Chapter 9. Thermal Performance 9.1. Introduction ............................................................................................................. 2 9.2. The Fission Heat Generation .............................................................................. 2 9.2.1. Energy Release from fission ............................................................................... 2 9.2.2. Fuel Burnup ......................................................................................................... 3 9.3. Fission Heat Removal ........................................................................................... 4 9.3.1. Heat Conduction in the Fuel .............................................................................. 4 9.3.2. Heat Transfer Resistances .................................................................................. 7 Gap Closure ................................................................................................................ 8 9.4. Axial Temperature Profile .................................................................................. 10 9.5. Thermal Conductivity .......................................................................................... 12 9.5.1. Thermal Conductivity in Porous Oxide .......................................................... 12 9.5.2.Thermal Conductivity Variation with Temperature ..................................... 14 9.6. Thermal Margins and Operational Limits ...................................................... 14 9.6.1. The LOCA ......................................................................................................... 15 9.6.2. Departure from nucleate boiling ..................................................................... 15 9.6.3. Cladding Temperature Limits ......................................................................... 16 9.6.4 Stored Energy ..................................................................................................... 17 Problems ........................................................................................................................ 17 References ..................................................................................................................... 20 Light Water Reactor Materials © Donald Olander and Arthur Motta 2/6/2016 9.1. Introduction One of the most important factors in designing nuclear power plants is the calculation of the power produced in the core and its removal by the coolant. To that end, coolant is circulated through the core and heat flows from the fuel rods to the coolant, which experiences a temperature rise as it passes through the core, as explained in Chapter 1. Since the heat is generated inside the fuel rods, temperature gradients are established inside the rods that enable the heat to flow outwards from the rods to the coolant, which results in a temperature profile within the rods. This temperature profile has a strong influence on the mechanical properties, on the microstructure evolution under irradiation and on corrosion processes occurring in the fuel and the cladding. Thus, a sound understanding of the factors governing the temperature distribution within a reactor fuel element is essential to predicting its performance during reactor exposure. Both the high temperatures and the steep temperature gradients are important for predicting fuel element performance. The temperature controls processes such as graingrowth, densification, fission product diffusion in the fuel and radiation damage accumulation, and corrosion rates in the fuel cladding. The temperature gradients in the fuel cause pore migration and formation of the central void, cause thermal stresses or fuel cracking, and pellet-cladding interaction. In the cladding, temperature gradients cause hydride rim formation and overall hydrogen redistribution. The topic of this chapter is the thermal performance of the fuel rod and the core. This includes a calculation of the temperature distribution in the fuel rod and in the core, and its change with reactor exposure. The thermal margins and accident conditions are also briefly discussed. 9.2. Fission Heat Generation Nuclear energy is generated in light-water reactors by the fission of uranium induced by absorption of neutrons. The fission of the uranium atom splits it into two smaller parts (the fission products), and releases two to three energetic neutrons (average energy ~ 2 MeV), as well as other particles such as betas, gammas and neutrinos. The neutrons released in the fission reaction cause fissions in other nuclei, a process called fission chain reaction. 