Tangible: Ball and Spring Model BallSpring.mov Show ball and spring model and movie and discuss what “pushing” and “pulling” is! Tangible: Activity - What’s in a name…block? WID 1082002 cubes JCST_SCALE-UP_article.pdf (article in the Journal of College Science Teaching describing the activity) Have them measure the total mass and count the atoms to determine mass of one atom. Have them do a cube root to verify number of atoms on a side and their separation. Find your name block’s density. (They’ll need scale and ruler.) Chapter 4 1 Vblock+slot = ( 3.78 cm ) (1.92 cm ) (1.92 cm ) = 13.9 cm 3 Vslot = ( 0.1 cm ) (1.1 cm ) (1.9 cm ) = 0.2 cm 3 Vblock-slot = 13.7 cm 3 m = 36.3 g r= ( m 36.3 g g g = = 2.6 cm 3 accepted value is 2.7 cm 3 3 V 13.7 cm ) One mole of Aluminum has a mass of 27 g, so how many moles are in your block? 36.3 g = 1.3 moles g 27 mole How many atoms are in your block? 23 1.3 moles 6 ´ 10 23 atoms atoms mole = 7.8 ´ 10 ( ) Your block is roughly two cubes, each with 3.9e23 atoms. How many atoms per side of that cube? 3 3.9 ´ 1023 = 73 ´ 106 atoms on a side So block is roughly 73 by 73 by 150 million atoms. How far apart are the atoms? This is approximately the diameter of an atom. 0.0192 m m datom = = 2.6 ´ 10 -10 atom = 2.6 A 6 73 ´ 10 atoms What is the mass of a single atom? 36.3 g g -23 -25 kg matom = = 4.7 ´ 10 = 0.47 ´ 10 7.8 ´ 10 23 atoms atom atom There is a direct way to calculate that value without referring to a specimen: g 27 mole M g kg matom = = = 4.5 ´ 10 -23 = 0.45 ´ 10 -25 23 atoms 6 ´ 10 mole N Avogadro atom atom (dimensional analysis) Chapter 4 2 Also a direct way to calculate distance between atoms: rmicro = datom = matom matom N atom matom = 3 = = rmacro 3 Vatom d atom N atom d atom 3 matom rmacro M = 3 rmacro ( 4.5 ´ 10 ) ( 2.7 ´ 10 ) -26 datom = 3 N Avogadro kg atom 3 kg m3 ( rmacro = 2.7 cm g 3 ) æ 1 kg ö æ 100 cm ö 4 çè 1000 g ÷ø çè 1 m ÷ø = 2.7 ´ 10 3 kg m3 datom = 2.6 ´ 10 -10 m Odd tables, find mass and diameter of gold atoms. Look up density on web. Atomic mass from book cover. g kg r = 19.3 cmg 3 , M = 197 mole matom = 3.3 ´ 10 -25 atom d = 2.6 ´ 10 -10 m Even tables, find mass and diameter of lead atoms: g kg r = 11.4 cmg 3 , M = 207 mole matom = 3.5 ´ 10 -25 atom d = 3.1 ´ 10 -10 m FYI: Prototypical solid has atoms with radius of about 10-10 m or one angstrom, mass about 10-25 kg; nuclei are 10-14 m radius Ponderable: Activity - Interatomic spring stiffness WID 1081774 pull Odd tables, find interatomic spring constant for gold Chapter 4 3 Web gives Y = 11.3e6 psi. Use Google to convert with “11.3e6 psi in N/m^2” gives 7.79e10 N/ m2 ks, i = Yd = 7.79 ´ 1010 mN2 2.6 ´ 10 -10 m = 20.2 mN ( )( ) Even tables, find interatomic spring constant for lead Web gives Y = 16GPa. Converting with Google gives 1.6e10 N/m2 ks, i = Yd = 1.6 ´ 1010 mN2 3.1 ´ 10 -10 m = 5.0 mN ( )( ) Clickers: Chapter 4 Tangible: Activity – Springs Initially: • If you are in an "a" group, do Lab: Macroscopic Springs • If you are in a "b" group, do Lab: Young's Modulus • If you are in a "c" group, do VPython: Spring Once you have completed your group's part, switch to another, then another. Lab: Macroscopic Springs WID 1109323 bounce (Can also use QID 849846 as a long question to replace QIDs 855731, 855732, 855733) (Uses PASCO’s “Equal Length Spring Set) Measure spring stiffness for springs in series and parallel (make sure that they use springs of the same color). Discuss the results. Have them use stopwatch or sonic ranger with bouncing hanging weight (use weight hanger so there is sonic reflection). Show that a bigger amplitude leads remarkably to the same period. Contrast with a bouncing ball. Emphasize that the dissipation isn’t the issue here but the timing, with larger amplitude having longer period. Evidently the larger forces with larger stretches makes the momentum increase enough to compensate exactly for the longer distance traveled. Check that their measurements of the stiffness are consistent. Also check that they do see that doubling the amplitude doesn’t significantly change the period, and ask for ideas on how that can be, considering that the mass has to go much farther (answer: bigger forces generate bigger momentum changes, and we get bigger speeds which apparently exactly compensate for the longer distance). Also make sure that they see with double the mass a period that is about 1.4 times as long. Chapter 4 4 Lab: Young’s Modulus WID 1109367 bounce (includes Excel sheet: Lab_Young’s_Modulus_Data.xls) Need equipment. Instructions have vernier calipers, but can just give them this info: Data: diameter of brass wire = 0.285e-3 m (0.285 millimeters) Special apparatus for Young’s