An INTRODUCTION TO ISSUES IN ENVIRONMENTAL GEOLOGY OF OIL SHALE AND TAR Sands Jeremy Boak, Colorado School of Mines Justin Birdwell, U. S. Geological Survey Outline ‣ Oil shale and tar sand overview ‣ Environmental issues ‣ 30th Oil Shale Symposium highlights 2 November 1, 2010 What is oil shale? ‣ Organic rich sedimentary rock ‣ Formed in lake or marine environments – Commonly carbonate rich; many not be classical shale (fissile argillaceous mudstone) – Contains kerogen – solid hydrocarbon – Primarily algal and bacterial precursor – Immature precursor to oil & gas ‣ Produces oil upon heating ‣ Or deeper burial 3 November 1, 2010 What is shale? Shale Averages* Vernik & Landis, 1996 Pettijohn, 1975 U. Green River L. Green River** Polish Gas Shale Q+F=Clay Carbonate=Clastic Calcite + Dolomite calcareous/ dolomitic mudstone Siliceous Dolomite Eagle Ford Niobrara siliceous marlstone argillaceous marlstone Monterey argillaceous mudstone (traditional shale) Montney Haynesville L. Marcellus 4 Barnett Muskwa Bakken Average Shale Clay Minerals * Data from Hall 2010 ** Burnham et al. 2009 Bazhenov November 1, 2010 siliceous mudstone Siliceous shale Monterey Porcellanite Quartz + Feldspar Petroleum system perspective Oil shale Shale-hosted oil Shale gas? 5 November 1, 2010 Oil shale resource estimates 11. Canada 13. Sweden 10. Estonia Ordovician-Devonian, marine Carboniferous, lacustrine Mesozoic, marine Cambrian-Ordovician, marine Ordovician, marine 15,241 million barrels 6,114 million barrels 16,286 million barrels 4. Russia 270,944 million barrels Ordovician-Jurassic, marine 1. Green River Formation >3,000,000 million barrels 15. Ukraine Tertiary, lacustrine 4,193 million barrels 16. Kazakhstan 2,837 million barrels 3. China 328,000 million barrels Primarily Tertiary, lacustrine 2. Other United States 12. Thailand 619,000 million barrels 6,401 million barrels Eastern Devonian, Phosphoria, Heath Devonian-Permian, marine Tertiary, lacustrine 9. Australia 24,000 million barrels Cretaceous, marine Tertiary, lacustrine 8. Morocco 37,800 million barrels Cretaceous, marine 17. Turkey 1,985 million barrels Tertiary, lacustrine 14. Egypt 5,700 million barrels Cretaceous, marine 6 7. Brazil 80,000 million barrels Permian, lacustrine or marine Tertiary, lacustrine November 1, 2010 5. Israel 6. Jordan Cretaceous, marine Cretaceous, marine 250,000 million barrels 102,000 million barrels Data Source: J. R. Dyni, Geology and Resources of Some World OilShale Deposits, (2006) U. S. Geological Survey Scientific Investigation Report 2005-5294, U. S. Geological Survey, Reston VA Updates from 26th through 30th Oil Shale Symposia, Colorado School of Mines In situ vs. external extraction – oil shale 7 November 1, 2010 In situ vs. external extraction – oil sands 8 November 1, 2010 Environmental issues for oil shale & tar sand ‣ Novel versions and combinations of familiar problems ‣ Consumption of water ‣ Potential contamination of water & atmosphere ‣ Challenges to habitat and range ‣ Interactions of ground water, surface water, soil, rock, air and ecosystem create a linked system – Exciting challenge to the research community to define & execute – Challenge to communicate research results & implications effectively – In a politically charged environment 9 November 1, 2010 Energy and carbon ‣ Extraction of useable hydrocarbons requires a larger input of energy than traditional hydrocarbons – Separation of heavy oil from poorly consolidated tar sands – Pyrolysis of solid kerogen in oil shale ‣ Raises questions of energy return on investment & carbon footprint ‣ Can alternative energy sources merge with these unconventional hydrocarbon resources to mitigate GHG emissions? 10 November 1, 2010 Water use and quality ‣ Water use potentially higher – despite advances in conservation & reuse of process water ‣ Mobilization of hydrocarbons underground – Target of some production schemes for oil shale and tar sand – Carries potential for contamination of ground water ‣ Particulate air emission – Surface mining & processing may contaminate surface & ground water – A novel contaminant pathway not yet clearly addressed 11 November 1, 2010 Land and ecosystem issues ‣ Large areal extent of both types of resources ‣ How to manage land to preserve ecosystems where these resources exist ‣ Migration corridors of significant concern ‣ High areal density of oil shale may mitigate concern ‣ Disposition of spent materials 12 November 1, 2010 Multiple use issues for oil shale ‣ Current development of deeper tight gas sands of Mesa Verde Group ‣ Other possible deeper targets ‣ Dual resource issues – Saline minerals of Green River Formation ‣ Environmental baseline? 13 November 1, 2010 Oil Shale Symposium environmental themes ‣ Water consumption ‣ Groundwater contamination ‣ Water systems evaluation ‣ Climate change impacts on water supply ‣ CO2 emissions from oil shale production ‣ Reuse of spent shale ‣ Species threats 14 November 1, 2010