P concentration (2.05 vs. 2.54 mg/L) compared to the Alderwood soil that did not receive compost amendment. Soluble-reactive P was 9% lower in the compost-amended soil (1.09 vs 1.19 mg/L) compared to the Alderwood soil that did not receive compost amendment. Nitrate-N was 17% higher in the compost-amended soil (1.68 vs 1.39 mg/L) compared to the Alderwood soil that did not receive compost amendment. The water flow data from several storm events was coupled with the nutrient concentration data to generate fluxes of nutrients from the plots. Results of these studys were variable, with compost-amended soils lower in total P runof than unamended. When totals of fluxes are summed, the compost-amended soils showed the following: * 70% less total P, * 58% less soluble-reactive P and * 7% less nitrate in runoff compared to runoff from the till-only soil. Differences in fluxes were attributed more to the changes in water flux rates than to water chemistry, but both accounted for the lowered P with compost amentment. The results of this study point out the promise of the use of organic amendments for improving water-holding capacity, runoff properties and runoff water quality of Alderwood soils converted to turfgrass from future development. The variability of results indicate a need for larger-scale field confirmation (with replicated plots) of the results from these constructed research plots. Ideally, any future study would include a turf established with other common commercially-utilized methods, such as the practice of placing sod directly onto glacial till soil. Effect of Compost on P Runoff Final Report page 5 INTRODUCTION AND PROJECT OVERVIEW The College of Forest Resources (CFR) examined the effectiveness of using compost as a soil amendment to increase surface water infiltration to reduce the quantity and/or intensity of surface and subsurface runoff from land development projects. In addition compost amendment was evaluated for its ability to reduce the transport of dissolved or suspended phosphorous (P) and nitrogen (NO3) from drainage waters for the City of Redmond. The goal was to evaluate options for improving the quality of water reaching Lake Samammish, Bear Creek and the Sammamish River. Currently, due to the wide distribution and inherent stability of till soils in the region, most residential housing developments are sited on the Alderwood soil series, which is characterized by a compacted subsurface layer that restricts vertical water flow. When disturbed (and particularly when disturbed with cut and fill techniques as with residential or commercial development), uneven water flow patterns develop due to restricted permeability. This horizontal flow of water on the surface and subsurface contributes to excessive overland flow, especially during storm events, and transport of dissolved and suspended particulates to surface waters. Research has demonstrated compost's effectiveness in improving the soil physical properties of porosity, continuity of macropores, and water holding capacity which directly influence soilwater relationships. It is clear that compost's chemical properties can also be valuable in some cases, such as in complexing potentially harmful trace metals including copper, lead, and zinc. Under this premise, the CFR examined the effectiveness of using compost to increase stormwater infiltration and water holding capacity of these glacial till soils. Additionally, the CFR examined whether or not increasing the infiltrative and retentive capacity of glacial till soils (Alderwood series) can increase the contact with and retention of P and N by soil absorptive mechanisms, and the production of P and N in surface and subsurface runoff by unamended and amended soils during rainfall events. The CFR utilized the existing Urban Water Resource Center (UWRC ) project site at the University of Washington's Center for Urban Horticulture (CUH) for conducting the study. The CFR utilized the UWRC design of large plywood beds for containing soil and soil-compost mixes. These beds were located at the College of Forest Resources Center for Urban Horticulture at the University of Washington. Water was supplied from a nearby existing water supply system and used to simulate actual rainfall conditions. Simulated rainfall events of varying intensity were scheduled to characterize infiltration rate, quantity of water flowing overland and subsurface, quantity of water leaving study plots, and water quality leaving study plots. Samples were taken over the period from March 7 to June 9, 1995. The following paper describes the site, methods, results, and potential implications of these studies. Effect of Compost on P Runoff Final Report page 6 SITE, METHODS AND MATERIALS Site Description and Construction What was done. Working with the UWRC, the CFR utilized the existing site and associated facilities at the University of Washington CUH. The system includes two different (different sites) Alderwood till soils that were transported to the site, and several mixtures of the till soils and compost mixtures readily available in the Seattle area. These mixtures include two control till soils, a 2:1, 3:1 and 4:1 mixture (soil:compost by volume) of Cedar Grove fine compost:till soil, a 2:1 Cedar Grove coarse compost:till soil mixture, and a 2:1 GroCo compost:till soil mixture. Figure M-1 shows the plot layout and treatments for the site. The soil and compost for this study was mixed on an asphalt surface with a bucket loader and hauled and dumped into the plot bays. The UWRC built the bays and installed the sprinkler and water monitoring system. A system of collection buckets to allow sampling of runoff at intervals ranging from 15 minutes to longer was installed as well. Soil and Compost Analysis Soil and soil/compost mixture samples were analyzed by the CFR analytical labs for the following parameters: 1) total C, 2) total N, 6) bulk density, 7) particle density, 3) gravimetric water holding capacity (field capacity) moisture, 4) volumetric water holding capacity (field capacity) moisture, 5) total porosity, 8) particle size analysis, and 9) soil structure. Samples were collected in August, 1994 from plot 1 (unamended Alderwood soil 1) and plot 2 (2:1 Cedar Grove fine compost:Alderwood soil 1). Analysis results are located in Appendix Table 1a. These were characterized for all of the above properties. Samples were also collected in December, 1994, but due to extremely wet conditions, it was not always possible to characterize samples for all of the above properties. Total C and N were determined using an automated CHN analyzer since they were considered to be the primary measures of soil productivity in these soils. Bulk density was estimated using a Effect of Compost on P Runoff Final Report page 7 coring device of known volume (bulk density soil sampler). The core was removed, oven dried, and weighed. Bulk density was calculated as the oven dry weight divided by the core volume. Particle density was determined by using a gravimetric displacement. A known weight of soil or soil/compost mixture was placed in a volumetric flask containing water. The volume of displacement was measured and Particle density calculated by dividing the oven dry weight by displaced volume. Gravimetric water holding capacity was determined using a soil column extraction method that approximates field capacity by drawing air downward through a soil column. Soil or soil/compost mixture was placed into 50 ml syringe tubes and tapped down (not compressed directly) to achieve the same bulk density as the field bulk density measured with coring devices. The column was saturated by drawing 50 ml of water through the soil column, then brought to approximate field capacity by drawing 50 ml of air through the soil or soil/compost column. Volumetric water holding capacity was calculated by multiplying gravimetric field capacity by the bulk density. Total porosity was calculated by using the following function: bulk density total porosity = 1-( particle density ) x 100% (eq. 1) Particle size distribution was determined both by sieve analysis and sedimentation analysis for particles less than 0.5 mm in size. Due to the light nature of the organic matter amendment, particle size analysis was sometimes difficult, and possibly slightly inaccurate. Soil structure was determined using the feel method and comparing soil and soil/compost mixture samples to known structures. Plot Establishment and Fertilization Plots were planted to a commercial turfgrass mixture during the Spring, 1994 season. Fertilizer was added to all plots during plot establishment in the Spring of 1994 (16-4-8 N-P2O5K2O) broadcast spread over the study bays at the rate recommended on the product label (0.005 lb fertilizer/ft2). The initial application resulted in an application of 0.023 lb of elemental P as orthophosphate per plot or 0.000087 lb P/ft2. This resulted in an application of 0.20 lb of elemental N as ammonium and nitrate (undetermined distribution) per plot or 0.00080 lb N/ft2. Due to the poor growth of the control plots, and in order to simulate what would have likely been done anyway on a typical residential lawn, an additional application of 0.005 lb/ft2 was made to control plots on May 25, 1995. This