Abstract This thesis focuses on the growth of high quality III-nitride materials by MOCVD along both c-direction and non-polar a-direction. High temperature AlN buffer layer is introduced, which can effectively reduce the dislocation density of the overlying layer. Stimulated emission at 340nm has been obtained by such AlN buffer techniques, which mechanism is understood by studying the strain relaxation in the QW structure with RSM measurements. A non-polar overgrowth approach has also been established for the growth of non-polar GaN, leading to an impressive improvement in the crystalline quality. Meanwhile, optical investigation on c-plane InGaN/GaN MQW nanorod structures has been performed, demonstrating an significantly enhanced photoluminescence emission. It has been concluded that the enhancement is due to the reduction on quantum confined Stark effect caused by strain relaxation in the MQW structure. ~1~ ~2~ Publication list 01. Journal articles 1. Q. Wang, Y. Gong, J. F. Zhang, J. Bai, F. Ranalli, and T. Wang, “Stimulated emission at 340 nm from AlGaN multiple quantum well grown using high temperature AlN buffer technologies on sapphire”, Appl. Phys. Lett., 95, 161904 (2009) 2. Y. Gong, K. Xing, and T. Wang “Influence of high temperature AlN buffer on optical gain in AlGaN/AlGaN multiple quantum well structure”, Appl. Phys. Lett., 99, 171912 (2011). 3. K. Xing, Y. Gong, J. Bai, and T. Wang, “InGaN/GaN quantum well structures with greatly enhanced performance on a-plane GaN grown using self-organized nano-masks”, Appl. Phys. Lett., 99, 181907 (2011). 4. Q. Wang, J. Bai, Y. Gong and T. Wang, “Influence of strain relaxation on the optical properties of InGaN/GaN multiple quantum well nanorods”, J. Phys. D: Appl. Phys., 44, 395102 (2011). 5. Y. Gong, K. Xing, and T. Wang, “Optical gain in AlGaN/AlGaN multiple quantum wells grown on high temperature AlN multiple buffers”, Phys. Status Solidi, 8(7-8): 2056-2058 (2011). 6. Y. Gong, K. Xing, J. Bai and T. Wang, “Greatly improved crystal quality of non-polar GaN grown on a-plane GaN nano-rod template obtained using self-organised nano-masks”, Phys. Status Solidi, 9(3-4):564-567 (2012). 7. Q. Wang, J. Bai, Y. Gong and T. Wang, “Investigation of the optical properties of InGaN/GaN nanorods with different indium composition”, Phys. Status Solidi, 9(3-4):620-623 (2012). 8. J. Bai, Y. Gong, K. Xing, X. Yu and T. Wang, “Efficient reduction of defects in (11-20) non-polar and (11-22) semi-polar GaN grown on nanorod templates”, Appl. Phys. Lett., 102, 101906 (2013). ~3~ 9. B. Liu, R. Smith, J. Bai, Y. Gong and T. Wang, “Great emission enhancement and excitonic recombination dynamics of InGaN/GaN nanorod structures”, Appl. Phys. Lett., 103, 101108 (2013). 10. K. Xing, Y. Gong, X. Yu, J, Bai, and T. Wang, “Improved Crystal Quality of (11-22) Semi-Polar GaN Grown on A Nanorod”, Jpn. Jour. Appl. Phys. 52, 08 (2013) 02. Conference Contributions: 1. Y. P. Gong, J. F. Zhang, Q. Wang, F. Ranalli and T. Wang, “Optical properties of AlGaN-based materials grown on a new AlN buffer”, UK Nitrides Consortium (UKNC) Summer Conference, University of Sheffield, UK (2009) 2. Y. P. Gong, J. F. Zhang, Q. Wang, F. Ranalli and T. Wang, “Optical properties of AlGaN-based materials grown on a new AlN buffer”, International Conference on Nitride Semiconductors, Jeju, South Korea (2009) 3. Y. P. Gong, J. Zhang, P. Renwick and T. Wang “Growth and characterisation of AlN with improved crystal quality by using multiple porous AlN buffers on sapphire” UK Nitride Consortium (UKNC) Winter Conference, Tyndall Institute, Cork, Ireland (2010) 4. J. Zhang, Y. P. Gong, Q. Wang, P. Renwick and T. Wang “Quantum well thickness dependent optical anisotropy of spontaneous emission from AlGaN multiple quantum well structures” UK Nitride Consortium (UKNC) Winter Conference, Tyndall Institute, Cork, Ireland (2010) 5. Y. P. Gong, K. Xing and T. Wang “Optical gain of strained AlGaN multiple quantum wells grown on AlN buffers” UK Nitride Consortium (UKNC) Winter Conference, Manchester, UK (2011) 6. Y. P. Gong, K. Xing, J. Bai and T. Wang “Greatly improved crystal quality of non-polar GaN grown on a-plane GaN nano-rod template obtained using a self-organized nano-mask” International Conference on Nitride Semiconductors, Glasgow, UK (2011) ~4~ 7. Y. P. Gong, K. Xing, X. Yu, J. Bai and T. Wang “Improved crystal quality of (11-22) semi-polar GaN grown on semi-polar nano-rod template” UK Nitride Consortium (UKNC) Summer Conference, University of Sheffield, UK (2012) ~5~