9.2.1. Energy Release from fission The overall energy release in a single fission reaction is 200 MeV, about 90% of which is deposited in the fuel pellet. Although every nuclide in the transuranic region can be fissioned if enough energy is imparted to it, the fission cross-section for certain fissile nuclides (U-233, U-235, Pu-239, Pu-241) is greatly increased if the neutron energy is reduced to values close to the thermal energy (~ 0.025 eV at reactor temperature). In thermal reactors (such as the light water reactors considered in this book), this energy reduction is achieved by passing the neutron flux through a moderator (water) which causes the neutrons to lose energy by successive collisions until they are in thermal Light Water Reactor Materials © Donald Olander and Arthur Motta 2/6/2016 equilibrium with their surroundings. To ensure that criticality (a fission chain reaction at a constant rate) can occur with thermal neutrons, natural uranium is enriched to a larger percentage of the isotope U-235 (3-5% in current reactors). In parallel with neutron-induced fission, neutron absorption can occur in uranium, causing transuranic (heavier than uranium) elements to be formed. Of chief importance among these is Pu-239, which forms directly by neutron absorption in U-238 followed by beta decay. This creates another fissile isotope which contributes to the fission rate. In parallel with the depletion of U-235, Pu-239 is created from U-238 so that at the end of the fuel residence time in the reactor, up to one third of the reactor energy is produced by plutonium fission. Not all the fissile material (U and Pu) is used by the time the fuel is removed from the reactor, so it is also possible to reprocess the spent fuel to extract U and Pu to fabricate mixed-oxide fuel (MOX), which consists of (U,Pu)O2. Thus, there are various sources of heat in a reactor core: fast fission of U-238, thermal fission of U-235 and Pu-239, and the radioactive decay of fission products. The last term is important in loss-of-coolant accident scenarios, since shutting down the fission chain reaction does not eliminate this heat source and cooling needs to be provided to avoid fuel damage (see chapter 28). However, during normal operation the most significant heat generation term is thermal fission in U-235 and Pu-239 (the fast fission rate is a few percent that of thermal fission). The first step in calculating the temperature profile is to calculate the rate of heat production by nuclear reactions, mostly nuclear fission. If we consider a fuel element at the beginning of life, containing enriched uranium and take thermal fission in U-235 to be the dominant heat production mechanism, the fission rate is given by F ( fission / cm3s) f N f f qNU f (9.1) wheref is the macroscopic thermal fission cross section (cm-1), is the thermal neutron flux (n.cm-2.s-1), Nf is the fissile atom density (fissile atom/cm3), f the thermal fission cross section (barn), q is the enrichment (fissile atom density/uranium density) , and NU is the uranium density (atom/cm3). The theoretical atom density in uranium dioxide is 2.5x 1022 atom/cm3, while the thermal fission cross-section for U-235 is ~ 550 barn. 9.2.2. Fuel Burnup The term burnup indicates the degree of usage of the fuel although it clearly has nothing to do with burning but rather with fissioning. There are three common measures of the integrated amount of irradiation to which the fuel has been subjected. The first is the fission density given by t F F (t )dt Ft [ fission / cm3 ] 0 for a constant fission rate. The second is the fractional burnup given by Light Water Reactor Materials © Donald Olander and Arthur Motta 2/6/2016 (9.2) number of fissions F initial number of uranium atoms NU (9.3) Finally, the burnup can be given as the number of megawatts days of thermal energy released by a fuel containing one metric ton of uranium. The 200 MeV released in each fission corresponds to 0.95 MW.day per gram fissioned. Thus [MWd / MTU ] 0.95 106 9.5 105 [%] (9.4) At the end of life, fuel burnup used to be about 3%, and thus approximately equal to 30,000 MWd/MtU Average fuel discharge burnups have been increasing for the past two decades, now reaching over 50,000 MWd/ton for pressurized water reactors and approaching that value for boiling water reactors [1]. The Nuclear Regulatory Commission has established a limit of 62,500 MWd/ton. Current efforts exist to certify fuel for higher burnups, as discussed in Chapter 28. 