helped to establish grass over a larger proportion of the Effect of Compost on P Runoff Final Report page 8 surface, which was quite bare. The compost-amended plots never appeared to need fertilizer following establishment, and thus fertilization wasn't necessary to establish turfgrass. Storm Simulation Both surface and subsurface runoff were collected following seven simulated rainfall events. To create uniform antecedent runoff conditions, some storm events were quickly followed by another event. Simulated rainfall was applied at total amounts ranging from 0.76 to 2.46 inches equivalent per storm, and rates ranging from 0.29 to 0.63 in/hour (Table M-1). The total amounts and rates of rainfall during artificial events was estimated by placing collection tins across and along the length of the plots. The amounts of water in the tins was measured at regular intervals during plot irrigation. Runoff Characterization and Collection Runoff amounts and rates were measured for 15 minute intervals by use of tipping bucket type devices attached to an electronic recorder. Each tip of the bucket was calibrated for each site and checked on a regular basis to give rates of surface and subsurface runoff from all plots. There appears to have been some movement of surface flow along the junction between the plot containers and soil or soil/compost during heavy surface flow events, particularly for the soil-only plots. There were also several instances where tipping buckets stuck during high rates of water flow. These were fairly easily noted visually and by the data on the recorder (Table M-1). Runoff was collected from bucket tips during 36 separate intervals by placing a collection bucket at the base of the tipping bucket during each simulated rainfall event. Anywhere from 1 to 7 samples were taken for each storm event with intervals ranging from 15 minutes to 191 hours (Table M-2). Runoff Analysis Runoff was analyzed by the CFR analytical laboratory for the following chemical species: 1) Soluble-reactive P (SRP), 2) Acid-hydrolyzeable phosphorus (AHP) 3) total Phosphorus (TP), 4) soluble nitrate (NO3) Effect of Compost on P Runoff Final Report page 9 All work was done in accordance with University of Washington analytical laboratory QA/QC procedures. RESULTS AND DISCUSSION Soil and Compost Analysis The total C, total N, bulk density, particle density, gravimetric water holding capacity (field capacity) moisture, volumetric water holding capacity (field capacity) moisture, total porosity, particle size analysis, and soil structure of Alderwood soil and soil/compost mixtures is given in Appendix 1 for the August, 1994 and December, 1994 samplings. Results show large changes in the chemistry and physical properties of the soil/compost mixtures due to the compost amendment (Appendix 1a, Appendix 1b). The terminology used in industry and science for compost and soil properties is somewhat inconsistent, so it will be explained quickly how calculations were made. First, percentages can be given as % by weight or % by volume. In this report, percent by weight uses an oven-dried basis for calculation. Volumes can change depending on handling, storage, moisture content and other factors. As a final note the density (volume per unit weight) for compost is usually much lower (i.e. 0.2-0.3 g/cm3) than for soil (i.e. 1.0-1.4 g/cm3), so a weight percent change from compost amendment will usually be much lower than a volume unit change, and moisture capacity based on volume may be much different than moisture capacity based on weight. Total C and organic matter was enhanced, increasing from 0.2-0.3% C (0.3-0.5% organic matter) to about 2.4-2.8% C by weight (4.1-4.8% organic matter) with the compost amendment. Total N was also enhanced, increasing from 0.04-0.12% to about 0.17-0.27% with the compost amendment. Gravimetric field moisture capacity increased significantly from 19-29% to 35% with the compost amendment. Volumetric field moisture capacity was also increased from 24 to 37% by the addition of compost. Total porosity was increased from 19 to 39%. It appears that the measurement of porosity might have been poor for the unamended sites, since this is extremely low for a soil. Bulk density was decreased from about 1.3-1.9 to 1.1-1.3 g/cm3. Particle density was decreased from about 2.3-2.5 to 2.0-2.1 g/cm3. Particle size analysis was not greatly affected by the compost amendment. Soil structure, which is not a quantitative property, was also not greatly affected by compost amendment. Thus, there was a generally beneficial effect of the compost amendment in regards to nutrient content as well as soil physical properties known to affect water relations in soils. Effect of Compost on P Runoff Final Report page 10 Storm Hydrology There are significant effects of the compost amendment on water relations in these soils. For instance, Figure R-1a to R-4b show results of four storm simulations for periods starting April 25, May 11, May 15 and May 25, 1995. These simulated storms ranged in total amounts from 1.4 to 4.8 inches, and in rates from 0.29 to 0.47 inches per hour. Though other events were sampled and measured, there were problems with the waterflow collectors, and data is not presented here. The first storm simulation clearly shows the general results, which were consistent throughout the study periods. For instance, Figure R-1a shows the rainfall, runoff (subsurface + surface flow), and storage for the period starting 8:30 AM April 25, 1995. The Y axis is given in liters (per 15 minute period), and the y axis hours from start of event. Following the start of the rainfall event, there is an increased lag time before significant runoff occurs (Figure R-1a and R-1b). The compost-amended plot continues to store higher rates and total amounts of water for a longer period of time. Following cessation of rainfall inputs, there are higher rates of runoff for a longer period of time. Quicker runoff response to rainfall events is the classic response of hydrology to urbanization, and this is clearly illustrated in Figure R-1a and R-1b. The total storage is also increased with the compost amendment, increasing from about 300 to 500 liters, and the field capacity is also increased from about 250 to 400 liters. Numerical characteristics of the response hydrology are summarized in Table R-1 for Simulation 1. Following the start of rainfall onto the sites at the rate of about 0.3 in/hour, it takes the control unamended plot 1 approximately 30 minutes to respond with runoff > 0.01 in/hour from an initial flow of nearly zero. The compost-amended site takes 1.0 hour or nearly twice as long to respond with flow > 0.01 in/hour. It takes 0.75 hours from the start of the rainfall simulation for flow to become > 0.1 in/hour in the unamended soil, while it takes 1.75 hours for the compost-amended soil to increase to that rate, an increase of 1 hour compared to the unamended site. In order for the runoff to reach 90% of input rate, it takes nearly 2.0 hours for the unamended site compared to 5.25 hours for the compost amended site, an increase of 3.25 hours compared to the control. This is an intense storm and results for moderate storms would likely show similar results. Following the cessation of rainfall, it takes 0.75 hours for runoff in the unamended site to drop to < 10% of the rate of input, where it takes 1.5 hours for the compost-amended site, an increase of 0.75 hours. It takes 1.75 hours following the cessation of rainfall for runoff in the unamended site to drop to <0.01 in/hour, while it takes 6.5 hours for the compost-amended site, an increase of 4.75 hours. Effect of Compost on P Runoff Final Report page 11 Similar results are seen with the additional three sampling periods, with storms of lesser total amounts, including one series of natural rainfall events (Figures R-2a to R-4b). Compostamended soils consistently had longer lag times to response, longer times to peak flows, higher base flows, higher total storage, and smaller total runoff than unamended soils. This indicates that compost-amended soils have better water-holding and runoff characteristics than unamended Alderwood soils and streamflow characteristics would likely benefit from an amendment made to Alderwood soils in the region. Water Chemistry Caveats. We believe it is important to start with a cautionary note in terms of directly comparing the concentrations of unamended with compost-amended plots in terms of the practical use of compost vs. inorganic fertilizers in a field situation to achieve a desired turf. If there is a minimum standard of aesthetic for the turf for a given area of land, whether it is compostamended or not, it is apparent from the visual appeal of the sites at CUH that more inorganic fertilizer will be applied in the unamended vs. the compost-amended Alderwood soils to achieve the same visual appeal. Following planting, compost-amended plots developed a dark green color quickly, and achieved 100% coverage much more rapidly than unamended plots. At the end of this study, the compost-amended sites were much better aesthetically, with a darker green color and no bare spots. No soil can be seen through the grass. There are many bare spots with exposed soil in the plots that did not