Memo To: Brice Zeller From: James Peck, P.E. Date: May 20, 2010 Re: South Yuma County Landfill - Contaminated Soil Acceptance Criteria This memorandum is provided to summarize South Yuma County Landfill’s (SYCL’s) waste acceptance criteria for accepting petroleum contaminated soil (PCS), Regulatory Requirements Contaminated waste soil is generally treated as solid waste in Arizona, subject to federal hazardous waste listing and characterization criteria. Arizona treats non-hazardous waste soils that are contaminated with petroleum products in three separate categories, special waste PCS, solid waste PCS, and non-regulated soils. Special waste PCS is contaminated soil which contains certain chlorinated aromatic (BTEX) or polynuclear aromatic hydrocarbon (PAH) contaminants at levels above non-residential soil remediation levels. Special waste PCS must be disposed of at a disposal facility authorized by the Arizona Department of Environmental Quality (ADEQ) to accept special waste PCS. Solid waste PCS is contaminated soil which contains BTEX and PAH contaminants at concentrations between the residential and non-residential soil remediation levels. Solid waste PCS can be disposed of as solid waste at any facility authorized to dispose of solid waste. Non-regulated soil is soil that contains BTEX and PAH compounds below the residential soil remediation levels. Non-regulated soil is not regulated as a solid waste but is considered an inert material. Table 1 lists the appropriate levels of BTEX and PAH compounds in soils for establishing whether or not a soil is special waste PCS, solid waste PCS, or non-regulated soil. South Yuma County Landfill Permits The SYCL is a municipal solid waste disposal facility operating under an approved Solid Waste Facility Plan, ADEQ approval No. 50366100.02, as amended January 15, 2010. The SYCL is approved to accept special waste PCS, and is therefore approved to accept all manner of nonhazardous soils contaminated with petroleum products. The ADEQ approved SYCL as a special waste facility for accepting special waste PCS in April 2001 (Approval 302233), which is maintained under SYCL’s solid waste facility plan approval. The Solid Waste Facility Plan includes provisions for the acceptance and disposal of special waste PCS and solid waste PCS. The ADEQ solid waste facility plan approval specifically lists special waste PCS as an acceptable waste type at the SYCL. D:\687295307.doc $ Page 1 Waste Acceptance Criteria SYCL requires all generators of environmentally contaminated soil to submit a waste profile identifying the source of the contamination and provide relevant analytical data characterizing the waste consistent with an approved sampling plan or where appropriate, through generator knowledge in light of known or potential sources of contamination. Contaminated soil that has the potential to leach contaminants in excess of toxicity characteristic criteria are required to provide Toxicity Characteristic Leaching Procedure (TCLP) data on the waste as listed in Table 2. TCLP will be required for PCS soil with potential to leach lead in excess of 100 mg/L. Contaminated soil that classifies as either a listed or characteristic hazardous waste under U.S. EPA hazardous waste classification criteria is not accepted at the SYCL. Special waste PCS must be accompanied by a special waste manifest including a special waste generator identification number provided by ADEQ. Generators of special waste PCS must submit a sampling plan along with analytical test results from an Arizona Department of Health Services licensed laboratory. Sampling of the special