9.3. Fission Heat Removal The thermal design of a fuel element is constrained by various limits. It is necessary to stay well below the fuel and the cladding melting temperatures at all times. It is also desirable to increase as much as possible the coolant outlet temperature from the core to maximize thermal efficiency. It is undesirable to have large temperature gradients in the fuel elements, as that leads to a variety of issues, as mentioned above. These constraints would dictate a fuel with high thermal conductivity and high melting point. This is achievable with metallic fuels, whose thermal conductivities are much higher than that of UO2. However, while metallic fuels exhibit serious dimensional instabilities under irradiation (Ch.27), uranium dioxide turns out to be a remarkably stable fuel matrix: it can undergo thermal cycling, can withstand severe amounts of radiation damage and can accommodate within its lattice the fission products and transuranic atoms produced during irradiation. The melting temperature of uranium dioxide is in the temperature range 2800-2865°C, as shown in the phase diagram in Chapter 2. 9.3.1. Heat Conduction in the Fuel The removal of heat from the cylindrical fuel element occurs in the radial direction, through a series of heat resistances, by conduction and convection. The heat transfer geometry is shown in Figure 9.1. Light Water Reactor Materials © Donald Olander and Arthur Motta 2/6/2016 TFC TFS TCI TCS TW R+tgap+ tC R+tgap R Figure 9.1: The heat transfer geometry in a nuclear fuel rod Heat is generated in the fuel pellet radius R and flows radially through the fuel, the pelletcladding gap, and the cladding itself to reach the coolant. Because the axial temperature variation is relatively small, and there is little azimuthal temperature variation, the steadystate heat conduction equation is written as: 1 d dT r F q ''' 0 r dr dr (9.5) where T is the temperature, r the radial position in the pellet, F is the fuel thermal conductivity and q ''' is the volumetric heat generation rate (W/cm3) given by q ''' FEF 3.2 1011 F [W / cm3 ] (9.6) where EF is the energy deposited in the fuel pellet with each fission (about 180 MeV). Equation (9.5) assumes a heat generation rate that is independent of r and of T (this is not strictly true, because of self-shielding, and other flux gradient effects.) If the variation of q ''' with r is known, an average volumetric heat generation rate q ''' can be calculated. One useful quantity is the linear heat generation rate (W/cm) obtained by q ' R 2 q ''' (9.7) Equation (9.5) can be solved if two boundary conditions are specified. These are: T ( R) TFS Light Water Reactor Materials © Donald Olander and Arthur Motta 2/6/2016 (9.8) dT dr 0 (9.9) r 0 where TFS is the fuel surface temperature . Integrating equation (9.5) twice we obtain T (r ) TFS q ''' r 2 C1 ln r C2 4 F (9.10) Applying the boundary conditions: T (r ) TFS q ''' R 2 r 2 q' 1 2 4 F R 4 F r2 1 2 R (9.11) or T (r ) TFS r2 1 2 TFC TFS R (9.12) where TFS is the fuel pellet surface temperature and TFC is the fuel centerline temperature. Thus a parabolic temperature profile is established whenever heat generation in the volume is homogenous. The equivalent forms of equation (9.11) for plate and sphere geometry are respectively: T (r ) TFS q ''' L2 x 2 1 for plate 2 F L2 q ''' R 2 r2 T (r ) TFS 1 for sphere 6 F R 2 (9.13) where L is the plate half-thickness and R is the radius of the sphere. From equation (9.12) it follows that the linear power at a given axial position is given by q ' (TFC TFS )4 F (9.14) This heat flux flows from the fuel through the fuel-cladding gap and through the cladding and into the coolant. Heat transfer through the cladding is achieved by conduction. Although heat transfer through the gap occurs through a gas, no flow or convective effects exist. As a result the process can be thought of as one of conduction with Light Water Reactor Materials © Donald Olander and Arthur Motta 2/6/2016 gap hgap t gap . where is the gap thickness and hgap the convective heat transfer coefficient in the gap. Solving the heat transfer equations for the cladding we find that the temperature drop through these two hollow cylinders is given by TFS TCI q ' TCI TCS q ' ln[( R t gap ) / R ] 2 k gap ln[( R t gap tC ) /( R t gap )] 2 C (9.15) (9.16) where TCI is the cladding inner radius temperature, TCS is the cladding outer radius temperature, C is the cladding thermal conductivity and tC is the cladding wall thickness. Heat transfer from the cladding surface to the coolant is achieved by convection. q' (TCS TW ) (9.17) h where TW is the bulk coolant temperature and h is the convective heat transfer coefficient between the cladding wall and the coolant, given for example by the Dittus-Boelter relation [2]. If t gap R then q ' (TFC TFS )4 F 2 k gap R(TFS TCI ) t gap 2 C (TCI TCS ) h(TCS TW ) (9.18) ln[( R tC ) / R] 9.3.2. Heat Transfer Resistances Using the well-known electric analogy, we can write that the temperature difference T (analogous to voltage), established through a material with a certain thermal resistance R (analogous to resistivity) creates a heat flux q’ (analogous to electric current) given by q' T (9.19) The resistances are all in series, such that the total thermal resistance in going from the centerline of the fuel to the coolant is given by the sum of the individual resistances. Light Water Reactor Materials © Donald Olander and Arthur Motta 2/6/2016 i 1 4 F t gap 2 gap 1 R tC ln 2 C R 2 ( R tC ) h 1 (9.20) For the case of the fuel rod when the gap is closed (tgap=0 and thus TFS=TCI) then equation (9.19) is written: TFC TW (9.21) t gap 1 1 1 R tC ln 4 F 2 gap R 2 C R 2 ( R tC )h where TW is the cooling water temperature, h is the convection coefficient from the clad to the coolant, and tC and C are the cladding thickness and thermal conductivity. q' Gap Closure The change in gap width upon fuel and cladding expansion is given by hot cold tgap tgap t gap Rc R (9.22) where Rc is the change in cladding radius and R is the change in fuel radius with temperature. It can be shown (see problem 9.1) that the radial swelling strain of the fuel when a parabolic profile is present is given by R F (T T fab ) (9.23) R where T is the average fuel temperature and Tfab is the fuel fabrication temperature and F is the coefficient of thermal expansion of UO2 . The corresponding swelling increase for the cladding is approximately equal to FR Rc c (Tc T fab ) Rc Thus the change in gap width upon heating is given by hot cold tgap tgap tgap Rcc (Tc Tfab ) RF F (T Tfab ) If an additional strain from fuel fission gas swelling occurs, it can be inserted in the equation above. Example 9.1: Calculation of a Fuel Rod Temperature Profile Light Water Reactor Materials © Donald Olander and Arthur Motta 2/6/2016 (9.24) (9.25) We can now evaluate the temperature profile for a typical fuel rod. The properties listed in table 9.1 can be used for this purpose; Table 9.1. Thermal properties of fuel materials Material Cp (J/gK) (g/cm3) UO2 10.98 0.330 Zircaloy 6.5 0.35 Steel 8.0 0.5 (W/mK) (K-1) 3 17 17 1.45x10-5 5-10x10-6 9.6x10-6 For this calculation we assume TW=310°C q’=15000 W/m h=20000 W/m2K Fuel pellet radius R=0.5 cm Fuel cladding thickness tC= 0.06 cm Gap width tgap= 0.03 cm from this we calculate the temperature drops in each resistance: From the coolant bulk through the coolant film to the cladding wall= 21.3 °C Through the cladding thickness = 15.9 °C In the fuel-cladding gap= 4.7 °C From the outer skin to the centerline of the fuel pellet=1250 °C Given the above, the fuel centerline temperature is 1602 °C. This is shown as the blue curve in Figure 9.2. It is clear that the greatest contributor to the increase in centerline temperature is the temperature rise in the fuel, but the gap can have a significant impact as well. This is illustrated by keeping all parameters the same, while substituting xenon for helium. As burnup increases, xenon gas is released into the fuelcladding gap degrading its thermal conductivity. If the xenon conductivity of 0.007565 W/mK is used instead of that of helium, we obtain a temperature drop in the gap of 94.7 °C (an increase of almost 100 °C), leading to a centerline temperature of 1691 °C (red curve). All other factors being equal, every temperature rise in the coolant will cause a corresponding temperature rise in the centerline temperature. Light Water Reactor Materials © Donald Olander and Arthur Motta 2/6/2016 2000 Coolant Fuel rod 1800 Gap 1600 Fuel cladding Temperature (C) 1400 1200 1000 800 600 Bulk Coolant Temperature 400 200 0 0.00 0.20 0.40 0.60 0.80 1.00 Radial Distance (cm) Figure 9.2 Temperature Profile in a fuel rod (see example 9.1) 9.4. Axial Temperature Profile Although the most significant temperature variation is in the radial direction it is also important to calculate the axial temperature variation. The axial power distribution can be written as z (9.26) q '( z ) qo 'cos H core where qo’ is the linear generation rate at the centerline of the core, and Hcore= zoutlet-zinlet is the height of the core. Light Water Reactor Materials © Donald Olander and Arthur Motta 2/6/2016 In addition to a radial temperature profile within the fuel rods, an axial temperature profile also exists, created by the combination of an axial fission rate profile and by the changing temperature of the coolant as it passes through the core, starting out cold and leaving hot. This temperature profile can be evaluated using a heat balance on the coolant. The overall rise in temperature of the coolant is sufficient to remove the heat generated by nuclear fission. Fig.9.3: For the element of coolant shown in Figure 9.3, the enthalpy of the fluid entering the element