receive compost amendment. The rates of growth of turf were also greater even after a considerable period of time. The visual appeal of the compost-amended sites was much greater during the duration of the study, although all sites did grow grass. However, when inorganic fertilizer was applied initially, it was applied equally at all sites since there was nothing but bare ground initially, and in addition, the standard of aesthetic is not quantitative. Over time, however, it was apparant that it would be very difficult to achieve the same visual appeal with inorganic fertilizer applied to Alderwood soil only in comparison to the compost-amended Alderwood soil. Unfortunately, this reduces the utility of this study in evaluating a compost-amended site that would not receive inorganic P fertilizers. We clearly needed a comparative study of equal visual appeal. This was not achieved, since the compostamended sites were clearly visually superior. Overall range of solution concentrations. The average solution analysis concentrations of samples are given Table R-2, with each individual sample analyzed given in Appendix 2, and averages of each plot in Appendix 3. It is obvious that there is a great deal of variation in P and N chemistry in runoff from these results. For instance, the average total P (TP) concentration for all samples analyzed was 2.29 mg/l while the minimum P was 0.07 and the maximum 21.0 mg/l Effect of Compost on P Runoff Final Report page 12 (Appendix 2, Appendix 3 and Table R-2). This represents a high degree of variation (greater than 100x) in concentration. This is not wholly unexpected in a system such as the one studied with treatments ranging from surface runoff with high water flow in a very infertile, unfertilized glacial till soil to surface and subsurface runoff in soils freshly fertilized with soluble NPK fertilizers. Basic conclusions are as follows 1) The high amount of variation (S.D. generally > 100%) seen in these results makes drawing specific and consistent conclusions with statistical significance difficult. 2) It was also not possible to directly compare compost-amended with unamended plots statistically (i.e. by ANOVA), since there are only two control plots at the CUH. The soluble-reactive P (SRP) concentration for all samples analyzed was 1.14 mg/l while the minimum P was 0.01 and the maximum 7.02 mg/l (Appendix 2, Appendix 3 and Table R-2), indicating that the SRP was generally a little less than half of the total for all samples (SRP/TP ration for all samples = 0.42). The average SRP concentration measured is considerably above the Water Quality recommendations for freshwater according to WAC 173-201 (1992), which is 0.100 for flowing water not discharging directly into a lake or impoundment. There is no standard for total phosphorus or nitrate. . The NO3-N concentration averaged 1.54 mg/l while the minimum NO3-N was 0.17 and the maximum 9.14 mg/l (Appendix 2, Appendix 3 and Table R-2). Thus, the variation of solution NO3-N was also quite high, ranging nearly 100x in concentration. Averages-comparison of amended vs. unamended. For overall averages, there was not a great deal of difference between runoff collected from compost-amended and unamended plots. For instance, runoff solutions had TP concentration averages of 2.54 mg/l in unamended vs. 2.05 mg/l for the compost-amended plots, indicating that overall, the amended sites had lower total P. This was true for SRP as well, with runoff averaging 1.19 mg/l in unamended vs. 1.09 mg/l for the compost-amended plots (Table R-2). The OP was higher in compost-amended soils, averaging 1.29 mg/l in unamended vs. 0.85 mg/l for the compost-amended plots. Runoff solutions had NO3-N concentration averages of 1.39 mg/l in unamended vs. 1.68 mg/l for the compost-amended plots, indicating that overall, the amended sites had higher NO3-N (Table R-2). Storm events-comparisons. Since the most direct comparisons that can be made are between plot 1 (unamended Alderwood soil 1) vs. plot 2 (2:1 Cedar Grove fine compost:Alderwood soil 1), and between plot 5 (unamended Alderwood soil 2) vs. plot 6 (2:1 GroCo compost:Alderwood soil 2), the plots of runoff concentrations vs. time are grouped comparing plot 1 with 2 and plot 5 with 6. Though there is a great deal of variation in the data, as mentioned earlier, there are some Effect of Compost on P Runoff Final Report page 13 trends in total P concentrations with time. It is also clear that the fertilization treatment in May that fertilization has an immediate effect on the P concentration of runoff from these sites. Figure R-5 and Figure R-6 show TP vs. event number (from Table M-2) for Plot 1 and 2 surface and subsurface runoff. The concentrations for collection intervals 1-7 are relatively low, but the concentration of the control unamended increases greatly following fertilization with organic fertilizer, increasing to 14.2 for the surface and 18.0 for subsurface runoff (Figure R-5 and Figure R-6) collected during the 05/27/95--09:00-12:20 interval. The total P concentrations decrease gradually over the following 2 weeks of collection and return to about their original baselines. The compost-amended plots, which neither needed nor received fertilizer, also had increases in TP concentrations, probably associated with increase organic matter decompostition and release of mineral nutrients. By the end of the study, the total P concentrations of solutions collected from surface and subsurface runoff from plot 1 and 2 were nearly the same (Figure R-6). High concentrations appeared to be associated with the fertilization treatment of unamended plot 1, and the P in these samples was highly soluble. For instance, 60% of the total P in the surface runoff from the 05/27/95--09:00-12:20 collection interval from plot 1 was SRP and nearly 40% of the P in the subsurface runoff was SRP. The TP concentrations in plot 5 (unamended Alderwood soil 2) and plot 6 (2:1 GroCo compost:Alderwood soil 2) show results very similar to those for plot 1 and 2. For instance, Figure R-7 shows TP vs. event number (from Table M-2) for Plot 5 and 6 surface and subsurface runoff. The concentrations are lower then 5 mg/l until after the second fertilization of control plots, and then it increases rapidly (maximum >20mg/l) for the control plot 5 for several sampling periods after that. The concentrations drop rapidly and by sampling period 32, the concentrations of total P are below 5 mg/l again. Soluble-reactive P (SRP) is the most bioavailable fraction of P analyzed in this study. SRP concentrations are lower than total P concentrations for all samples taken at the same time, and also generally lower overall. When plots 1 and 5 are fertilized, the SRP also increases greatly in the unamended plot, and generally decreases back to previous levels after several weeks (Figure R-8). The same general pattern of response to fertilization is seen in plot 5 (unamended Alderwood soil 2), compared to plot 6 (2:1 GroCo compost:Alderwood soil 2). Following the second fertilization of unamended plots on May 2, SRP concentrations increase abruptly for plot 5, and then decrease after several weeks of elevated SRP concentrations. Overall, concentrations of SRP are lower for the compost-amended vs. control plots (Figure R-8 and R-9). Nitrate concentrations varied considerably in these studies and there was no clear pattern. There was no apparent increase in Nitrate concentration following the second fertilization of the Effect of Compost on P Runoff Final Report page 14 control plots on May 25, either, which is unexpected. Apparently, the control plots are nitrogen and not phosphorus-limited in fertility, such that an increase in the availability of nitrogen does not necessarily increase the solubility since the plants and microbes in the soil retain that added nitrogen, and do not allow it to mineralize to nitrate. This variability in nitrate concentration can be seen in Figure R-10 and Figure R-11. Hydrology and Water Chemistry Assimilation The hydrology data and phosphorus and nitrogen data was combined to estimate loss of SRP, total P and nitrate from plots for periods of time where the hydrology and chemistry data were considered to be adequate to calculate flux (i.e. no problems with tipping buckets, and no problems with overflow of nutrient-solution collectors). Early problems with hydrology preclude the use of some data for hydrology (as indicated in Table M-1), and all storms were not adequately sampled for chemistry. Collection periods for which adequate data are available includes the collection periods from May 15-16, May 25-26, May 30-June 3, and June 6-10. Data were merged by applying the concentration of the solution (in mg/liter) collected by the runoff volume (in liters) for surface and subsurface collectors for each 15-minute increment of time. The amount of nutrient that is lost from the plot in this runoff was then summed and plotted over time. Since there were problems with estimating surface vs. subsurface runoff in volumes, and solution collection was volume-weighted, no separation of nutrient loss from surface vs. subsurface runoff was attempted. The estimated nutrient production is thus mg per plot, and these units are used in Figure R-12 to R-15. May 