modulus. The intent is not to get an accurate measurement (which is difficult because the wire necessarily has some kinks in it and therefore behaves a bit like a coiled spring, which lowers the value obtained). VPython: Spring WID 594349 bounce WID 599948 “VPython: Spring Extra Credit” (can be used if 3D oscillations are extra credit) Spring3D.py shell program Have them use VPython to model a ball and spring moving on y-axis, starting from a shell on WebAssign. Chapter 4 5 Discussion: Analytical solution for spring system Now we’ll start using what we’ve learned about masses and springs and atoms and bonds together… Covered in book, chapter 3. Discuss analytical solution for an idealized spring system (no friction etc.) Draw a cosine curve, define amplitude and period. Momentum principle says slope of p vs t is F graph. Guess the analytical result that x = Acos(wt), explain meaning of A and = 2/T. æ 2p ö x = A cos (w t ) = A cos ç t è T ÷ø For example, if T = 1.2 s, after one period back to maximum amplitude: æ 2p ö æ 2p ö x = A cos ç t ÷ = A cos ç 1.2 s÷ = A cos ( 2p ) = A è T ø è 1.2 s ø w= ks m Ponderable: Activity - Coiled wire WID 1110037 rdf47 (4.P.55) Coiled_wire_solution.pdf Chapter 4 6 Chapter 4 7 Demo: Speed of sound in a solid NEED ON TABLE: Ball-spring models Imagine you have a long metal rod. You take a hammer and strike one end. What happens? Deforms, Vibrates, Makes a sound Vibration: do all the atoms vibrate instantly, the moment you hit it? Think about ball-spring model—look at model on the table! No—ones on the end vibrate first—then what happens? They compress bonds, exert forces on neighbors, and so on Vibration/compression travels, or propagates What is this?: A sound wave! What would influence the speed of sound in a solid? Mass, Spring stiffness, Initial stretch?? (think about it) How would you write a VPython program to model this and predict the speed of sound? Very similar to your spring program, just more masses & springs! VPython Demo: Speed of sound in a solid 04_speed_of_sound.py Group A and B—look up speed of sound in Aluminum Group C—look up speed of sound in Lead Run program for Aluminum Program models the propagation of sound through a metal. Linear chain of (N+2) atoms, first and last atoms fixed in position. Atoms connected by interatomic "springs" (16 N/m for Al, 5 N/m for Pb). Four parts of program to model propagation of sound through a metal: (1) Click an atom to displace it, then click repeatedly to see motion. (2) Same as (1), but also shows graph of displacements. (3) Click an atom to displace it, click anywhere when pulse reaches right end. (4) Same as (3), but lead atoms (Pb) instead of aluminum (Al). Move to next part or back by clicking an atom at the end of the chain. Atoms at the end of the chain are fixed in position. Why do you think lead has a lower speed of sound? What’s different? Lead has lower interatomic ks and bigger atomic mass Chapter 4 8 Let’s make connection between speed of sound and frequency of oscillating masses: dp = Fnet dt dpx = Fnet, x = -ks x dt d dvx d2 x m =m 2 =m dt dt ( 2 ( A cos (w t )) = m d ( -Aw sin (w t )) = m dt dt 2 ) m -Aw 2 cos (w t ) = -ks A cos (w t ) so mw 2 = ks and w = x Also useful to define f º ( -Aw 2 ) cos (w t ) = -ks x ks 2p = m T 1 so w = 2p f T Lead (massive atoms, weak springs) 1200 m/s compared to aluminum (lighter atoms, stiffer springs) 5000 m/s Single atom—about how far does it move: d! In about how long? T! So v should be proportional to d/T or d*omega. It turns out: v = wd = ks, i ma d where k s, i is the stiffness of the interatomic bond, d is the bond length, ma is the mass of one atom Book does copper, gets 3640 m/s. on page 163 Do speed of sound in Aluminum k 17.7 mN v = w d = s, i d = 2.3 ´ 10 -10 m = 5160 ms -26 ma 4.5 ´ 10 kg ( ) Why is this important? Micro-macro connections Tangible: It’s a race Speed of Sound.xls Fill in the table, given Y, M, and rho. A does Al, B does Au, C does Pb. Book does Cu. Chapter 4 9 Aluminum Young's Modulus, Y Gold Copper units 1.60E+10 1.17E+11 N/m^2 197 207 64 g/mole Density, rho 2.70E+03 1.93E+04 1.14E+04 8.94E+03 kg/m^3 Mass of an atom, ma 4.49E-26 3.27E-25 3.44E-25 1.06E-25 kg =M/1000/6.02E+23 Diameter of atom,d 2.61E-10 2.63E-10 3.18E-10 2.33E-10 m =(ma/rho)^0.333 Atomic Mass, M 6.90E+10 1.60E+10 Lead 27 Interatomic spring constant, ksi 18.0 4.2 5.1 27.3 N/m =Y*d speed of sound 5226 941 1224 3740 m/s =SQRT(ksi/ma)*d Book does atomic diameter of copper on page 142, interatomic bond stiffness for copper on page 145 (from measurements), speed of sound in copper on page 163 http://www.engineer ingtoolbox.com/youn g-modulusd_417.html 2.7 g/cm^3 = 2.7e3 kg/m^3 Chapter 4 10