is QC pW (TW Tref ) (9.27) where Q m / N rods is the mass flow rate associated with one fuel rod, C pW is the specific heat of water, and Tref is a reference water temperature. Upon exiting the control volume, the enthalpy increase of the water is dTW dz (9.28) dz At steady-state this increase is equal to the energy produced in the fuel section of the control volume dT QC pW W dz q ' dz (9.29) dz Assuming no radial flux variation, an energy balance in the coolant gives QC pW QC pW (Toutlet Tinlet ) zoutlet q '( z )dz (9.30) zinlet where Q is the core mass flow rate in (kg/s), Cp is the coolant specific heat (J/kg°C), Tinlet and Toutlet are the inlet and outlet coolant temperatures. Inserting equation (9.26) into equation (9.30) and integrating to a height z instead of to the top of the core will yield the temperature of the coolant at height z. qo ' H core z sin 1 QC pW H core Light Water Reactor Materials © Donald Olander and Arthur Motta 2/6/2016 TW ( z ) TWinlet (9.31) As expected the highest temperature occurs at the outlet. 9.5. Thermal Conductivity The heat conduction equations derived above apply only when the thermal conductivity is constant (does not depend on temperature, chemistry or fuel microstructure). This section discusses the thermal conductivity of the fuel rod constituent materials, (especially the fuel), their variation with temperature, composition and burnup and the methods used to take these variations into account. Because most of these variations occur in the fuel, the next sections discuss fuel thermal conductivity. In the as-fabricated fuel the thermal conductivity depends on many parameters, as discussed in the following sub-sections. For the cladding the thermal conductivity is most strongly affected by the formation of the outer wall oxide (as discussed in chapter 22). The thermal conductivity of the fuel, gap and cladding is essential to determining the temperature distribution and transient thermal response of the fuel rod. The thermal conductivity of the fuel also determines the amount of stored heat in the fuel which is a consequence of the large gradients that have to be established order for the heat to flow out at steady state. 9.5.1. Thermal Conductivity in Porous Oxide When uranium dioxide is fabricated by sintering (see chapter 16) it is possible to control the sintering conditions so that the pores initially present are eliminated to varying degrees during the sintering process, resulting in a solid with less than the ideal theoretical density of 10.95 g/cm3. The presence of the pores allows for free space to accommodate fission gases, thus reducing swelling. However, the effect of those pores is to diminish the overall thermal conductivity of the material. In addition, during irradiation porosity develops in the form of bubbles and voids whose distribution varies with radius, linear power and with burnup. It is then necessary to evaluate the thermal conductivity of the composite material, which is done in the following Light Water Reactor Materials © Donald Olander and Arthur Motta 2/6/2016 Figure 9.4. Geometry for analysis of effect of pores on thermal conductivity [3] Consider a homogenous distribution of cube-shaped pores. We can then define a “unit cell of volume associated with each pore, as shown in Figure 9.4. If we consider that heat flow occurs along the y direction, then two pathways exist for the heat to transverse the cube: through the “pore tube”, or around it. Clearly when going around the pore, the thermal conductivity will be that of the dense UO2 while going through the tube the thermal conductivity will be a composite of pore and uranium dioxide. The overall conductivity is then F (1 f P )UO f P tube (9.32) where fP is the fraction of cross sectional area perpendicular to heat flow occupied by the pore. Each tube consists of a square pillar conductity of dense UO2 and of a pore. The fraction occupied by the pore in the tube is ftube. Then the effective conductivity of the tube is f (1 f Ptube ) 1 (9.33) Ptube tube pore UO2 By substituting (9.33) into (9.32) we obtain 2 2 1 [(1 ftube ) / ftube ]( pore / UO2 ) ( / ) F (1 f P )UO2 1 pore UO2 ftube F (1 f P )UO 1 ( pore / UO2 ) (9.34) (9.35) Note that the porosity pF is given by pF f p f tube (9.36) f p pF 2/ 3 (9.37) For cubic pores Light Water Reactor Materials © Donald Olander and Arthur Motta 2/6/2016 ftube pF 1/ 3 F (1 pF2/ 3 )UO 1 2 For the case where the pore is << UO2 then (9.38) ( pore / UO2 ) p1/F 3 F (1 pF2/3 )UO 2 (9.39) (9.40) 9.5.2.Thermal Conductivity Variation with Temperature The integration of equation (9.5) was performed assuming that the thermal conductivity is independent of the radial position r. In fact the thermal conductivity of UO2 varies significantly with temperature [3] which in turn varies markedly with radial position. For example an empirical fit of data has given the following equation for thermal conductivity of UO2 F 0.0130 1 [W / cm. C ] (0.038 0.45 pF )T (9.41) To take into account the dependence of thermal conductivity with temperature it would then be necessary to solve the heat conduction equations with UO2 being f(T). This would normally be done by numerical methods. 