15-16 Sampling Period. The data from the May 15-16 sampling period shows that following establishment of plots 5 and 6 to turfgrass during the winter and spring of 1994-1995, the nutrient output is quite low (Figure R-12). For instance, for a 30 hour period starting 8:00 AM on May 15, 1995, only 25 mg of SRP, 493 mg of total P, and 959 mg of nitrate were lost as runoff from plot 5 (unamended Alderwood soil 2), and 320 mg of SRP, 684 mg of total P, and 780 mg of nitrate were lost as runoff from plot 6 (2:1 GroCo compost:Alderwood soil 2), despite the 1.8 in of rainfall applied to the sites, and the large production of runoff (Figure R3a and R-3b). In these events, the SRP is almost 10 times as high for the compost-amended vs. unamended, but the total P is comparable. This may indicate that much of the P from the control site is particulate (it was noted that control sites had higher suspended matter), while from the compost site it is soluble. These total amounts of P are relatively small compared to runoff from the events following fertilization of the plots. Effect of Compost on P Runoff Final Report page 15 May 25-26 Sampling Period. The effect of the May 25 fertilization is readily apparent in the measured runoff for the May 25-26 event (Figure R-13). Note that the runoff production scale for these events is nearly 20 times that of the May 15-16 sampling event. A total of 5,200 mg vs. 1,900 mg of SRP was produced from the unamended plot 5 compared to the compost-amended plot 6 (Figure R-13). A total of 12,600 mg vs. 3,200 mg of total P was produced from the unamended plot 5 compared to the compost-amended plot 6 (Figure R-13). A total of 17,500 mg of total P was added with the amendment of May 15, so this represents over 72% of the original fertilizer amendment running off with the first storm on plot 5. Thus, it appears that the unamended plot has very little ability to retain fertilizer P during an intense storm event. Less obvious is the reason why the unamended plot 6 also increased P production. This increase was much less than that seen in plot 5. Bruce Jensen offered some insight into a possible reason when he noted that semi-wild Canada geese living in the area seem to love eating grass on the compostamended plots, while ignoring the unamended plots. During these feedings they also leave a considerable amount of droppings, which probably have high amounts of soluble inorganic nutrients associated with them. Unfortunately, these factors make the comparisons of these sites suspect. An additional explanation that may be likely is the increased mineralization of organic matter as the weather warms and organic matter decomposition rates (that release mineral P) increase. The runoff of nitrate was almost identical for site 5 vs. site 6 (Figure R-13), with 2,052 mg for site 5 vs. 2,219 mg for site 6 produced during the storm events. Nearly 160,000 mg of N was added with the fertilization amendment, but there does not appear to be a significant effect of this amendment on nitrate. Thought the fertilizer was not analyzed and no comparison of ammonium vs. nitrate was given, it is likely that most of the nitrogen was in an ammonium form. This could have been produced in the runoff in high concentrations. Since there was no NH4 analysis done on the samples, it is unknown if this actually did occur. May 30-June 3 Sampling Period. Samples were collected over longer periods of time starting at the end of May (Figure R-14). Sampling was conducted during a 120 hour period starting 8:00 AM on May 31, 1995 on 1 (unamended Alderwood soil 1) plot 2 (2:1 Cedar Grove fine compost:Alderwood soil 1). A total of 392 mg of SRP, 1405 mg of total P, and 1209 mg of nitrate were lost as runoff from plot 1, while 466 mg of SRP, 849 mg of total P, and 1184 mg of nitrate were lost as runoff from plot 2. Note that an increasing amount of the P in the unamended plot is insoluble, and probably of the particulate form. The data from this sampling period shows the nutrient P concentrations and total runoff following the fertilization event are dropping quickly in the control plot. Remember that 72% of the total P was lost during the first 30 hours following fertilization during the May 25-26 Effect of Compost on P Runoff Final Report page 16 simulated storms, so there may not be much of the original P left in these sites. In the case of plot 6, the geese were still visiting the site during this time, and this may affect the results due to their droppings, which contain high amounts of P. June 3-10 Sampling Period. A long-term collection of runoff was conducted from June 3-10 (Figure R-15). Sampling was conducted during a 180 hour period starting 10:00 AM on June 3, 1995 on plot 1 (unamended Alderwood soil 1), and plot 2 (2:1 Cedar Grove fine compost:Alderwood soil 1). A total of 40 mg of SRP, 94 mg of total P, and 468 mg of nitrate were lost as runoff from plot 1, while 42 mg of SRP, 61 mg of total P, and 386 mg of nitrate were lost as runoff from plot 2. Most of the production of P and N from the compost-amended plot was during periods well after the artificial storm events, whereas most of the nutrient production from the unamended plot was during or immediately following the storm event. These data show that nutrient production has dropped considerably compared to the storms of May. For the control plot which received an additional fertilizer amendment after establishment, this would point at the loss of soluble P due to loss and adsorption following the fertilizer addition. It is uncertain why the production is lowering in the compost-amended plots, but it may be due to an increasing demand for available nutrients by the rapidly growing grass in a system that is now more depleted of available nutrients. Unfortunately, the high amount of varibility and lack of suitable replication of plots in this study make conclusions difficult. It should be noted that the artificial storms utilized in these studies represent intense rainfall events of 25-100 year return intervals. It would be expected that the differences between the tillonly soil and the compost-amended till soil would be greater at less-intense rainfall events, though the peak rates of runoff of both are likely to be reduced. SUMMARY AND CONCLUSIONS Summary of Results Nutrient production from sites was highly variable, but following intense leaching during the winter of 1994 and spring of 1995, concentrations and total runoff of P was slightly higher from compost-amended sites. Nitrate concentrations and runoff were about the same. However, there was insufficient grass growth in unamended sites, even following an establishment fertilization, so an additional fertilizer addition was made. The compost-fertilized site was very attractive and needed no fertilization. In fact, the initial establishment fertilization probably wasn’t necessary either based on studies of turfgrass growth in compost-amended soils without inorganic fertilization at the University of Washington on similar soils. Following the fertilizer addition in Effect of Compost on P Runoff Final Report page 17 the control plots, 72% of the P fertilizer added immediately ran off the site during the first storm following fertilization, resulting in a 200-fold increase in P runoff with a single storm. The fertilizer did seem to increase the rate of grass growth, and nutrient concentrations rapidly decreased over time in the control sites. The limited results available from these studies point out the necessity of conducting a field study that incorporates sufficient repetitions, time, and fertilization regimes that establish similar turfgrass. Unfortunately, a lot of effort was spent on development of methods of conducting this study, since none like has been conducted previously. The results of these studies clearly show that compost amendment alters soil properties known to affect water relations of soils, including the water holding capacity, porosity, bulk density, and structure, as well as increasing soil C and N, and probably other nutrients as well. Results also show that compost amendments affect water runoff patterns during and following storm events, and runoff of nutrients from unamended vs. amended sites. In all cases, compost amendment increased the lag time of response of a soil runoff hydrograph to a storm event, increased the time to peak flow, decreased the rapidity of drop of the hydrograph following cessation of the storm event, and increased the "base flow" in the period following the storm event. The amendment increased the peak storage and field capacity of plots nearly 100%, and reduced the total runoff depending on the intensity and duration of the storm event (i.e. small storms = little or no runoff; large storms = almost complete runoff). Following one storm with another showed that antecedent conditions were very important in determining total runoff from a particular storm event. These observations were true of both the Cedar Grove and GroCo amendments. However, the GroCo:soil 2 combination appeared to have a much higher water holding capacity than the Cedar Grove:soil 1 mixture. This is probably due to the fact that the GroCo is made with biosolids, and contains much more finely divided and decomposed organic matter