Teacher Background for Stoichiometric Calculations TEKS 8E (New) Perform stoichiometric calculations, including determination of mass relationships between reactants and products, calculation of limiting reagents, and percent yield. TEKS Chemistry TEKS 8E How the TEKS Changed 1998 TEKS 2010–2011 TEKS This content was not included in the 1998 TEKS. 8E Perform stoichiometric calculations, including determination of mass relationships between reactants and products, calculation of limiting reagents, and percent yield. Unpacking the TEKS Explain to students that stoichiometry involves the calculation of quantities in chemical reactions. Calculations using balanced chemical equations are called stoichiometric calculations. Use TEKS Lesson 8E: Stoichiometric Calculations to help students understand how to plan and execute calculations involving the amounts of reactants or products in chemical reactions. Related Content TEKS 8E falls under knowledge and skills statement 8. The student can quantify the changes that occur during chemical reactions. Several other 2010–2011 TEKS for Chemistry discuss stoichiometry concepts, including: 8A Define and use the concept of a mole. 8B Use the mole concept to calculate the number of atoms, ions, or molecules in a sample of material. 8D Use the law of conservation of mass to write and balance chemical equations. 9B Perform stoichiometric calculations, including determination of mass and volume relationships between reactants and products for reactions involving gases. 1 Content Refresher Prior Knowledge A balanced chemical equation tells you what amounts of reactants to mix and what amount of a product to expect. Chemists use balanced chemical equations as a basis for calculating how much reactant is needed or how much product will be formed in a reaction. When you know the quantity of one substance in a reaction, you can calculate the quantity of any other substance consumed or produced in the reaction. Quantity usually means the amount of a substance expressed in grams or moles. However, quantity could just as well be in liters, tons, or molecules. Content and Vocabulary For chemists, stoichiometry is like bookkeeping—it allows chemists to tally the amounts of reactants and products using ratios of moles or representative particles derived from balanced chemical equations. Activating Prior Knowledge Students should know how to balance chemical equations and understand the mole concept. They should also be familiar with conversion problems involving mass, moles, and/or volume. chemical equation: a representation of a chemical reaction; the formulas of the reactants (on the left) are connected by an arrow with the formulas of the products (on the right) conversion factor: a ratio of equivalent measurements used to convert a quantity from one unit to another law of conservation of mass: in any physical change or chemical reaction, mass is conserved; mass can neither be created nor destroyed molar mass: a term used to refer to the mass of one mole of any substance Engage students in a review of moles and molar mass. Ask: What is a mole? (A mole is equivalent to 6.02 1023 particles of a substance.) Ask: How can you determine the number of moles of a substance in a chemical equation? (The number of moles is represented by the substance’s coefficient.) Ask: What is molar mass? (Molar mass is the mass of one mole of a substance.) mole: an amount of a substance that contains 6.02 1023 representative particles of that substance representative particles: the smallest unit into which a substance can be broken down without a change in composition; usually atoms, molecules, or ions Misconception Alert Students sometimes try to do mass-mass conversions by incorrectly using the mole ratio as a mass ratio. That is, they use grams instead of moles as the units in the mole ratio and then skip the mass-mole conversion step. Stress that because the number of grams in one mole of a substance varies with its molar mass, a mass-mole conversion is a necessary intermediate step in mass-mass stoichiometric problems. Caution students not to make quick judgments when finding the limiting reagent in a reaction. Often, students make a decision based on mass, or they do not completely finish the calculation and answer prematurely. Encourage students to read a problem slowly, formulate a plan, and write each calculation in steps until a final answer is obtained. Emphasize the importance of checking the reasonableness of an answer. 2 Covering the TEKS and Their Breakouts Students will master TEKS 8E when they read and answer: Lesson Questions 3, 4 where they will (8Ei) perform stoichiometric calculations, including determination of mass relationships between reactants and products. Lab Quantitative Analysis Question 1 where they will (8Ei) perform stoichiometric calculations, including determination of mass relationships between reactants and products. Lesson Questions 6, 7, 8 where they will (8Eii) perform stoichiometric calculations, including calculation of limiting reagents. Lesson Questions 9, 10, 11 where they will (8Eiii) perform stoichiometric calculations, including percent yield. 3