9.6. Thermal Margins and Operational Limits A nuclear reactor is different from conventional power plants in that because of the need to avoid fuel damage, the operational constraints are on the maximum temperature in the core, rather than on the average temperature. Reactor operational conditions depend both on the maximum allowable fuel rod temperature (centerline temperature) and the maximum allowable cladding temperature. Because the neutron flux and coolant temperature vary axially and radially through the core, so do the fuel rod temperatures. To base the normal operation limits on the highest maximum temperature they have to be calculated for the hottest channel. The power profiles that give rise to the temperature profile can be characterized using the power peaking factor PF (r ) q '(r ) (r ) q '(r ) (9.42) It is necessary to set thermal limits and to ensure that the reactor does not exceed those during normal operation or accident conditions. In light-water reactors the accidents of greatest concern (those associated with the greatest potential for fuel damage) are those in Light Water Reactor Materials © Donald Olander and Arthur Motta 2/6/2016 which the temperature of the fuel is raised beyond acceptable limits, either (i) through the production of excessive power (as in a reactivity initiated accident, Chapter 28) or (ii) having too little coolant, as in a loss of coolant accident (LOCA). 9.6.1. The Loss-of-Coolant Accident (LOCA) The loss of coolant accident is a design-basis accident in light water reactors. The postulated accident required for analysis is a guillotine break in a main primary coolant pipe, allowing coolant to freely discharge out of the primary system into the containment building. In that event, although the control rods shut down the reactor, power continues to be produced by the decay heat of the fission products. At steady-state, this amounts to approximately 10% of the full-power thermal output of the reactor, which for a typical 1000MWe reactor amounts to ~ 300 MW. In addition, some energy is stored in the core from the temperature gradients necessary to ensure heat flow. The combination of decay heat and stored heat distribution can cause the cladding temperature to rise above acceptable limits if not enough emergency cooling is supplied. In the case of loss of cooling, the cladding temperature can rise above acceptable limits. Thus, it is necessary to ensure that the reactor continues to be cooled. The Emergency Core Cooling System (ECCS) then injects water into the core, allowing the cladding temperature to remain low and avoiding fuel failure. Figure 9.5. Cladding to water heat flux as a function of temperature If for some reason there is a failure to deliver adequate core cooling, there is a mismatch between power produced and heat removed, the cladding temperature rises, as does the temperature of water/steam mixture that forms. The heat flux in such a situation is shown in Figure 9.5. As the temperature of the water/steam mixture rises, the heat flux initially also rises, due to the high degree of nucleate boiling that occurs, as a higher rate of bubble generation causes improved mixing and more efficient heat transfer. Thus in the first region the heat transfer coefficient increases as the increased mixing produced by the bubbles causes more efficient heat transfer. 9.6.2. Departure from nucleate boiling As the temperature of the cladding increases the bubble density increases until the bubbles coalesce and a continuous film is formed. Once that occurs (point c), the heat flux is severely decreased as the heat transfer coefficient of steam is much lower than that Light Water Reactor Materials © Donald Olander and Arthur Motta 2/6/2016 of water. This departure from nucleate boiling (DNB) occurs at a critical heat flux qc’ and can have severe consequences for the fuel. To avoid reaching the critical heat flux, thermal margins are established. According to equation (9.42), the peaking factor in the hottest channel needs to be such that the heat flux in the hottest channel is lower than the critical heat flux by a safety margin in normal operation, as illustrated in Figure 9.6. Figure 9.6. Illustration of DNB limits The Departure from Nucleate Boiling Ration (DNBR) is then a useful measure of how close this dangerous situation is approached. 