as well as flocculants designed to precipitate suspended material from water during the water treatment process. GroCo amendment also had a more pronounced effect on increasing lag times and base flows. Implications of Results Nutrient runoff was affected by compost amendment, but primarily from the lowering of total runoff amounts and not due to lowering of nutrient concentrations in runoff. Compost-amended turfgrass was uniformly beautiful, and required little or no fertilization, which is a definite positive aspect of compost amendment. The poor quality of the unamended plots would likely have resulted in addition nutrient application, and when we did this, almost all of the P fertilizer ran off with the next storm event. This resulted in much more nutrient runoff from sites not Effect of Compost on P Runoff Final Report page 18 amended with compost compared to compost-amended sites. This may actually be the biggest benefit of compost amendment...lack of need for further lawn fertilization. Application of compost material similar to that in this study would be possible by applying 4 inches of compost onto the surface of an Alderwood soil and tilling to a total depth of 12 inches, including the compost amendment (8 inches into the soil). This mixing would probably need to be thorough and deep to achieve the conditions of this study, and this is not likely to be possible with most existing equipment. However, if the compost is well incorporated into the soil, most of the benefits of amendment seen in this study would likely be seen from a field application. The results of this study clearly show that compost amendment is likely an effective means of decreasing peak flows from all but the most severe storm events following very wet antecedent conditions. An added benefit of amendments is an increased base flow in antecedent conditions following storm events. The increases in water holding capacity with compost amendment shows that storms up to 0.8 inches total rainfall would be well buffered in amended soils and not result in significant peak flows, whereas without the amendment a storm about 0.4 inches total rainfall would be similarly buffered. If a significant percentage of till soils disturbed were amended with compost in this manner, it would have this positive effect on hydrology. The absolute amount depends on many factors, but it is clear that compost amendment is an excellent means of retaining runoff on-site and reducing the rate of runoff from all but the most intense storm events. The effect of compost amendment on total runoff amounts during the wettest parts of the winter would likely be minimal on these Alderwood soils since there is very little transpiration during the winter. However, during the early fall and late spring seasons, the additional water-holding capacity of the compost-amended soils would result in additional transpiration from the plots and possibly lowered need for irrigation. Despite the lack of probable effect on total runoff during the winter season, the effect on storm peak flows would clearly be beneficial. Future Directions The resources of this study were largely consumed figuring out how to get these sampling systems to work. Although there will always be similar problems in such studies, a lot more stands to be gained from additional work on the CUH sites. For instance, a range of mediumintensity simulated storms needs to be run, and longer-term evaluations could be made since all plots are likely to change in chemistry and structure over time. Two critical questions need to be answered: 1) Is the compost amendment permanent? Effect of Compost on P Runoff Final Report page 19 2) Will the properties of the unamended site improve with time? If these question could be answered utilizing these sites, the long-term effect of the amendment could be evaluated. In addition, a series of field trials would ideally be created, with the area of compost-amended vs. unamended evaluated from runoff into a small catchment. Whether or not such a site exists is not easily answered here, but such a test of the utilization of compost would be the ideal means to test its effect on runoff quantity and quality. Ideally, any future study would include a turf established with other common commercially-utilized methods, such as the practice of placing sod directly onto glacial till soil. Effect of Compost on P Runoff Final Report page 20 Table M-1. Storm S imulation Summary characteris tics† Start date Plots studied Start time 1&2 1&2 930 930 duration –– h –– 8 8 1&2 1&2 900 1430 1.5 2 0.95 0.89 0.63 0.45 Plot 1 bucket overflowed May 13 1&2 900 3 1.42 0.47 Natural storm on previous day May 16 May 17 5&6 5&6 930 1000 3 2 1.04 0.76 0.35 0.38 Gutters covered Gutters covered May 25 May 26 5&6 5&6 1200 1200 6 6 2.06 2.03 0.34 0.34 Gutters covered Gutters covered § May 28 1&2 900 6 1.90 0.32 Buckets stuck on both plots!!! Gutters covered § May 30 § May 31 1&2 1&2 1000 1000 6 6 1.85 1.87 0.31 0.31 Plot 1 bucket stuck??? Gutters covered June 9 1&2 1000 3 April 26 April 27 § May 5 § May 6 Average depth Rate Comments¥ –– in –– –– in/h –– 2.46 0.31 2.33 0.29 Gutters covered † data from Kyle Kolsti, UW Center for Urban Water Res ources ¥ hydrology data highlighted in italics had one or more problems and was deleted from consideration in the hydrology results section § storm data not analyzed due to problems noted in "Comments" Effect of Compost on P Runoff Final Report page 21 Table M-2. Summary of Run Collection Times Field Run 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 Collector placed On 03/07/95--10:30 04/25/95--09:00 04/27/95--10:00 05/01/95--10:18 05/04/95--09:30 05/08/95--09:30 05/12/95--09:00 05/15/95--09:00 05/15/95--12:45 05/15/95--13:15 05/16/95--10:14 05/16/95--12:15 05/16/95--12:30 05/16/95--13:00 05/24/95--12:05 05/25/95--11:45 05/25/95--15:30 05/25/95--18:06 05/25/95--18:21 05/26/95--21:15 05/26/95--21:30 05/27/95--09:00 05/27/95--12:20 05/27/95--15:15 05/27/95--15:46 05/27/95--21:10 05/31/95--10:00 05/31/95--16:30 05/27/95--21:10 05/31/95--10:00 05/31/95--16:30 06/03/95--10:10 06/06/95--19:52 06/09/95--10:00 06/09/95--20:10 06/09/95--10:00 Collector taken Off 03/15/95--09:00 04/26/95--09:00 04/28/95--11:00 05/03/95--18:00 05/08/95--09:30 05/12/95--09:00 05/15/95--09:00 05/15/95--12:45 05/15/95--13:15 05/16/95--10:10 05/16/95--12:15 05/16/95--12:30 05/16/95--13:00 05/24/95--12:00 05/25/95--11:30 05/25/95--15:20 05/25/95--18:06 05/25/95--18:21 05/26/95--21:15 05/26/95--21:30 06/03/95--10:10 05/27/95--12:20 05/27/95--15:15 05/27/95--15:46 05/27/95--21:10 05/31/95--09:55 05/31/95--16:30 06/03/95--10:10 05/31/95--09:55 05/31/95--16:30 06/03/95--10:10 06/06/95--19:52 06/09/95--10:00 06/09/95--20:10 06/10/95--20:16 06/10/95--20:16 Sampling duration (hours) 191 24.0 25.0 56 96 95 72 3.8 0.5 20.9 2.0 0.3 0.5 191 23.4 3.6 2.6 0.2 26.9 0.3 181 3.3 2.9 0.5 5.4 85 6.5 66 85 6.5 66 82 62 10.2 24.1 34.3 Effect of Compost on P Runoff Final Report Table R-1. Hydrological characteristics of s imulated rainfall hydrologic characteristic total input rainfall rate runoff > 0.01 in/hour runoff > 0.1 in/hour runoff rate > 90% input rate runoff < 10% of input rate† runoff < 0.01 in/hour total input rainfall rate runoff > 0.01 in/hour runoff > 0.1 in/hour runoff rate > 90% input rate runoff < 10% of input rate† runoff < 0.01 in/hour additional control compost lag with unamended amended compost ––––––––– simulation 1, storm 1 ––––––––– 2.33 in 2.46 in 0.28 in/h 0.30 in/h 0.50 h 1.00 h 0.50 h 0.75 h 1.75 h 1.00 h 2.00 h 5.25 h 3.25 h 0.75 h 1.50 h 0.75 h 1.75 h 6.50 h 4.75 h ––––––––– simulation 1, storm 2 ––––––––– 2.09 in 2.29 in 0.26 in/h 0.29 in/h 0.25 h 0.50 h 0.25 h 0.50 h 1.00 h 0.50 h 0.75 h 1.25 h 0.50 h 0.75 h 1.50 h 0.75 h 1.75 h >2.00 h page 22 Effect of Compost on P Runoff Final Report page 23 Table R-2. Summary statis tics for solution chemis try analyses Treatment average (treated and control) analyzed in laboratory total Acid reactive digested Total NitrateP P P nitrogen SRP ACP TP NO3-N derived measures Occluded Organic P P (ACP-TP) (TP-ACP) OCP OP –––––––––––––––– average concentration (mg/l) ––––––––––––––––––– 1.14 1.51 2.29 1.54 0.24 1.06 control unamended compost amended 1.19 1.09 1.56 1.46 2.54 2.05 1.39 1.68 0.25 0.22 1.29 0.85 control unamended lower compost amended lower 1.04 1.22 1.22 1.59 2.07 2.43 1.57 1.75 0.13 0.24 0.99 1.11 control unamended upper compost amended upper 1.40 0.91 2.06 1.25 3.17 1.53 1.16 1.57 0.43 0.19 1.71 0.45 Effect of Compost on P Runoff Final Report page 24 Figure M-1. University of Washington Center for Urban Water Resources compost amendment research site layout. 