waste PCS must be performed in accordance with the written sampling plan, which must be developed in accordance with the requirements of EPA’s SW846 or ADEQ’s Quality Assurance Project Plan.1 The sampling frequency for waste characterization must be consistent with the approved sampling plan. Analytical sampling data must include polynuclear aromatic hydrocarbons, petroleum aromatics. Other analyses such as soil pH, flashpoint, and total metals may be requested by SYCL depending on the waste generator’s profile. An acceptable sampling frequency for PCS soil characterization is as follows: 1-10 cubic yards 11-20 cubic yards 21-100 cubic yards 101-500 cubic yards: 500-10,000 cubic yards: >10,000 cubic yards: 2, one from each half 3, one from each third 4, one from each quarter 1 per 25 cubic yards, maximum of 10 samples 10 samples plus 1 sample for every 500 cubic yards above 500 cubic yards 20 samples plus 1 sample for every 5,000 cubic yards above 10,000 cubic yards For solid waste PCS, SYCL requires documentation from the generator verifying that the waste is not hazardous and does not contain any contaminants above the threshold for special waste PCS. Demonstration that the waste is non-hazardous must be provided by the generator and may include a determination of soil pH, soil flashpoint, and toxicity either by the TCLP or by total concentrations of BTEX and metals at levels that could not possibly exceed TCLP thresholds for hazardous waste. Attachments: Tables (2) U.S. EPA, Test Methods for Evaluating Solid Waste, SW-846, 3rd Edition, Volume II: Field Manual, Physical/Chemical Method, Chapter 9, Revision 6, 2007, and ADEQ, Quality Assurance Project Plan, Chapter 9, May 1991. 1 D:\687295307.doc $ Page 2 TABLES TABLE 1 Petroleum Contaminated Soil Classification Thresholds Special Waste Constituents (A.R.S. § 49-851A.3 BTEX EPA Method 8260 or 8021 PAHS Polynuclear Aromatic Hydrocarbons Commonly found in diesel and lubricant oil EPA Method 8310 Regulated Contaminants Solid Waste PCS >Residential SRLs (in ppm, mg/kg) Special Waste PCS >Non-Residential SRLs (in ppm, mg/kg) Benzene 0.65 1.4 Toluene 650 650 Ethylbenzene 400 400 Total Xylenes 270 420 Acenaphthylene 3,700 29,000 Anthracene 22,000 240,000 Benz[A]anthracene 6.9 21 Benzo[A]pyrene 0.69 2.1 Benzo[B]fluoranthene 6.9 21 Benzo[K]fluoranthene 69 210 Cyrysene 680 2,000 Dibenz[A,H]anthracene 0.69 2.1 Fluoranthene 2,300 22,000 Fluorene 2,700 26,000 Indenopyrene 6.9 21 Naphthalene 56 190 Pyrene 2,300 29,000 Notes: ppm = parts per million mg/kg = milligrams per kilogram Derived from ADEQ, Petroleum Contaminated Soil Fact Sheet, July 2008, Publication FS 08-14. TCLP limit (mg/L) Waste Limit - Totals (mg/kg) Arsenic 5.0 100 Barium Constituent 100.0 2000 Benzene 0.5 10 Cadmium 1.0 20 Carbon Tetrachloride 0.5 10 0.03 0.6 100.0 2000 Chloroform 6.0 120 Chromium 5.0 100 Cresol 200.0 4000 o-Cresol 200.0 4000 m-Cresol 200.0 4000 p-Cresol 200.0 4000 10.0 200 1,4-Dichlorobenzene 7.5 150 1,2-Dichloroethane 0.5 10 1,1-Dichloroethene 0.7 14 2,4-Dinitrotoluene 0.1 2 Chlordane Chlorobenzene 2,4-D Endrin 0.02 0.4 0.008 0.16 Hexachlorobenzene 0.1 2 Hexachloro-1,3-butadiene 0.5 10 Hexachlorothane 3.0 60 Lead 5.0 100 Lindane 0.4 8 Heptachlor (and its epoxide) Mercury 0.2 4 10.0 200 200.0 4000 2.0 40 100.0 2000 Pyridine 5.0 100 Selenium 1.0 20 Silver 5.0 100 Tetrachloroethene 0.7 14 Toxaphene 0.5 10 Trichloroethene 0.5 10 2,3,5-Trichlorophenol 400.0 8000 2,4,6-Trichlorophenol 2.0 40 2,4,5-TP 1.0 20 Vinyl Chloride Notes: mg/L = milligrams per Liter mg/kg = milligrams per kilogram 0.2 4 Methoxychlor Methyl Ethyl Ketone Nitrobenzene Pentachlorophenol