9.6.3. Cladding Temperature Limits Once DNB has occurred cladding temperature s quickly increases. This temperature rise, in turn exponentially increases the rate of chemical reaction between the Zircaloy cladding and the steam. As the reaction proceeds, the heat of reaction causes further acceleration of the reaction rate, while the hydrogen produced and released to the containment increases the risk of explosion. Since DNB would only be expected to occur in highly improbable accident scenarios, it is not necessary to show that fuel failure does not occur. Rather, it is only necessary to demonstrate in that case that the consequences are not excessive, i.e. that fuel does not get damaged to the point that a coolable geometry cannot be maintained. The cladding temperature limit was established to avoid excessive reaction of the Zircaloy cladding with water. It has been shown that a high temperature excursion and consequent reaction with steam and oxygen absorption by the cladding causes significant post-quench cladding embrittlement [4]. As explained in Chapter 28, such limits are on maximum cladding temperature TC 1204 C and on the equivalent cladding reacted Light Water Reactor Materials © Donald Olander and Arthur Motta 2/6/2016 (9.43) ECR 17% (9.44) To avoid this scenario, a cladding temperature limit has been established of 1204°C (2200°F) such that this runaway reaction process cannot occur. 9.6.4 Stored Energy One of the consequences of a low fuel thermal conductivity is that large temperature gradients are needed in the fuel pellet to drive the heat flux out from the fuel to the coolant. The large temperature gradient means that there is a significant amount of stored energy in the fuel. This is one of the reasons why cooling must continue to be provided even in the case of a loss of coolant accident. In the event there was no cooling at the cladding surface the heat redistributes across the fuel pin until the temperatures are even across the rod. This redistribution would likely cause the cladding temperature to rise above acceptable limits. The stored energy per unit length of fuel rod is Estored C R F p 2 rdr (T T ) S (9.45) 0 where C pF is the volumetric heat capacity of the fuel (J/m3C) For a parabolic profile with constant thermal conductivity, we obtain the stored energy by inserting equation (9.11) into equation (9.45) to obtain q ' r2 1 4 F R 2 0 from where we obtain the stored energy per unit length of fuel rod (J/m) Estored C R F p 2 rdr (9.46) C pF q ' R 2 (9.47) 8 F Thus the coolant needs to provide enough heat transfer capability to remove at least this much heat, in addition to the heat generated by fission product decay which is about 10% of the thermally rated power at the moment of shutdown. Estored Problems 9.1. Verify that the burnup when expressed in megawatt.day/metric ton is equal to 9.5 x 105 the fractional burnup. 9.2 The temperature dependence of the thermal conductivity of UO2 is given theoretically by: Light Water Reactor Materials © Donald Olander and Arthur Motta 2/6/2016 k= ko/(1+BT) where ko and B are constants and T is the temperature in K. Using this equation, derive the equation giving the temperature difference between the fuel centerline and the fuel surface. The fuel surface temperature is Ts and the rod linear power is P. 9.3 In calculating the temperature distribution in the cladding, it is possible to neglect the curvature and approximate the geometry as a slab. (a) Derive the equation for the temperature difference between the inside and outside surfaces for cladding of thickness tc and inner radius Rci on a fuel rod operating at linear power q’. The cladding thermal conductivity is c. (b) Show mathematically how the result of (a) reduces to for the case of thin cladding(tc<<Rci). (c) The cladding of PWR fuel is 0.7 mm thick and 8 mm in diameter. What is the fractional error in the temperature difference due to the use of slab geometry? 9.4. Demonstrate equation (9.21) 9.5. Prove that the fractional thermal expansion of the outside diameter of a solid cylinder of radius R with thermal expansion coefficient in a parabolic temperature distribution is T , where T is the volume-averaged temperature rise of the solid. 