32' 8' control soil 1 2:1 CG fine soil 1 weather station 2:1 CG coarse soil 1 4:1 CG fine soil 1 control soil 2 2:1 GroCo soil 2 3:1 CG fine soil 2 Detail of Soil Sampling Scheme 3 1 2 4 4' 5 6 7 8 1' 2' 2' 8' 5' 16' 9' Effect of Compost on P Runoff Final Report page 25 Interval flows (liters/hour) 160 120 Plot 1 Control unamended 80 40 0 0 5 10 -40 15 20 Hours from start of event 25 30 35 25 30 35 Interval flows (liters/hour) 200 160 120 Plot 2 Compost amended 80 40 0 -40 0 5 10 15 20 Hours from start of event start 8:30 AM April 25, 1995 Figure R-1a. Comparison of intervals of rainfall, runoff, s urface flow, s ubsurface flow and s torage volumes for plot 1 (control) and 2 (amended) for sequential rainfall events s tarting April 25, 1995. Rainfall Runoff Surface flow Subsurface flow Storage Effect of Compost on P Runoff Final Report page 26 Water balance for storm event Rainfall unamended amended –––––– liters –––––– total liters per plot 2,780 2,997 percent runoff percent retention inches storm event 4.60 4.96 inches runoff inches retention Runoff unamended amended –––––– liters –––––– 2,491 2,658 90 89 10 11 4.12 0.48 4.40 0.56 3000 total rainfall control unamended compost-amended 2500 Total flux (liters) 2000 1500 1000 total runoff control unamended compost-amended 500 0 Hours from start of event Total storage (liters) 600 500 compost-amended 400 300 control unamended 200 rainfall storage control unamended compost-amended 100 0 0 start 8:30 AM April 25, 1995 5 10 15 20 Hours from start of event 25 30 Figure R-1b. Comparison of total rainfall input, cumulative runoff, and net storage for plot 1 (control) and 2 (amended) for sequential rainfall events starting April 25, 1995. 35 Effect of Compost on P Runoff Final Report page 27 160 140 Interval flows (liters/hour) 120 100 80 Plot 1 Control unamended 60 40 20 0 0 5 10 Hours from start of event 15 20 25 15 20 25 Interval flows (liters/hour) 120 100 80 60 Plot 2 Compost amended 40 20 0 -20 0 5 -40 10 Hours from start of event -60 start 2:00 PM May 11, 1995 Figure R-2a. Comparison of intervals of rainfall, runoff, s urface flow, s ubsurface flow and s torage volumes for plot 1 (control) and 2 (amended) for rainfall event starting May 11, 1995. Rainfall Runoff Surface flow Subsurface flow Storage Effect of Compost on P Runoff Final Report page 28 Water balance for storm event Rainfall unamended amended –––––– liters –––––– total liters per plot 1,081 1,081 percent runoff percent retention inches storm event 1.79 1.79 inches runoff inches retention Runoff unamended amended –––––– liters –––––– 740 639 68 59 32 41 1.22 0.56 1.06 0.73 1200 total rainfall control unamended and compost-amended Total flux (liters) 1000 800 600 total runoff control unamended compost-amended 400 200 0 0 5 10 15 Hours from start of event 20 25 Total storage (liters) 600 500 400 300 rainfall storage control unamended compost-amended 200 100 0 0 5 10 15 20 start 2:00 PM Hours from start of event May 11, 1995 Figure R-2b. Comparison of total rainfall input, cumulative runoff, and net storage for plot 1 (control) and 2 (amended) for sequential rainfall events starting May 11, 1995. 25 Effect of Compost on P Runoff Final Report page 29 Interval flows (liters/hour) 50.0 40.0 30.0 20.0 Plot 5 Control unamended 10.0 0.0 0 5 10 15 20 25 30 20 25 30 Hours from start of event Interval flows (liters/hour) 50.0 40.0 30.0 20.0 Plot 6 Compost amended 10.0 0.0 0 5 start 8:00 AM May 15, 1995 10 15 Hours from start of event Figure R-3a. Comparison of intervals of rainfall, runoff, s urface flow, s ubsurface flow and s torage volumes for plot 5 (control) and 6 (amended) for rainfall event starting May 15, 1995. Rainfall Runoff Surface flow Subsurface flow Storage Effect of Compost on P Runoff Final Report page 30 Water balance for storm event Rainfall unamended amended –––––– liters –––––– total liters per plot 1,041 1,081 percent runoff percent retention inches storm event 1.72 1.79 inches runoff inches retention Runoff unamended amended –––––– liters –––––– 798 347 77 32 23 68 1.32 0.40 0.57 1.22 1200 total rainfall control unamended and compost-amended 1000 Total flux (liters) 800 total runoff control unamended compost-amended 600 400 200 0 0 5 10 15 Hours from start of event 20 25 30 800 Total storage (liters) 700 600 500 rainfall storage control unamended compost-amended 400 300 200 100 0 0 5 10 15 20 25 start 8:00 AM Hours from start of event May 15, 1995 Figure R-3b. Comparison of total rainfall input, cumulative runoff, and net storage for plot 5 (control) and 6 (amended) for sequential rainfall events starting May 15, 1995. 30 Effect of Compost on P Runoff Final Report page 31 Interval flows (liters/hour) 50.0 40.0 30.0 Plot 5 Control unamended 20.0 10.0 0.0 0 5 10 Interval flows (liters/hour) -10.0 15 20 Hours from start of event 25 30 35 40 25 30 35 40 50.0 40.0 30.0 Plot 6 Compost amended 20.0 10.0 0.0 -10.0 0 5 start 11:00 AM May 25, 1995 10 15 20 Hours from start of event Figure R-4a. Comparison of intervals of rainfall, runoff, surface flow, subs urface flow and storage volumes for plot 5 (control) and 6 (amended) for rainfall event starting May 25, 1995. Rainfall Runoff Surface flow Subsurface flow Storage Effect of Compost on P Runoff Final Report page 32 Water balance for storm event Rainfall unamended amended –––––– liters –––––– total liters per plot 2,432 2,432 percent runoff percent retention inches storm event 4.03 4.03 inches runoff inches retention Runoff unamended amended –––––– liters –––––– 1,749 1,214 72 50 28 50 2.90 1.13 2.01 2.02 2500 total rainfall control unamended and compost-amended Total flux (liters) 2000 1500 1000 total runoff control unamended compost-amended 500 0 0 5 10 15 20 Hours from start of event 25 30 35 40 0 5 10 15 20 25 30 35 start 11:00 AM Hours from start of event May 25, 1995 Figure R-4b. Comparison of total rainfall input, cumulative runoff, and net storage for plot 5 (control) and 6 (amended) for sequential rainfall events starting May 25, 1995. 40 Total storage (liters) 1400 1200 1000 rainfall s torage control unamended compost-amended 800 600 400 200 0 Effect of Compost on P Runoff Final Report page 33 20 Total P concentration (mg/L) 15 10 Treatments 5 Plot 1 control unamended surface subsurface Plot 2 compost amended surface subsurface 0 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 Event number (see Table R-1 for s ampling durations). Figure R-5. Total P concentration of plot 1 (control unamended) and plot 2 (compost-amended). 30 32 34 36 Effect of Compost on P Runoff Final Report page 34 20 Total P concentration (mg/L) 15 Treatments 10 Plot 1 control unamended surface subsurface Plot 2 compost amended surface subsurface 5 0 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 Event number (s ee Table R-1 for sampling durations). Figure R-6. Total P concentration following fertilization of plot 1 (control unamended) and plot 2 (compost-amended). 36 Effect of Compost on P Runoff Final Report page 35 25 plots 1 & 5 fertilized Total P concentration (mg/L) 20 15 Treatments Plot 5 control unamended surface subsurface Plot 6 compost amended surface subsurface 10 5 0 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 Event number (see Table R-1 for s ampling durations). Figure R-7. Total P concentration of plot 5 (control unamended) and plot 6 (compost-amended). Effect of Compost on P Runoff Final Report page 8 6 Soluble Reactive Phosphate (mg/L) Treatments 4 Plot 1 control unamended surface Plot 2 compost amended surface subsurface subsurface 2 plots 1 & 5 fertilized 0 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 Event number (s ee Table R-1 for sampling durations). Figure R-8. Soluble reactive phosphate concentration of plot 1 (control unamended) and plot 2 (compost-amended). 36 Effect of Compost on P Runoff Final Report page 37 8 Soluble Reactive Phosphate (mg/L) plots 1 & 5 fertilized Treatments Plot 5 control unamended surface Plot 6 compost amended surface 6 subsurface subsurface 4 2 0 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 Event number (see Table R-1 for s ampling durations). Figure R-9. Soluble reactive phos phate concentration of plot 5 (control unamended) and plot 6 (compost-amended). Effect of Compost on P Runoff Final Report page 10 Total NO3-N concentration (mg/L) 9 8 7 Treatments 6 Plot 1 control unamended surface subsurface 5 Plot 2 compost amended surface subsurface 4 3 2 plots 1 & 5 fertilized 1 0 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 Event number (see Table R-1 for s ampling durations). Figure R-10. Total NO3-N concentration following fertilization of plot 1 (control unamended) and plot 2 (compos t-amended). 