Name: 1 Properties of Atoms and Introduction to the Periodic Table – Notes Structure of the Atom • ___________________ are abbreviated in scientific shorthand – first letter or two of element’s name • ____________________– smallest piece of matter that still has the properties of the element Atoms • ____________________ • ____________________ • ____________________ • ____________________ ____________________ have electrical charge of _____ do not have an electrical charge have electrical charge of _____ and ____________________ are in the of an atom; electrons surround the nucleus ____________________ and ____________________ are made up of smaller particles called ____________________ • Quarks are studied by ____________________ accelerated charged particles with protons, which leave tracks in a bubble chamber • ____________________quarks are known to exist; the sixth is called the ____________________ quark ____________________ • Said all matter consisted of four elements: • ____________________ • ____________________ • ____________________ • ____________________ ____________________ (Greek) 400BC was first to propose an ____________________ Theory • Believed all matter was composed of small indivisible & indestructible particles he called atoms, from Greek word atomos. John ____________________ (early 1800’s) – atomic theory based on experimentation • All ____________________ are composed of ____________________ • Atoms of the same element are ____________________, atoms of different elements are ____________________ • Atoms of different elements can join together in single whole number ratios to form ____________________ • Chemical reactions occur when atoms are ____________________, ____________________ or ____________________ 2 J.J. ____________________ (English, 1897) • Discovered ____________________using a cathode ray tube. • Sealed tube with vacuum inside and electrodes on each end. When connected to electric current, a beam traveled from cathode to anode. He called the beam “cathode rays.” They were ____________________. • Proposed “______________________________” model of the atom. • Was a field of ____________________ distributed positive and negative charge. In 1911, ________________________________________interpreted these results and suggested a new model for the atom. He said that Thomson's model could not be right. The positive charge must be , otherwise the heavy alpha particles fired at foil could never be repelled back towards their source. On this model, the electrons orbited around the dense ____________________ (center of the atom). ____________________ (early 1900’s) The next important development came in 1914 when Danish physicist Niels Bohr revised the model again. It had been known for some time that the ____________________given out when atoms were heated always had specific amounts of ____________________, but no one had been able to explain this. Bohr suggested that the electrons must be (or shells). The nucleus is the center of an atom, containing protons and neutrons. The energy must be given out when 'excited' electrons fall from a high energy level to a low one. Scientists use scaled-up ____________________ to represent atoms. • Early models of atoms used a solid ____________________. • Current ________________________________________model shows electrons traveling in specific energy levels around a nucleus of protons and neutrons Masses of Atoms ____________________– composed mostly of the protons and neutrons in the nucleus • Unit of measurement for atomic particles is ____________________ ____________________ (amu) which is one-twelfth the mass of a carbon atom containing six protons and six neutrons. • • ____________________– the number of ____________________ in an atom; number of protons also ____________________ the element The sum of the number of protons and neutrons in the nucleus of an atom is the ____________________. 3 Element H O K I Pb Atomic # 1 Mass # 16 Protons Neutrons 0 Electrons 8 19 20 127 53 82 125 • ____________________ – atoms of the same element with different numbers of neutrons • Different isotopes have different ____________________ • Numbers of ____________________ is equal to mass number minus atomic number • Name of ____________________followed by mass number identifies the isotope • ________________________________________is the weighted-average mass of an element’s isotopes Average atomic mass is closest to its most ____________________ isotope • The Periodic Table • Elements are organized in the ______________________________by increasing atomic number. • In the late 1800’s, Dmitri ____________________ devised the first periodic table based on _________________________. • In 1913, Henry Moseley arranged the elements by _________________________rather than atomic mass. • • • • • Vertical columns in the periodic table are ____________________ of elements with similar ____________________. • Elements in the same group have the same number of ____________________ in their ____________________ energy level Each of the seven energy levels can have a ____________________ number of ____________________. • Energy level one can contain at most ____________________ electrons • Energy level two can contain at most ____________________ electrons Rows in the Periodic Table are called ____________________ Each row in the periodic table ends when an outer energy level is ____________________ ________________________________________use the element symbol and dots to represent outer energy level electrons. 4 Molecular Formula • Electron Dot Diagram Structural Formula ____________________ – horizontal rows of elements that contain increasing numbers of protons and electrons. • Elements are classified as • Elements are ____________________ in laboratories all over the world Electromagnetic Radiation (Light) as a Key to Understanding Electron Paths • Early scientists discovered that ________________________________________ (light) is given off by atoms of an element when they have been excited by some form of ____________________. Furthermore, atoms of different elements give off different ____________________ of light when they are excited. Spectral Analysis of Emitted Light from Excited Atoms • When the emitted light from excited atoms was passed through a prism, a curious spectrum of discrete ________________________________________, separate energies was observed rather than a continuous spectrum of ROY G BIV. • Furthermore, different ____________________ show totally different line spectra. • In fact, line spectra are used to ____________________the presence of different ____________________ Interpretation of Atomic Spectra • The line spectrum must be related to ____________________ transitions in the atom. • ____________________= atom gaining energy • ____________________ = atom releasing energy • Since all samples of an element give the exact same pattern of lines, every atom of that element must have only certain, identical ____________________ • The energy of an atom is ____________________ – limited to discrete values • If the atom could have all possible energies, then the result would be a ____________________ spectrum instead of lines 5 Interpretation of Atomic Line Spectra in terms of Electron Paths • ____________________ may be thought of as traveling in concentric shells or energy levels about the nucleus. • The ____________________ of the shells increase as one proceeds ____________________ from the nucleus. • When an atom ____________________ energy, electrons are promoted from an inner, ____________________ energy, shell to an outer, ____________________ energy shell. • Conversely, when an excited atom ____________________ energy, electrons drop down from an excited ____________________higher energy shells to an ____________________ lower energy shells Read pages 106 – 127 in your book, and answer the following questions on the back: 1. Characterize the size of an atom. 2. What are the charges and relative masses of the three main subatomic particles? 3. Describe Thomson’s, Millikan’s, and Rutherford’s contributions to the atomic theory. Include their experiments. 4. How many Protons and electrons are in each of the following atoms: a. Flourine b. Aluminm c. Calcium 5. How many neutrons are in each atom? a. 168O c. 3216S b. 10847Ag d. 8035Br 6. Three isotopes of oxygen are oxygen-16, oxygen-17 and oxygen-18. Write the complete symbol for each, including the atomic number and mass number. How is the mass number shown on the Periodic Table determined? 7. Why are the atomic masses not whole numbers? 8. How does the atomic number of an element identify the element? 9. How can atomic number and mass number be used to find the numbers of protons, neutrons and electrons? 10. What criteria did Mendeleev use to construct his periodic table of the elements? How did Moseley arrange the elements? Which is used today? 11. Identify each element as a metal, metalloid or nonmetal: a. Gold d. Sulfur b. Silicon e. Barium c. Manganese 12. Name two elements that have properties similar to those of the element calcium. 13. What are the properties of: a. Metals b. Non-metals c. Metalloids