9.6. Derive equation (9.13) 9.7 Duplex fuel consists of two radial zones with different enrichments of the uranium. Such pellets reduce the fuel centerline temperature below that of conventional uniformlyenriched fuel operating at the same linear power. In a particular fuel design, the center of the pellet to a radius ri consists of natural uranium and the outer annulus ri<r<R contains 4% enriched fuel. This fuel design is to be compared to conventional single-enrichment fuel containing 3.2% 235U, neglecting neutron-flux depression in the pellet and assuming a temperature-independent fuel thermal conductivity. (a) What is the value of ri that gives the same average power density in the duplex and homogeneous fuels? (b) What is the ratio of the temperature difference between the fuel centerline and surface for the two designs at the same linear power? 9.8 Solutions to transient heat-conduction problems often are expressed in terms of a dimensionless time t/d2 and a dimensionless position r/d, where =k/Cp is the thermal diffusivity, d is a characteristic dimension of the body, and t and r are time and position, Light Water Reactor Materials © Donald Olander and Arthur Motta 2/6/2016 respectively. The ratio d2/ is a characteristic time for the problem. When the imposed time scale of the transient is much longer than the characteristic time, the quasi-steadystate form of the heat conduction equation is sufficient for the analysis. If the transient occurs in times shorter or comparable to the characteristic time, the full time-dependent heat conduction equation must be solved. (a) A PWR is shut down from full power in 1/2 minute. Considering typical properties, which components of the fuel rod(fuel and cladding) can be treated by quasisteady-state heat conduction during this transient? (b) The first wall of a fusion reactor is a steel plate 1 cm thick. The back side of the wall is maintained at constant temperature by a coolant. The front face is suddenly exposed to a plasma disruption that increases the heat flux instantaneously. Approximately how long is required for the increased heat load on the front face be felt at the back face of the wall? The thermal conductivity, heat capacity, and density of the particular steel are 0.23 W/cmK, 0.32 J/g-K, and 8.7 g/cm3, respectively. 9.9 A fuel rod operates at a linear power P with a radial power density distribution H(r)=Ho+ar2, where Ho and a are constants. a is positive because the effect it describes is the neutron flux depression in the fuel pellet. What is the difference between the centerline-to-surface temperature difference for this rod compared to one operating at the same linear power but with a uniform radial power density distribution? 9.10 A fast reactor fuel pin operates at a linear power of 700 W/cm at an axial location where the coolant (liquid sodium) is 500oC. Under these conditions, a central portion of the fuel is molten. The heat transfer properties of this fuel pin are: kgap/tgap = 0.5 W/cm2-K kc/tc = 9 W/cm2-K hcoolant = 12 W/cm2-K ksolid fuel = 0.03 W/cm-K kliquid fuel = 0.05 W/cm-K R = 0.35 cm (a) What is the fuel surface temperature? (b) To what fractional radius is the fuel molten? (c) What is the fuel centerline temperature? Light Water Reactor Materials © Donald Olander and Arthur Motta 2/6/2016 9.11 A key safety limit in light-water reactors is the stored energy in the fuel. This is the thermal energy (relative to 25oC) contained in the temperature distributions in the fuel pellet and in the cladding. In the event of a loss-of-coolant accident, flowing liquid water is replaced by stagnant steam, which acts as an insulating blanket over the fuel rod. Even though heat production by fission has been shut off, the original temperature profiles relax to a constant temperature that is the same in both fuel and cladding. This final temperature must not exceed a regulatory limit. Before shutdown, the fuel operated at 500 W/cm linear power and the local water coolant temperature was 300oC. The fuel pellet diameter is 1 cm and the cladding thickness is 1 mm. The fuel-cladding gap is closed, so the temperature drop across the gap is negligible. The external heat transfer coefficient in the water coolant is very large, so there is no temperature drop here either. (a) What are the fuel surface and centerline temperatures during operation? (b) What is the final uniform fuel and cladding temperature after the adiabatic relaxation of the original distributions? Use the thermal properties given in the chapter. References [1] [2] [3] [4] R. Yang, O. Ozer, and H. Rosenbaum, "Current Challenges and Expectations of High Performance Fuel for the Millenium," Light Water Reactor Fuel Performance Meeting, Park City, Utah, ANS, 2000. M. M. El-Wakil, Nuclear Heat Transport: American Nuclear Society, 1978. D. R. Olander, Fundamental Aspects of Nuclear Reactor Fuel Elements: ERDA, 1976. G. Hache and H. M. Chung, "The history of LOCA embrittlement criteria," 28th Water Reactor Safety Information Meeting, Bethesda, USA, NRC, 2001, 205-237. Light Water Reactor Materials © Donald Olander and Arthur Motta 2/6/2016