38 Effect of Compost on P Runoff Final Report 6 Total NO3-N concentration (mg/L) 5 4 page 39 plots 1 & 5 fertilized Treatments Plot 5 control unamended surface Plot 6 compost amended surface subsurface subsurface 3 2 1 0 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 Event number (s ee Table R-1 for sampling durations). Figure R-11. Total NO3-N concentration following fertilization of plot 5 (control unamended) and plot 6 (compost-amended). Soluble Phosphate flux (mg per plot) Effect of Compost on P Runoff Final Report 350 300 250 200 150 100 50 0 Total Phosphorus flux (mg per plot) 0 start 8:00 AM May 15, 1995 Nitrate-N flux (mg per plot) 320 till soil only till with compost amendment 25 5 10 20 25 30 684 till soil only till with compost amendment 493 5 10 15 20 25 30 Time from start of first storm event (hours) 959 1000 900 800 700 600 500 400 300 200 100 0 0 start 8:00 AM May 15, 1995 15 Time from start of first storm event (hours) 700 600 500 400 300 200 100 0 0 start 8:00 AM May 15, 1995 page 40 till soil only till with compost amendment 780 5 10 15 20 25 30 Time from start of first storm event (hours) Figure R-12. Measured runoff of total P, SRP and NO3-N from May 1516 storm s imulation for plots 5 and 6 Effect of Compost on P Runoff Final Report page 41 Soluble Phosphate flux (mg per plot) 6000 5,189 5000 till soil only till with compost amendment 4000 3000 2000 1,880 1000 0 0 5 Total Phosphorus flux (mg per plot) start 11:00 AM May 25, 1995 10 15 20 25 30 35 40 Time from start of first storm event (hours) 14000 12000 12,657 till soil only till with compost amendment 10000 8000 6000 4000 2000 3,257 0 0 start 11:00 AM May 25, 1995 5 10 15 20 25 30 Nitrate-N flux (mg per plot) 40 Time from start of first storm event (hours) 2500 2000 35 2,219 till soil only till with compost amendment 2,052 1500 1000 500 0 0 5 start 11:00 AM May 25, 1995 10 15 20 25 30 35 Time from start of first storm event (hours) Figure R-13. Measured runoff of total P, SRP and NO3-N from May 2526 storm simulation for plots 5 and 6 40 Soluble Phosphate flux (mg per plot) Effect of Compost on P Runoff Final Report 466 500 450 400 350 300 250 200 150 100 50 0 392 till soil only till with compost amendment Total Phosphorus flux (mg per plot) 0 20 40 60 1600 1400 1200 1000 800 600 400 200 0 80 100 120 1405 849 till soil only till with compost amendment 0 start 8:00 AM May 31, 1995 Nitrate-N flux (mg per plot) page 42 20 40 60 80 100 Time from start of first storm event (hours) 1400 1200 1000 800 600 400 200 0 120 1209 1184 till soil only till with compost amendment 0 start 8:00 AM May 31, 1995 20 40 60 80 100 120 Time from start of first storm event (hours) Figure R-14. Measured runoff of total P, SRP and NO3-N from May 30June 3 storm simulation for plots 1 and 2. Soluble Phosphate flux (mg per plot) Effect of Compost on P Runoff Final Report 42 45 40 35 30 25 20 15 10 5 0 0 20 start 10:00 AM June 3, 1995 40 Total Phosphorus flux (mg per plot) Nitrate-N flux (mg per plot) 60 80 100 120 140 160 180 Time from start of first storm event (hours) 94 till soil only till with compost amendment 61 40 60 80 100 120 140 160 180 Time from start of first storm event (hours) 500 450 400 350 300 250 200 150 100 50 0 0 20 start 10:00 AM June 3, 1995 40 till soil only till with compost amendment 100 90 80 70 60 50 40 30 20 10 0 0 20 start 10:00 AM June 3, 1995 page 43 468 till soil only till with compost amendment 40 60 80 100 386 120 140 160 Time from start of first storm event (hours) Figure R-15. Measured runoff of total P, S RP and NO3-N from June 6-10 storm simulation for plots 1 and 2 180 Effect of Compost on P Runoff Final Report page 44 Appendix 1a. Summary of soil analysis data for field plots. Sampled August, 1994. (note that samples for the August analysis were taken according to Figure M-1 sampling scheme). Sampled in August, 1994 Plot and rep Plot 1, rep 1 Plot 1, rep 2 Plot 1, rep 3 Plot 1, rep 4 Plot 1, rep 5 Plot 1, rep 6 Plot 1, rep 7 Plot 1, rep 8 Plot 2, rep 1 Plot 2, rep 2 Plot 2, rep 3 Plot 2, rep 4 Plot 2, rep 5 Plot 2, rep 6 Plot 2, rep 7 Plot 2, rep 8 amended average no compost average total total C N % by weight 0.2 0.12 0.3 0.14 0.3 0.13 0.3 0.15 0.2 0.12 0.3 0.10 0.5 0.12 0.2 0.11 2.2 0.26 2.6 0.27 3.4 0.28 2.7 0.25 2.8 0.24 2.0 0.22 2.5 0.30 4.5 0.36 2.8 0.27 0.3 0.12 Field Field Capacity Capacity Total g/g ml/ml Porosity % % % 20 28 48 18 22 52 18 21 56 18 24 42 16 20 49 16 22 46 16 20 52 28 35 50 37 41 47 39 39 56 34 33 52 32 36 49 33 37 47 32 35 53 46 49 48 27 30 44 35 37 50 19 24 49 Particle Size Analysis Bulk Density g/cm3 1.37 1.22 1.15 1.38 1.28 1.35 1.23 1.26 1.12 0.98 0.95 1.14 1.14 1.07 1.06 1.14 1.08 1.28 Particle Density g/cm3 2.63 2.54 2.64 2.39 2.53 2.50 2.54 2.54 2.12 2.23 1.97 2.25 2.13 2.29 2.03 2.05 2.13 2.54 < 2mm parts percentage 2-0.02 0.02-0.005 0.005-0.002 <.002 % % % % 76.3 12.5 1.3 10.0 76.3 11.3 3.8 8.8 76.3 12.5 1.3 10.0 75.0 13.8 3.8 7.5 76.3 13.8 2.5 7.5 76.3 13.8 1.3 8.8 76.3 13.8 1.3 8.8 76.3 12.5 1.3 10.0 73.8 12.5 6.3 7.5 77.5 10.0 5.0 7.5 77.5 10.0 5.0 7.5 77.5 10.0 5.0 7.5 77.5 10.0 5.0 7.5 73.8 12.5 6.3 7.5 76.3 10.0 6.3 7.5 73.8 12.5 6.3 7.5 75.9 10.9 5.6 7.5 76.1 13.0 2.0 8.9 soil structure by visual and feel method single grain / weak granular single grain / weak granular single grain / weak granular single grain / weak granular single grain / weak granular single grain / weak granular single grain / weak granular single grain / weak granular single grain / weak granular single grain / weak granular single grain / weak granular single grain / weak granular single grain / weak granular single grain / weak granular single grain / weak granular single grain / weak granular Effect of Compost on P Runoff Final Report page 45 Appendix 1b. Summary of soil analysis data for field plots. Sampled December, 1994. Caution: sampling of these sites was done under less than ideal conditions when the soils was highly saturated. This could easily lead to compaction of these sandy-textured soils when sampling for bulk density and affect any porosity-related analysis Sampled December 13, 1994 Sample designation plot 1 BD, control plot 2 BD, CGfine2:1 plot 3 BD, CGcoarse2:1 plot 3 Grab, CGcoarse2:1 plot 4 Grab, CGfine4:1 plot 5 Grab, control plot 6 Grab, Groco2:1 plot 7 Grab, CGfine3:1 amended average no compost average total C % 0.2 3.1 3.0 3.1 1.8 0.1 1.2 2.2 2.4 0.2 total N % 0.02 0.20 0.23 0.23 0.13 0.05 0.06 0.16 0.17 0.04 Field Field Capacity Capacity Total g/g ml/ml Porosity % % % 19 41 38 46 24 29 35 34 35 39 29 19 Particle Size Analysis Bulk Density g/cm3 1.97 1.16 1.45 1.30 1.97 Particle Density g/cm3 2.33 1.99 2.05 2.02 2.33 < 2mm parts percentage 2-0.02 0.02-0.005 0.005-0.002 <.002 % % % % 82 72 82 78 79 82 78 9 18 12 15 15 12 14 2 7 3 4 5 3 5 7 3 3 3 1 3 4 soil structure by visual and feel method single grain / weak granular single grain / weak granular single grain / weak granular single grain / weak granular single grain / weak granular single grain / weak granular single grain / weak granular single grain / weak granular Effect of Compost on P Runoff Final Report page 46 Appendix 2. Laboratory analyses for water samples analyzed in the study. Sample 1-L-0 1-L-1 1-L-2 1-L-3 1-L-4 1-L-5 1-L-6 1-L-7 1-L-22 1-L-23 1-L-24 1-L-25 1-L-27 1-L-28 1-L-30 1-L-31 1-L-32 1-L-33 1-L-36 1-U-1 1-U-2 1-U-3 1-U-4 1-U-5 1-U-6 field upper (U) plot lower (L) run† 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 L L L L L L L L L L L L L L L L L L L U U U U U U 0 1 2 3 4 5 6 7 22 23 24 25 27 28 30 31 32 33 36 1 2 3 4 5 6 Date analysis reported 3/10/95 3/27/95 5/3/95 5/3/95 5/3/95 5/15/95 5/15/95 5/15/95 6/9/95 6/9/95 6/9/95 6/9/95 6/9/95 6/9/95 6/9/95 6/9/95 6/9/95 6/12/95 6/12/95 3/27/95 5/3/95 5/3/95 5/3/95 5/15/95 5/15/95 analyzed in laboratory derived measures total Acid Occluded Organic reactive digested Total NitrateP P P P P nitrogen Ac-P - TR-P T-P - Ac-P TR-P Ac-P T-P NO3-N Oc-P Or-P ––––––––––––––––––––––––––––– mg/L ––––––––––––––––––––––––––––––––––––––––– 0.48 0.51 0.75 n.d. 0.03 0.24 0.06 0.07 0.23 n.d. 0.00 0.16 0.07 i.s. 0.07 n.d. i.s. i.s. 0.03 i.s. 0.07 n.d. i.s. i.s. 0.06 i.s. 0.11 n.d. i.s. i.s. 0.06 0.19 0.80 0.79 0.12 0.62 0.03 0.06 0.15 1.00 0.03 0.10 0.03 0.06 0.10 0.81 0.03 0.04 7.02 7.11 18.02 1.30 0.09 10.91 3.61 3.81 4.49 1.43 0.20 0.68 2.49 2.71 3.42 1.18 0.22 0.71 0.61 0.83 1.17 1.40 0.23 0.33 3.12 3.57 4.53 1.09 0.45 0.96 0.22 0.35 0.37 1.07 0.12 0.02 0.08 0.14 0.21 2.39 0.06 0.07 0.07 0.36 0.53 9.14 0.28 0.17 0.13 0.16 0.35 0.52 0.03 0.19 0.12 0.13 0.24 4.35 0.01 0.11 0.14 0.17 0.30 2.42 0.03 0.13 i.s. i.s. 0.76 n.d. i.s. i.s. 0.03 i.s. 0.22 n.d. i.s. i.s. 0.08 i.s. 0.42 n.d. i.s. i.s. 0.05 i.s. 0.38 n.d. i.s. i.s. 0.06 0.08 0.19 0.81 0.02 0.11 0.11 0.12 0.29 0.81 0.01 0.17 Effect of Compost on P Runoff Final Report page 47 Appendix 2. Laboratory analyses for water samples analyzed in the study. Sample 1-U-7 1-U-22 1-U-23 1-U-24 1-U-27 1-U-28 1-U-30.31 1-U-32 1-U-33 1-U-36 2-L-1 2-L-2 2-L-3 2-L-4 2-L-5 2-L-6 2-L-7 2-L-22 2-L-23 2-L-24 2-L-25 2-L-26 2-L-27 2-L-28 2-L-29 field upper (U) plot lower (L) run† 1 1 1 1 1 1 1 1 1 1 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 U U U U U U U U U U L L L L L L L L L L L L L L L 7 22 23 24 27 28 30-31 32 33 36 1 2 3 4 5 6 7 22 23 24 25 26 27 28 29 Date analysis reported 5/15/95 6/9/95 6/9/95 6/9/95 6/9/95 6/9/95 6/9/95 6/9/95 6/12/95 6/12/95 3/27/95 5/3/95 5/3/95 5/3/95 5/15/95 5/15/95 5/15/95 6/9/95 6/9/95 6/9/95 6/9/95 6/9/95 6/9/95 6/9/95 6/9/95 analyzed in laboratory derived measures total Acid Occluded Organic reactive digested Total NitrateP P P P P nitrogen Ac-P - TR-P T-P - Ac-P TR-P Ac-P T-P NO3-N Oc-P Or-P ––––––––––––––––––––––––––––– mg/L ––––––––––––––––––––––––––––––––––––––––– 0.03 0.06 0.23 0.95 0.03 0.17 5.53 5.68 14.24 1.57 0.15 8.57 3.45 4.14 5.69 0.69 0.69 1.55 2.84 3.30 4.06 1.31 0.47 0.75 1.54 1.76 2.33 2.42 0.22 0.57 0.20 1.35 2.03 0.60 1.16 0.68 2.20 2.35 2.87 0.49 0.16 0.52 0.14 0.35 0.40 0.44 0.20 0.05 0.11 0.14 0.26 1.42 0.03 0.12 0.17 0.33 0.44 1.05 0.16 0.11 0.19 0.19 0.57 n.d. 0.01 0.38 0.36 i.s. 0.43 n.d. i.s. i.s. 0.43 i.s. 0.52 n.d. i.s. i.s. 0.48 i.s. 0.53 n.d. i.s. i.s. 0.41 0.43 0.54 0.87 0.02 0.11 0.30 0.38 0.55 0.91 0.08 0.17 0.24 0.45 0.62 1.01 0.21 0.17 1.00 1.25 1.51 1.71 0.25 0.25 0.53 0.75 0.79 1.40 0.23 0.03 0.46 0.67 0.94 1.23 0.22 0.27 0.40 0.55 0.52 0.36 0.75 0.69 0.77 0.55 1.01 0.80 0.83 0.61 1.07 1.84 1.93 0.74 0.35 0.14 0.25 0.19 0.25 0.12 0.06 0.06 Effect of Compost on P Runoff Final Report page 48 Appendix 2. Laboratory analyses for water samples analyzed in the study. Sample 2-L-30 2-L-31 2-L-32 2-L-33 2-L-36 2-U-1 2-U-2 2-U-3 2-U-4 2-U-5 2-U-6 2-U-7 2-U-22 2-U-23 2-U-24 2-U-27 2-U-28 2-U-30.31 2-U-32 2-U-33 2-U-36 3-L-1 3-L-4 3-L-32 3-U-1 field upper (U) plot lower (L) run† 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 3 3 3 3 L L L L L U U U U U U U U U U U U U U U U L L L U 30 31 32 33 36 1 2 3 4 5 6 7 22 23 24 27 28 30-31 32 33 36 1 4 32 1 Date analysis reported 6/9/95 6/9/95 6/9/95 6/12/95 6/12/95 3/27/95 5/3/95 5/3/95 5/3/95 5/15/95 5/15/95 5/15/95 6/9/95 6/9/95 6/9/95 6/9/95 6/9/95 6/9/95 6/9/95 6/12/95 6/12/95 3/27/95 5/3/95 6/9/95 3/27/95 analyzed in laboratory derived measures total Acid Occluded Organic reactive digested Total NitrateP P P P P nitrogen Ac-P - TR-P T-P - Ac-P TR-P Ac-P T-P NO3-N Oc-P Or-P ––––––––––––––––––––––––––––– mg/L ––––––––––––––––––––––––––––––––––––––––– 0.37 0.46 0.60 2.16 0.09 0.14 0.30 0.40 0.51 1.99 0.10 0.11 0.28 0.33 0.46 7.82 0.05 0.14 0.56 0.58 0.62 2.83 0.02 0.04 0.35 0.41 0.46 0.43 0.07 0.05 i.s. i.s. 0.81 n.d. i.s. i.s. 0.45 i.s. 1.11 n.d. i.s. i.s. 0.15 i.s. 0.30 n.d. i.s. i.s. 0.20 i.s. 0.57 n.d. i.s. i.s. 0.24 0.31 0.32 0.89 0.07 0.01 0.03 i.s. 0.26 0.80 i.s. i.s. 0.11 0.21 0.32 0.92 0.11 0.11 2.32 2.79 3.85 1.43 0.47 1.06 0.58 0.73 0.77 1.17 0.15 0.04 0.52 0.69 1.03 1.30 0.17 0.35 1.20 1.40 1.53 1.21 0.20 0.13 0.31 0.52 0.53 0.56 0.20 0.02 0.25 0.33 0.46 0.55 0.08 0.13 n.s. n.s. n.s. n.s. n.s. n.s. 0.64 0.78 0.81 3.64 0.14 0.03 0.35 0.37 0.55 2.24 0.02 0.19 0.59 0.63 0.93 n.d. 0.04 0.31 0.32 i.s. 0.69 n.d. i.s. i.s. 1.04 1.28 1.37 1.03 0.24 0.10 0.54 0.59 1.69 n.d. 0.04 1.10 Effect of Compost on P Runoff Final Report page 49 Appendix 2. Laboratory analyses for water samples analyzed in the study. Sample 3-U-4 3-U-32 5-L-1 5-L-4 5-L-8 5-L-9 5-L-10 5-L-11 5-L-12 5-L-13 5-L-14 5-L-15 5-L-16 5-L-17 5-L-18 5-L-19 5-L-20 5-L-32 5-L-34 5-L-35 5-U-1 5-U-4 5-U-8 5-U-11.14 5-U-15 field upper (U) plot lower (L) run† 3 3 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 U U L L L L L L L L L L L L L L L L L L U U U U U 4 32 1 4 8 9 10 11 12 13 14 15 16 17 18 19 20 32 34 35 1 4 8 11–14 15 Date analysis reported 5/3/95 6/9/95 3/27/95 5/3/95 5/15/95 5/15/95 5/15/95 5/15/95 5/15/95 5/15/95 5/15/95 6/9/95 6/9/95 6/9/95 6/9/95 6/9/95 6/9/95 6/9/95 6/12/95 6/12/95 3/27/95 5/3/95 5/15/95 5/15/95 6/9/95 analyzed in laboratory derived measures total Acid Occluded Organic reactive digested Total NitrateP P P P P nitrogen Ac-P - TR-P T-P - Ac-P TR-P Ac-P T-P NO3-N Oc-P Or-P ––––––––––––––––––––––––––––– mg/L ––––––––––––––––––––––––––––––––––––––––– 0.59 i.s. 1.76 n.d. i.s. i.s. 0.60 0.63 0.85 ND 0.03 0.22 0.19 0.20 0.44 n.d. 0.01 0.24 2.56 i.s. 3.30 n.d. i.s. i.s. 0.01 0.10 0.27 1.29 0.09 0.17 0.01 0.10 0.41 1.15 0.09 0.31 0.05 0.14 0.89 1.42 0.09 0.75 0.11 0.12 0.28 1.38 0.02 0.16 0.12 0.30 0.43 1.74 0.18 0.14 0.08 0.10 0.83 1.16 0.02 0.73 0.14 0.14 0.81 1.39 0.00 0.66 1.48 1.58 2.60 1.05 0.10 1.02 4.01 4.31 7.08 1.25 0.31 2.77 1.96 2.21 3.01 0.82 0.25 0.80 2.05 2.36 3.51 0.54 0.31 1.15 1.68 1.86 2.53 0.51 0.18 0.68 4.86 5.42 12.86 0.94 0.56 7.44 0.46 0.50 0.69 0.78 0.05 0.19 0.15 0.19 0.33 1.42 0.03 0.14 0.22 0.29 0.33 1.27 0.07 0.04 0.09 0.10 0.36 n.d. 0.01 0.26 0.16 i.s. 0.26 n.d. i.s. i.s. 0.03 0.24 0.66 1.38 0.21 0.43 0.03 0.51 0.99 0.95 0.49 0.48 1.53 1.87 2.94 2.69 0.34 1.07 Effect of Compost on P Runoff Final Report page 50 Appendix 2. Laboratory analyses for water samples analyzed in the study. Sample 5-U-16 5-U-17 5-U-18 5-U-19 5-U-20 5-U-32 5-U-34 5-U-35 6-L-1 6-L-4 6-L-8 6-L-9 6-L-10 6-L-11 6-L-12 6-L-13 6-L-14 6-L-15 6-L-16 6-L-17 6-L-18 6-L-19 6-L-20 6-L-21 6-L-32 field upper (U) plot lower (L) run† 5 5 5 5 5 5 5 5 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 U U U U U U U U L L L L L L L L L L L L L L L L L 16 17 18 19 20 32 34 35 1 4 8 9 10 11 12 13 14 15 16 17 18 19 20 21 32 Date analysis reported 6/9/95 6/9/95 6/9/95 6/9/95 6/9/95 6/9/95 6/12/95 6/12/95 3/27/95 5/3/95 5/15/95 5/15/95 5/15/95 5/15/95 5/15/95 5/15/95 5/15/95 6/9/95 6/9/95 6/9/95 6/9/95 6/9/95 6/9/95 6/9/95 6/9/95 analyzed in laboratory derived measures total Acid Occluded Organic reactive digested Total NitrateP P P P P nitrogen Ac-P - TR-P T-P - Ac-P TR-P Ac-P T-P NO3-N Oc-P Or-P ––––––––––––––––––––––––––––– mg/L ––––––––––––––––––––––––––––––––––––––––– 6.22 8.64 21.00 2.46 2.42 12.36 2.62 3.11 4.33 0.17 0.49 1.22 5.95 6.19 15.49 0.29 0.24 9.30 n.s. n.s. n.s. n.s. n.s. n.s. 3.49 5.20 5.85 0.97 1.71 0.65 0.86 0.97 1.17 1.08 0.11 0.20 0.19 0.49 0.54 0.82 0.31 0.05 0.15 0.39 0.42 2.11 0.24 0.03 2.17 2.26 13.78 n.d. 0.09 11.51 0.08 i.s. 0.42 n.d. i.s. i.s. 1.27 2.01 3.19 2.77 0.75 1.18 1.47 2.13 3.31 2.58 0.66 1.18 2.01 2.21 3.76 2.36 0.20 1.55 0.88 0.93 1.53 1.93 0.05 0.60 1.85 1.99 2.31 1.67 0.14 0.32 1.74 2.42 3.50 1.95 0.68 1.08 2.87 2.89 5.48 2.38 0.02 2.59 2.52 2.54 4.51 1.36 0.02 1.97 0.88 1.07 1.78 1.94 0.19 0.71 0.56 0.82 1.12 0.52 0.26 0.30 1.91 2.08 2.85 0.34 0.17 0.77 3.71 3.93 5.63 0.44 0.22 1.70 4.81 5.02 11.49 2.02 0.20 6.47 4.83 6.83 11.58 1.32 2.00 4.76 1.97 2.04 2.12 0.52 0.06 0.09 Effect of Compost on P Runoff Final Report page 51 Appendix 2. Laboratory analyses for water samples analyzed in the study. Sample 6-L-34 6-L-35 6-U-1 6-U-4 6-U-8 6-U-11.14 6-U-15 6-U-16 6-U-17 6-U-18 6-U-19 6-U-20 6-U-32 6-U-34 6-U-35 field upper (U) plot lower (L) run† 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 L L U U U U U U U U U U U U U 34 35 1 4 8 11–14 15 16 17 18 19 20 32 34 35 Date analysis reported 6/12/95 6/12/95 3/27/95 5/3/95 5/15/95 5/15/95 6/9/95 6/9/95 6/9/95 6/9/95 6/9/95 6/9/95 6/9/95 6/12/95 6/12/95 analyzed in laboratory derived measures total Acid Occluded Organic reactive digested Total NitrateP P P P P nitrogen Ac-P - TR-P T-P - Ac-P TR-P Ac-P T-P NO3-N Oc-P Or-P ––––––––––––––––––––––––––––– mg/L ––––––––––––––––––––––––––––––––––––––––– 2.15 2.45 2.60 1.94 0.30 0.15 2.41 2.51 2.67 2.78 0.10 0.16 0.64 0.67 1.53 n.d. 0.03 0.87 0.77 i.s. 2.07 n.d. i.s. i.s. 0.63 1.23 2.34 2.73 0.60 1.11 0.85 0.99 1.31 1.94 0.15 0.32 1.76 2.14 2.71 5.04 0.39 0.57 1.56 1.86 2.60 0.55 0.30 0.74 1.41 1.79 2.53 0.23 0.38 0.74 0.72 0.92 1.12 2.76 0.20 0.20 0.91 1.07 3.06 0.94 0.16 1.98 n.s. n.s. n.s. n.s. n.s. n.s. 1.71 1.98 2.08 1.51 0.27 0.10 2.40 2.65 2.85 1.17 0.25 0.20 4.08 4.13 4.28 1.34 0.06 0.15 † see Table R-1 for explanation of runs; runs that contain more than one number are continuous through several runs Effect of Compost on P Runoff Final Report page 52 Appendix 3. S ummary statistics for solution chemistry analyses analyzed in laboratory derived measures total Acid Occluded Organic reactive digested Total NitrateP P P P P nitrogen Ac-P - TR-P T-P - Ac-P Sample plot U/L TR-P Ac-P T-P NO3-N Oc-P Or-P –––––––––––––––– average concentration (mg/l) ––––––––––––––––––– control 1 L 0.97 1.26 1.89 2.06 0.12 0.96 control 1 U 1.10 1.64 2.18 1.05 0.27 1.11 amended 2 L 0.42 0.57 0.68 1.86 0.14 0.15 amended 2 U 0.52 0.81 0.88 1.34 0.16 0.20 amended 3 L 0.65 0.95 1.00 1.03 0.14 0.20 amended 3 U 0.58 0.61 1.43 n.d. 0.04 0.66 control 5 L 1.12 1.17 2.26 1.13 0.14 1.02 control 5 U 1.78 2.52 4.50 1.29 0.60 2.37 amended 6 L 2.11 2.56 4.40 1.70 0.34 2.06 amended 6 U 1.45 1.77 2.37 1.82 0.25 0.63 –––––––––––––––– minimum concentration (mg/l) –––––––––––––––––– control 1 L 0.03 0.06 0.07 0.52 0.00 0.02 control 1 U 0.03 0.06 0.19 0.44 0.01 0.05 amended 2 L 0.19 0.19 0.43 0.43 0.01 0.03 amended 2 U 0.03 0.21 0.26 0.55 0.02 0.01 amended 3 L 0.32 0.63 0.69 1.03 0.04 0.10 amended 3 U 0.54 0.59 0.85 n.d. 0.03 0.22 control 5 L 0.01 0.10 0.27 0.51 0.00 0.04 control 5 U 0.03 0.10 0.26 0.17 0.01 0.03 amended 6 L 0.08 0.82 0.42 0.34 0.02 0.09 amended 6 U 0.63 0.67 1.12 0.23 0.03 0.10 –––––––––––––––– maximum concentration (mg/l) ––––––––––––––––– control 1 L 7.02 7.11 18.02 9.14 0.45 10.91 control 1 U 5.53 5.68 14.24 2.42 1.16 8.57 amended 2 L 1.00 1.25 1.51 7.82 0.35 0.38 amended 2 U 2.32 2.79 3.85 3.64 0.47 1.06 amended 3 L 1.04 1.28 1.37 1.03 0.24 0.31 amended 3 U 0.60 0.63 1.76 n.d. 0.04 1.10 control 5 L 4.86 5.42 12.86 1.74 0.56 7.44 control 5 U 6.22 8.64 21.00 2.69 2.42 12.36 amended 6 L 4.83 6.83 13.78 2.78 2.00 11.51 amended 6 U 4.08 4.13 4.28 5.04 0.60 1.98 Effect of Compost on P Runoff Final Report page 53 Appendix 3. S ummary statistics for solution chemistry analyses analyzed in laboratory derived measures total Acid Occluded Organic reactive digested Total NitrateP P P P P nitrogen Ac-P - TR-P T-P - Ac-P Sample plot U/L TR-P Ac-P T-P NO3-N Oc-P Or-P ––––––––––––––––––––– standard deviation –––––––––––––––––––––– control 1 L 1.8 2.0 4.2 2.3 0.1 2.7 control 1 U 1.7 1.9 3.6 0.6 0.3 2.4 amended 2 L 0.2 0.3 0.3 1.8 0.1 0.1 amended 2 U 0.6 0.8 0.9 0.9 0.1 0.3 amended 3 L 0.4 0.5 0.3 0.1 0.1 amended 3 U 0.0 0.0 0.5 n.d. 0.0 0.6 control 5 L 1.5 1.6 3.2 0.3 0.1 1.8 control 5 U 2.3 2.9 6.8 0.9 0.8 4.3 amended 6 L 1.3 1.4 3.8 0.8 0.5 2.9 amended 6 U 1.0 1.0 0.9 1.4 0.2 0.6 –––––––––––––––– number of samples analyzed ––––––––––––––––––– control 1 L 19 16 19 14 16 16 control 1 U 15 12 16 12 12 12 amended 2 L 19 16 19 15 16 16 amended 2 U 14 10 15 11 10 10 amended 3 L 3 2 3 1 2 2 amended 3 U 3 2 3 n.d. 2 2 control 5 L 18 17 18 16 17 17 control 5 U 12 11 12 10 11 11 amended 6 L 19 18 19 17 18 18 amended 6 U 12 11 12 10 11 11